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Comprehensive study on the pyrolysis product characteristics of tobacco stems based on a novel nitrogen-enriched pyrolysis method

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Listed:
  • Bai, Jing
  • Gao, Hang
  • Xu, Junhao
  • Li, Lefei
  • Zheng, Peng
  • Li, Pan
  • Song, Jiande
  • Chang, Chun
  • Pang, Shusheng

Abstract

The research on tobacco stems (TS) mainly focuses on the analysis of their own pyrolysis products, and there are few reports on the nitrogen-enriched pyrolysis of TS. Therefore, the microwave pyrolysis characteristics of TS impregnated with different ammonia sources was investigated. The yield, composition and characteristics of pyrolysis products were investigated by elemental analysis, GC/MS, GC and XPS, and the pyrolytic mechanism of TS was discussed. The results showed that TS impregnated with ammonia sources increased the contents of nitrogen-containing compounds (NCCs), and the contents of acid and carbonyl compounds decreased. The introduction of glycine inhibited the pyrolysis of TS to some extent and improved the yield of solid products. Among them, the bio-oil of TS loaded with 6 wt% urea had the highest content of NCCs (33.469%), which were mainly nitrogen-containing heterocyclic compounds (NCHs), including pyridines, pyrroles and pyrazines. Moreover, the introduction of urea inhibited the decomposition of nicotine and improved the yield of this valuable chemical. Biochar is widely applied in fertilizer, catalyst, electrode material and adsorption material because of its high N content. The impregnation of urea increased the yield of H2 and lowered the yield of CO2. Moreover, the nitrogen-rich pyrolysis of biomass increases the content of NCCs and improves the useable value of products.

Suggested Citation

  • Bai, Jing & Gao, Hang & Xu, Junhao & Li, Lefei & Zheng, Peng & Li, Pan & Song, Jiande & Chang, Chun & Pang, Shusheng, 2022. "Comprehensive study on the pyrolysis product characteristics of tobacco stems based on a novel nitrogen-enriched pyrolysis method," Energy, Elsevier, vol. 242(C).
    • Handle: RePEc:eee:energy:v:242:y:2022:i:c:s0360544221027845
    DOI: 10.1016/j.energy.2021.122535
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    2. Shi, Xiaopeng & Wang, Biao & Hu, Junhao & Chen, Wei & Chang, Chun & Pang, Shusheng & Li, Pan, 2023. "Investigating the synergistic driving action of microwave and char-based multi-catalysts on biomass catalytic pyrolysis into value-added bio-products," Renewable Energy, Elsevier, vol. 219(P2).
    3. Li, Linghao & Zheng, Xiaoen & Zhang, Fan & Yu, Haipeng & Wang, Hong & Jia, Zhiwen & Sun, Yan & Jiang, Enchen & Xu, Xiwei, 2023. "Formamide hydrothermal pretreatment assisted camellia shell for upgrading to N-containing chemical and supercapacitor electrode preparation using the residue," Energy, Elsevier, vol. 265(C).
    4. Wang, Yurou & Guo, Wenjuan & Chen, Wei & Xu, Gongxun & Zhu, Guoqiang & Xie, Geliang & Xu, Lujiang & Dong, Chengyu & Gao, Shuai & Chen, Yingquan & Yang, Haiping & Chen, Hanping & Fang, Zhen, 2024. "Co-production of porous N-doped biochar and hydrogen-rich gas production from simultaneous pyrolysis-activation-nitrogen doping of biomass: Synergistic mechanism of KOH and NH3," Renewable Energy, Elsevier, vol. 229(C).
    5. Bai, Jing & Huang, Guilin & Qiu, Chenxu & Shang, Xutao & Sun, Zihui & Hu, Junhao & Chang, Chun, 2024. "Preparation of low-nitrogen bio-oil from co-pyrolysis of waste tobacco stem and corn stalk: Product characteristics and denitrogenation mechanism," Energy, Elsevier, vol. 301(C).
    6. Bai, Jing & Li, Lefei & Chen, Zhiyong & Chang, Chun & Pang, Shusheng & Li, Pan, 2023. "Study on the optimization of hydrothermal liquefaction performance of tobacco stem and the high value utilization of catalytic products," Energy, Elsevier, vol. 281(C).
    7. Li, Boyu & Fan, Xing & Yu, Senshen & Xia, Hongying & Nong, Yonghong & Bian, Junping & Sun, Mingyu & Zi, Wenhua, 2023. "Microwave heating of biomass waste residues for sustainable bioenergy and biomass materials preparation: A parametric simulation study," Energy, Elsevier, vol. 274(C).

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