IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v261y2022ipbs0360544222021910.html
   My bibliography  Save this article

Enhancement of the production of aromatics and bio-syngas from microwave ex-situ pyrolysis based on Zn/Zr modified biochar and multi-catalysts

Author

Listed:
  • Shi, Xiaopeng
  • Li, Pan
  • Wang, Xianhua
  • Song, Jiande
  • Fang, Shuqi
  • Chang, Chun
  • Pang, Shusheng

Abstract

The main purpose of this work was to explore the effect of metal modified biochar and multi-catalysts on improving the quality of products by microwave pyrolysis (MVP) of biomass. Single-component catalysts and multi-catalysts were prepared by Zn/Zr impregnation methods. The prepared catalysts were evaluated by XRD, BET, FT-IR and SEM. The properties, composition and product distribution of bio-oil and bio-syngas were analyzed. The results showed that ZSM-5 obtained more bio-oil (42.16 wt%) at the expense of gas product yield, and BC obtained the highest gas yield (43.10 wt%). Zn promoted the selectivity of aromatic hydrocarbons in bio-oil, Zr could effectively improve the yield of syngas and upgrading bio-oil, respectively. Zr-modified multi-catalyst was prepared, and the highest syngas yield (91.54 vol%) and aromatic hydrocarbon products were obtained. Among them, the selectivity of monocyclic aromatic hydrocarbons (MAHs) reached 21.82%. The mechanism of MVP of biomass under the effect of Zn/Zr modified different catalysts was proposed. The study has successfully demonstrated an approach for producing high-value bio-oil and bio-syngas from microwave multi-catalyst pyrolytic system.

Suggested Citation

  • Shi, Xiaopeng & Li, Pan & Wang, Xianhua & Song, Jiande & Fang, Shuqi & Chang, Chun & Pang, Shusheng, 2022. "Enhancement of the production of aromatics and bio-syngas from microwave ex-situ pyrolysis based on Zn/Zr modified biochar and multi-catalysts," Energy, Elsevier, vol. 261(PB).
    • Handle: RePEc:eee:energy:v:261:y:2022:i:pb:s0360544222021910
    DOI: 10.1016/j.energy.2022.125307
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544222021910
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2022.125307?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Bhattacharya, Madhuchhanda & Basak, Tanmay, 2016. "A review on the susceptor assisted microwave processing of materials," Energy, Elsevier, vol. 97(C), pages 306-338.
    2. Fan, Liangliang & Liu, Lei & Xiao, Zhiguo & Su, Zheyang & Huang, Pei & Peng, Hongyu & Lv, Sen & Jiang, Haiwei & Ruan, Roger & Chen, Paul & Zhou, Wenguang, 2021. "Comparative study of continuous-stirred and batch microwave pyrolysis of linear low-density polyethylene in the presence/absence of HZSM-5," Energy, Elsevier, vol. 228(C).
    3. Suriapparao, Dadi V. & Hemanth Kumar, Tanneru & Reddy, B. Rajasekhar & Yerrayya, Attada & Srinivas, B. Abhinaya & Sivakumar, Pandian & Prakash, S. Reddy & Sankar Rao, Chinta & Sridevi, Veluru & Desing, 2022. "Role of ZSM5 catalyst and char susceptor on the synthesis of chemicals and hydrocarbons from microwave-assisted in-situ catalytic co-pyrolysis of algae and plastic wastes," Renewable Energy, Elsevier, vol. 181(C), pages 990-999.
    4. Luo, Juan & Sun, Shichang & Chen, Xing & Lin, Junhao & Ma, Rui & Zhang, Rui & Fang, Lin, 2021. "In-depth exploration of the energy utilization and pyrolysis mechanism of advanced continuous microwave pyrolysis," Applied Energy, Elsevier, vol. 292(C).
    5. Chang, Chun & Liu, Zihan & Li, Pan & Wang, Xianhua & Song, Jiande & Fang, Shuqi & Pang, Shusheng, 2021. "Study on products characteristics from catalytic fast pyrolysis of biomass based on the effects of modified biochars," Energy, Elsevier, vol. 229(C).
    6. Li, Yu & Tan, Zhiwu & Zhu, Youjian & Zhang, Wennan & Du, Zhenyi & Shao, Jingai & Jiang, Long & Yang, Haiping & Chen, Hanping, 2022. "Effects of P-based additives on agricultural biomass torrefaction and particulate matter emissions from fuel combustion," Renewable Energy, Elsevier, vol. 190(C), pages 66-77.
    7. Huang, Yu-Fong & Chiueh, Pei-Te & Kuan, Wen-Hui & Lo, Shang-Lien, 2016. "Microwave pyrolysis of lignocellulosic biomass: Heating performance and reaction kinetics," Energy, Elsevier, vol. 100(C), pages 137-144.
    8. Bai, Jing & Gao, Hang & Xu, Junhao & Li, Lefei & Zheng, Peng & Li, Pan & Song, Jiande & Chang, Chun & Pang, Shusheng, 2022. "Comprehensive study on the pyrolysis product characteristics of tobacco stems based on a novel nitrogen-enriched pyrolysis method," Energy, Elsevier, vol. 242(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Shi, Xiaopeng & Wang, Biao & Hu, Junhao & Chen, Wei & Chang, Chun & Pang, Shusheng & Li, Pan, 2023. "Investigating the synergistic driving action of microwave and char-based multi-catalysts on biomass catalytic pyrolysis into value-added bio-products," Renewable Energy, Elsevier, vol. 219(P2).
    2. Wang, Biao & Chen, Yasen & Chen, Wei & Hu, Junhao & Chang, Chun & Pang, Shusheng & Li, Pan, 2024. "Enhancement of aromatics and syngas production by co-pyrolysis of biomass and plastic waste using biochar-based catalysts in microwave field," Energy, Elsevier, vol. 293(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Biao & Chen, Yasen & Chen, Wei & Hu, Junhao & Chang, Chun & Pang, Shusheng & Li, Pan, 2024. "Enhancement of aromatics and syngas production by co-pyrolysis of biomass and plastic waste using biochar-based catalysts in microwave field," Energy, Elsevier, vol. 293(C).
    2. Li, Jinglin & Lin, Li & Ju, Tongyao & Meng, Fanzhi & Han, Siyu & Chen, Kailun & Jiang, Jianguo, 2024. "Microwave-assisted pyrolysis of solid waste for production of high-value liquid oil, syngas, and carbon solids: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PA).
    3. Shi, Xiaopeng & Wang, Biao & Hu, Junhao & Chen, Wei & Chang, Chun & Pang, Shusheng & Li, Pan, 2023. "Investigating the synergistic driving action of microwave and char-based multi-catalysts on biomass catalytic pyrolysis into value-added bio-products," Renewable Energy, Elsevier, vol. 219(P2).
    4. Ren, Xueyong & Shanb Ghazani, Mohammad & Zhu, Hui & Ao, Wenya & Zhang, Han & Moreside, Emma & Zhu, Jinjiao & Yang, Pu & Zhong, Na & Bi, Xiaotao, 2022. "Challenges and opportunities in microwave-assisted catalytic pyrolysis of biomass: A review," Applied Energy, Elsevier, vol. 315(C).
    5. Ali Mubarak Al-Qahtani, 2023. "A Comprehensive Review in Microwave Pyrolysis of Biomass, Syngas Production and Utilisation," Energies, MDPI, vol. 16(19), pages 1-16, September.
    6. Tao, Ming & Yang, Zheng & Zhao, Yan & Wu, Xingyu & Wu, Chengqing, 2024. "Failure characteristics of microwave heat-treated stressed sandstone: Implications for deep rock breakage using TBM cutting," Energy, Elsevier, vol. 292(C).
    7. Sun, Jiaman & Luo, Juan & Lin, Junhao & Ma, Rui & Sun, Shichang & Fang, Lin & Li, Haowen, 2022. "Study of co-pyrolysis endpoint and product conversion of plastic and biomass using microwave thermogravimetric technology," Energy, Elsevier, vol. 247(C).
    8. Tian, Beile & Mao, Songbo & Guo, Feiqiang & Bai, Jiaming & Shu, Rui & Qian, Lin & Liu, Qi, 2022. "Monolithic biochar-supported cobalt-based catalysts with high-activity and superior-stability for biomass tar reforming," Energy, Elsevier, vol. 242(C).
    9. Hu, Mian & Laghari, Mahmood & Cui, Baihui & Xiao, Bo & Zhang, Beiping & Guo, Dabin, 2018. "Catalytic cracking of biomass tar over char supported nickel catalyst," Energy, Elsevier, vol. 145(C), pages 228-237.
    10. Kostyniuk, Andrii & Likozar, Blaž, 2024. "Wet torrefaction of biomass waste into high quality hydrochar and value-added liquid products using different zeolite catalysts," Renewable Energy, Elsevier, vol. 227(C).
    11. Furszyfer Del Rio, Dylan D. & Sovacool, Benjamin K. & Foley, Aoife M. & Griffiths, Steve & Bazilian, Morgan & Kim, Jinsoo & Rooney, David, 2022. "Decarbonizing the ceramics industry: A systematic and critical review of policy options, developments and sociotechnical systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    12. Chen, Chunxiang & Zhao, Jian & Wei, Yixue & Huang, Xiaodong & Lu, Wei & Fan, Dianzhao & Bi, Yingxin & Qiu, Hongfu, 2023. "Influence of graphite/alumina on co-pyrolysis of Chlorella vulgaris and polypropylene for producing bio-oil," Energy, Elsevier, vol. 265(C).
    13. Huang, Yu-Fong & Kuan, Wen-Hui & Chang, Chun-Yuan, 2018. "Effects of particle size, pretreatment, and catalysis on microwave pyrolysis of corn stover," Energy, Elsevier, vol. 143(C), pages 696-703.
    14. Bai, Jing & Li, Lefei & Chen, Zhiyong & Chang, Chun & Pang, Shusheng & Li, Pan, 2023. "Study on the optimization of hydrothermal liquefaction performance of tobacco stem and the high value utilization of catalytic products," Energy, Elsevier, vol. 281(C).
    15. Pan, Ruming & Martins, Marcio Ferreira & Debenest, Gérald, 2022. "Optimization of oil production through ex-situ catalytic pyrolysis of waste polyethylene with activated carbon," Energy, Elsevier, vol. 248(C).
    16. Li, Longzhi & Cai, Dongqiang & Zhang, Lianjie & Zhang, Yue & Zhao, Zhiyang & Zhang, Zhonglei & Sun, Jifu & Tan, Yongdong & Zou, Guifu, 2023. "Synergistic effects during pyrolysis of binary mixtures of biomass components using microwave-assisted heating coupled with iron base tip-metal," Renewable Energy, Elsevier, vol. 203(C), pages 312-322.
    17. Md Said, Mohamad Syazarudin & Azni, Atiyyah Ameenah & Wan Ab Karim Ghani, Wan Azlina & Idris, Azni & Ja'afar, Mohamad Fakri Zaky & Mohd Salleh, Mohamad Amran, 2022. "Production of biochar from microwave pyrolysis of empty fruit bunch in an alumina susceptor," Energy, Elsevier, vol. 240(C).
    18. Yang, Huayu & Yan, Bowen & Chen, Wei & Fan, Daming, 2023. "Prediction and innovation of sustainable continuous flow microwave processing based on numerical simulations: A systematic review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    19. Nallagatla Vinod Kumar & Gajanan L. Sawargaonkar & C. Sudha Rani & Ajay Singh & T. Ram Prakash & S. Triveni & Prasad J. Kamdi & Rajesh Pasumarthi & Rayapati Karthik & Bathula Venkatesh, 2023. "Comparative Analysis of Pigeonpea Stalk Biochar Characteristics and Energy Use under Different Biochar Production Methods," Sustainability, MDPI, vol. 15(19), pages 1-17, September.
    20. Li, Boyu & Fan, Xing & Yu, Senshen & Xia, Hongying & Nong, Yonghong & Bian, Junping & Sun, Mingyu & Zi, Wenhua, 2023. "Microwave heating of biomass waste residues for sustainable bioenergy and biomass materials preparation: A parametric simulation study," Energy, Elsevier, vol. 274(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:261:y:2022:i:pb:s0360544222021910. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.