IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v242y2022ics0360544221027845.html
   My bibliography  Save this article

Comprehensive study on the pyrolysis product characteristics of tobacco stems based on a novel nitrogen-enriched pyrolysis method

Author

Listed:
  • Bai, Jing
  • Gao, Hang
  • Xu, Junhao
  • Li, Lefei
  • Zheng, Peng
  • Li, Pan
  • Song, Jiande
  • Chang, Chun
  • Pang, Shusheng

Abstract

The research on tobacco stems (TS) mainly focuses on the analysis of their own pyrolysis products, and there are few reports on the nitrogen-enriched pyrolysis of TS. Therefore, the microwave pyrolysis characteristics of TS impregnated with different ammonia sources was investigated. The yield, composition and characteristics of pyrolysis products were investigated by elemental analysis, GC/MS, GC and XPS, and the pyrolytic mechanism of TS was discussed. The results showed that TS impregnated with ammonia sources increased the contents of nitrogen-containing compounds (NCCs), and the contents of acid and carbonyl compounds decreased. The introduction of glycine inhibited the pyrolysis of TS to some extent and improved the yield of solid products. Among them, the bio-oil of TS loaded with 6 wt% urea had the highest content of NCCs (33.469%), which were mainly nitrogen-containing heterocyclic compounds (NCHs), including pyridines, pyrroles and pyrazines. Moreover, the introduction of urea inhibited the decomposition of nicotine and improved the yield of this valuable chemical. Biochar is widely applied in fertilizer, catalyst, electrode material and adsorption material because of its high N content. The impregnation of urea increased the yield of H2 and lowered the yield of CO2. Moreover, the nitrogen-rich pyrolysis of biomass increases the content of NCCs and improves the useable value of products.

Suggested Citation

  • Bai, Jing & Gao, Hang & Xu, Junhao & Li, Lefei & Zheng, Peng & Li, Pan & Song, Jiande & Chang, Chun & Pang, Shusheng, 2022. "Comprehensive study on the pyrolysis product characteristics of tobacco stems based on a novel nitrogen-enriched pyrolysis method," Energy, Elsevier, vol. 242(C).
    • Handle: RePEc:eee:energy:v:242:y:2022:i:c:s0360544221027845
    DOI: 10.1016/j.energy.2021.122535
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544221027845
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2021.122535?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chen, Wei & Fang, Yang & Li, Kaixu & Chen, Zhiqun & Xia, Mingwei & Gong, Meng & Chen, Yingquan & Yang, Haiping & Tu, Xin & Chen, Hanping, 2020. "Bamboo wastes catalytic pyrolysis with N-doped biochar catalyst for phenols products," Applied Energy, Elsevier, vol. 260(C).
    2. Kan, Tao & Strezov, Vladimir & Evans, Tim J., 2016. "Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1126-1140.
    3. Chang, Chun & Liu, Zihan & Li, Pan & Wang, Xianhua & Song, Jiande & Fang, Shuqi & Pang, Shusheng, 2021. "Study on products characteristics from catalytic fast pyrolysis of biomass based on the effects of modified biochars," Energy, Elsevier, vol. 229(C).
    4. Fang, Shuqi & Jiang, Luyao & Li, Pan & Bai, Jing & Chang, Chun, 2020. "Study on pyrolysis products characteristics of medical waste and fractional condensation of the pyrolysis oil," Energy, Elsevier, vol. 195(C).
    5. Collard, François-Xavier & Blin, Joël, 2014. "A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 594-608.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Shi, Xiaopeng & Li, Pan & Wang, Xianhua & Song, Jiande & Fang, Shuqi & Chang, Chun & Pang, Shusheng, 2022. "Enhancement of the production of aromatics and bio-syngas from microwave ex-situ pyrolysis based on Zn/Zr modified biochar and multi-catalysts," Energy, Elsevier, vol. 261(PB).
    2. Shi, Xiaopeng & Wang, Biao & Hu, Junhao & Chen, Wei & Chang, Chun & Pang, Shusheng & Li, Pan, 2023. "Investigating the synergistic driving action of microwave and char-based multi-catalysts on biomass catalytic pyrolysis into value-added bio-products," Renewable Energy, Elsevier, vol. 219(P2).
    3. Li, Linghao & Zheng, Xiaoen & Zhang, Fan & Yu, Haipeng & Wang, Hong & Jia, Zhiwen & Sun, Yan & Jiang, Enchen & Xu, Xiwei, 2023. "Formamide hydrothermal pretreatment assisted camellia shell for upgrading to N-containing chemical and supercapacitor electrode preparation using the residue," Energy, Elsevier, vol. 265(C).
    4. Bai, Jing & Li, Lefei & Chen, Zhiyong & Chang, Chun & Pang, Shusheng & Li, Pan, 2023. "Study on the optimization of hydrothermal liquefaction performance of tobacco stem and the high value utilization of catalytic products," Energy, Elsevier, vol. 281(C).
    5. Li, Boyu & Fan, Xing & Yu, Senshen & Xia, Hongying & Nong, Yonghong & Bian, Junping & Sun, Mingyu & Zi, Wenhua, 2023. "Microwave heating of biomass waste residues for sustainable bioenergy and biomass materials preparation: A parametric simulation study," Energy, Elsevier, vol. 274(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Magdalena Matusiak & Radosław Ślęzak & Stanisław Ledakowicz, 2020. "Thermogravimetric Kinetics of Selected Energy Crops Pyrolysis," Energies, MDPI, vol. 13(15), pages 1-15, August.
    2. Bai, Xiaopeng & Wang, Guanghui & Zhu, Zheng & Cai, Chen & Wang, Zhiqin & Wang, Decheng, 2020. "Investigation of improving the yields and qualities of pyrolysis products with combination rod-milled and torrefaction pretreatment," Renewable Energy, Elsevier, vol. 151(C), pages 446-453.
    3. Bhoi, P.R. & Ouedraogo, A.S. & Soloiu, V. & Quirino, R., 2020. "Recent advances on catalysts for improving hydrocarbon compounds in bio-oil of biomass catalytic pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    4. Cai, Junmeng & He, Yifeng & Yu, Xi & Banks, Scott W. & Yang, Yang & Zhang, Xingguang & Yu, Yang & Liu, Ronghou & Bridgwater, Anthony V., 2017. "Review of physicochemical properties and analytical characterization of lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 309-322.
    5. Kawale, Harshal D. & Kishore, Nanda, 2020. "Comparative study on pyrolysis of Delonix Regia, Pinewood sawdust and their co-feed for plausible bio-fuels production," Energy, Elsevier, vol. 203(C).
    6. Ribeiro, Luiz Augusto Badan & Martins, Robson Cristiano & Mesa-Pérez, Juan Miguel & Bizzo, Waldir Antonio, 2019. "Study of bio-oil properties and ageing through fractionation and ternary mixtures with the heavy fraction as the main component," Energy, Elsevier, vol. 169(C), pages 344-355.
    7. Cai, Junmeng & Xu, Di & Dong, Zhujun & Yu, Xi & Yang, Yang & Banks, Scott W. & Bridgwater, Anthony V., 2018. "Processing thermogravimetric analysis data for isoconversional kinetic analysis of lignocellulosic biomass pyrolysis: Case study of corn stalk," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2705-2715.
    8. Mohsin Raza & Abrar Inayat & Basim Abu-Jdayil, 2021. "Crude Glycerol as a Potential Feedstock for Future Energy via Thermochemical Conversion Processes: A Review," Sustainability, MDPI, vol. 13(22), pages 1-27, November.
    9. Mohsin Raza & Abrar Inayat & Ashfaq Ahmed & Farrukh Jamil & Chaouki Ghenai & Salman R. Naqvi & Abdallah Shanableh & Muhammad Ayoub & Ammara Waris & Young-Kwon Park, 2021. "Progress of the Pyrolyzer Reactors and Advanced Technologies for Biomass Pyrolysis Processing," Sustainability, MDPI, vol. 13(19), pages 1-42, October.
    10. Yang, Yuhan & Wang, Tiancheng & Hu, Hongyun & Yao, Dingding & Zou, Chan & Xu, Kai & Li, Xian & Yao, Hong, 2021. "Influence of partial components removal on pyrolysis behavior of lignocellulosic biowaste in molten salts," Renewable Energy, Elsevier, vol. 180(C), pages 616-625.
    11. Primaz, Carmem T. & Ribes-Greus, Amparo & Jacques, Rosângela A., 2021. "Valorization of cotton residues for production of bio-oil and engineered biochar," Energy, Elsevier, vol. 235(C).
    12. Qin, Fanzhi & Zhang, Chen & Zeng, Guangming & Huang, Danlian & Tan, Xiaofei & Duan, Abing, 2022. "Lignocellulosic biomass carbonization for biochar production and characterization of biochar reactivity," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    13. Sitek, Tomáš & Pospíšil, Jiří & Poláčik, Ján & Špiláček, Michal & Varbanov, Petar, 2019. "Fine combustion particles released during combustion of unit mass of beechwood," Renewable Energy, Elsevier, vol. 140(C), pages 390-396.
    14. Andrew N. Amenaghawon & Chinedu L. Anyalewechi & Charity O. Okieimen & Heri Septya Kusuma, 2021. "Biomass pyrolysis technologies for value-added products: a state-of-the-art review," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 23(10), pages 14324-14378, October.
    15. Xu, Hao & Cheng, Shuo & Hungwe, Douglas & Yoshikawa, Kunio & Takahashi, Fumitake, 2022. "Co-pyrolysis coupled with torrefaction enhances hydrocarbons production from rice straw and oil sludge: The effect of torrefaction on co-pyrolysis synergistic behaviors," Applied Energy, Elsevier, vol. 327(C).
    16. José Airton de Mattos Carneiro-Junior & Giulyane Felix de Oliveira & Carine Tondo Alves & Heloysa Martins Carvalho Andrade & Silvio Alexandre Beisl Vieira de Melo & Ednildo Andrade Torres, 2021. "Valorization of Prosopis juliflora Woody Biomass in Northeast Brazilian through Dry Torrefaction," Energies, MDPI, vol. 14(12), pages 1-17, June.
    17. da Silva, Jean Constantino Gomes & Pereira, Jefferson Leque Claudio & Andersen, Silvia Layara Floriani & Moreira, Regina de Fatima Peralta Muniz & José, Humberto Jorge, 2020. "Torrefaction of ponkan peel waste in tubular fixed-bed reactor: In-depth bioenergetic evaluation of torrefaction products," Energy, Elsevier, vol. 210(C).
    18. Dai, Leilei & Wang, Yunpu & Liu, Yuhuan & Ruan, Roger & He, Chao & Yu, Zhenting & Jiang, Lin & Zeng, Zihong & Tian, Xiaojie, 2019. "Integrated process of lignocellulosic biomass torrefaction and pyrolysis for upgrading bio-oil production: A state-of-the-art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 20-36.
    19. Xu, Hao & Hungwe, Douglas & Yang, Pu & Yu, Mengzhu & Cheng, Shuo & Yoshikawa, Kunio & Takahashi, Fumitake, 2024. "Oil sludge addition enables prediction of biomass pyrolysis product profiles by synergistic behaviors between biomass components and oil sludge," Applied Energy, Elsevier, vol. 362(C).
    20. Muzyka, Roksana & Misztal, Edyta & Hrabak, Joanna & Banks, Scott W. & Sajdak, Marcin, 2023. "Various biomass pyrolysis conditions influence the porosity and pore size distribution of biochar," Energy, Elsevier, vol. 263(PE).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:242:y:2022:i:c:s0360544221027845. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.