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Enhancement of the production of aromatics and bio-syngas from microwave ex-situ pyrolysis based on Zn/Zr modified biochar and multi-catalysts

Author

Listed:
  • Shi, Xiaopeng
  • Li, Pan
  • Wang, Xianhua
  • Song, Jiande
  • Fang, Shuqi
  • Chang, Chun
  • Pang, Shusheng

Abstract

The main purpose of this work was to explore the effect of metal modified biochar and multi-catalysts on improving the quality of products by microwave pyrolysis (MVP) of biomass. Single-component catalysts and multi-catalysts were prepared by Zn/Zr impregnation methods. The prepared catalysts were evaluated by XRD, BET, FT-IR and SEM. The properties, composition and product distribution of bio-oil and bio-syngas were analyzed. The results showed that ZSM-5 obtained more bio-oil (42.16 wt%) at the expense of gas product yield, and BC obtained the highest gas yield (43.10 wt%). Zn promoted the selectivity of aromatic hydrocarbons in bio-oil, Zr could effectively improve the yield of syngas and upgrading bio-oil, respectively. Zr-modified multi-catalyst was prepared, and the highest syngas yield (91.54 vol%) and aromatic hydrocarbon products were obtained. Among them, the selectivity of monocyclic aromatic hydrocarbons (MAHs) reached 21.82%. The mechanism of MVP of biomass under the effect of Zn/Zr modified different catalysts was proposed. The study has successfully demonstrated an approach for producing high-value bio-oil and bio-syngas from microwave multi-catalyst pyrolytic system.

Suggested Citation

  • Shi, Xiaopeng & Li, Pan & Wang, Xianhua & Song, Jiande & Fang, Shuqi & Chang, Chun & Pang, Shusheng, 2022. "Enhancement of the production of aromatics and bio-syngas from microwave ex-situ pyrolysis based on Zn/Zr modified biochar and multi-catalysts," Energy, Elsevier, vol. 261(PB).
    • Handle: RePEc:eee:energy:v:261:y:2022:i:pb:s0360544222021910
    DOI: 10.1016/j.energy.2022.125307
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    1. Shi, Xiaopeng & Wang, Biao & Hu, Junhao & Chen, Wei & Chang, Chun & Pang, Shusheng & Li, Pan, 2023. "Investigating the synergistic driving action of microwave and char-based multi-catalysts on biomass catalytic pyrolysis into value-added bio-products," Renewable Energy, Elsevier, vol. 219(P2).
    2. Wang, Biao & Chen, Yasen & Chen, Wei & Hu, Junhao & Chang, Chun & Pang, Shusheng & Li, Pan, 2024. "Enhancement of aromatics and syngas production by co-pyrolysis of biomass and plastic waste using biochar-based catalysts in microwave field," Energy, Elsevier, vol. 293(C).

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