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Various biomass pyrolysis conditions influence the porosity and pore size distribution of biochar

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  • Muzyka, Roksana
  • Misztal, Edyta
  • Hrabak, Joanna
  • Banks, Scott W.
  • Sajdak, Marcin

Abstract

Biochar is obtained from the pyrolysis of biomass in the absence of oxygen and has great potential as a sorbent or as a carbon sequestration material. Although numerous studies have investigated biochar characteristics, the biochar porosity and sorption properties obtained with different pyrolysis conditions are still largely unclear. The objective of this study was to determine the interrelationships among temperature, material grain size, heating rate, and retention time, as well as the effects of the interactions of these variables on the surface morphology of biochar made from wheat straw. The sorption, porosity, and pore size distribution of biochars prepared at different pyrolytic temperatures were determined. Elemental analysis, BET-N2 surface area analysis, ICP‒OES, and Fourier transform infrared spectroscopy were used to characterize 19 wheat straw biochars obtained via pyrolysis at different temperatures (500–700 °C), heating rates (20 and 30 °C/min), and residence times (5 and 15 min). Based on a full factorial design method and variance analysis, the optimal conditions for wheat straw pyrolysis and the variables that have a statistically significant effect on biochar quality were determined. A high surface area of 400 m2/g and an average pore size of approximately 2.34 nm were obtained at 700 °C for a grain size of 0.5–1.0 mm at a heating rate of 20 °C/min and a residence time of 5 min.

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  • Muzyka, Roksana & Misztal, Edyta & Hrabak, Joanna & Banks, Scott W. & Sajdak, Marcin, 2023. "Various biomass pyrolysis conditions influence the porosity and pore size distribution of biochar," Energy, Elsevier, vol. 263(PE).
  • Handle: RePEc:eee:energy:v:263:y:2023:i:pe:s0360544222030146
    DOI: 10.1016/j.energy.2022.126128
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    Cited by:

    1. Sadeghi Darvazeh, Saeed & Mansoori Mooseloo, Farzaneh & Gholian-Jouybari, Fatemeh & Amiri, Maghsoud & Bonakdari, Hossein & Hajiaghaei-Keshteli, Mostafa, 2024. "Data-driven robust optimization to design an integrated sustainable forest biomass-to-electricity network under disjunctive uncertainties," Applied Energy, Elsevier, vol. 356(C).
    2. Marcin Sajdak & Artur Majewski & Francesca Di Gruttola & Grzegorz Gałko & Edyta Misztal & Michał Rejdak & Andreas Hornung & Miloud Ouadi, 2023. "Evaluation of the Feasibility of Using TCR-Derived Chars from Selected Biomass Wastes and MSW Fractions in CO 2 Sequestration on Degraded and Post-Industrial Areas," Energies, MDPI, vol. 16(7), pages 1-14, March.
    3. Roksana Muzyka & Szymon Sobek & Mariusz Dudziak & Miloud Ouadi & Marcin Sajdak, 2023. "A Comparative Analysis of Waste Biomass Pyrolysis in Py-GC-MS and Fixed-Bed Reactors," Energies, MDPI, vol. 16(8), pages 1-15, April.

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