IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v263y2023ipes0360544222030146.html
   My bibliography  Save this article

Various biomass pyrolysis conditions influence the porosity and pore size distribution of biochar

Author

Listed:
  • Muzyka, Roksana
  • Misztal, Edyta
  • Hrabak, Joanna
  • Banks, Scott W.
  • Sajdak, Marcin

Abstract

Biochar is obtained from the pyrolysis of biomass in the absence of oxygen and has great potential as a sorbent or as a carbon sequestration material. Although numerous studies have investigated biochar characteristics, the biochar porosity and sorption properties obtained with different pyrolysis conditions are still largely unclear. The objective of this study was to determine the interrelationships among temperature, material grain size, heating rate, and retention time, as well as the effects of the interactions of these variables on the surface morphology of biochar made from wheat straw. The sorption, porosity, and pore size distribution of biochars prepared at different pyrolytic temperatures were determined. Elemental analysis, BET-N2 surface area analysis, ICP‒OES, and Fourier transform infrared spectroscopy were used to characterize 19 wheat straw biochars obtained via pyrolysis at different temperatures (500–700 °C), heating rates (20 and 30 °C/min), and residence times (5 and 15 min). Based on a full factorial design method and variance analysis, the optimal conditions for wheat straw pyrolysis and the variables that have a statistically significant effect on biochar quality were determined. A high surface area of 400 m2/g and an average pore size of approximately 2.34 nm were obtained at 700 °C for a grain size of 0.5–1.0 mm at a heating rate of 20 °C/min and a residence time of 5 min.

Suggested Citation

  • Muzyka, Roksana & Misztal, Edyta & Hrabak, Joanna & Banks, Scott W. & Sajdak, Marcin, 2023. "Various biomass pyrolysis conditions influence the porosity and pore size distribution of biochar," Energy, Elsevier, vol. 263(PE).
    • Handle: RePEc:eee:energy:v:263:y:2023:i:pe:s0360544222030146
    DOI: 10.1016/j.energy.2022.126128
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544222030146
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2022.126128?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Merckel, Ryan D. & Heydenrych, Mike D. & Sithole, Bruce B., 2021. "Pyrolysis oil composition and catalytic activity estimated by cumulative mass analysis using Py-GC/MS EGA-MS," Energy, Elsevier, vol. 219(C).
    2. Zhang, Li & Yao, Zonglu & Zhao, Lixin & Li, Zhihe & Yi, Weiming & Kang, Kang & Jia, Jixiu, 2021. "Synthesis and characterization of different activated biochar catalysts for removal of biomass pyrolysis tar," Energy, Elsevier, vol. 232(C).
    3. Das, Shaon Kumar & Ghosh, Goutam Kumar, 2022. "Hydrogel-biochar composite for agricultural applications and controlled release fertilizer: A step towards pollution free environment," Energy, Elsevier, vol. 242(C).
    4. Liu, Yang & Song, Yongmeng & Ran, Chunmei & Siyal, Asif Ali & Chtaeva, Polina & Dai, Jianjun & Jiang, Zhihui & Deng, Zeyu & Zhang, Tianhao & Ao, Wenya & Fu, Jie, 2020. "Pyrolysis of furfural residue in a bubbling fluidized bed reactor: Biochar characterization and analysis," Energy, Elsevier, vol. 211(C).
    5. Saxena, Shobhit & Pinjari, Abdul Rawoof & Bhat, Chandra R., 2022. "Multiple discrete-continuous choice models with additively separable utility functions and linear utility on outside good: Model properties and characterization of demand functions," Transportation Research Part B: Methodological, Elsevier, vol. 155(C), pages 526-557.
    6. Kan, Tao & Strezov, Vladimir & Evans, Tim J., 2016. "Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1126-1140.
    7. Liu, Zhongzhe & Hughes, Matthew & Tong, Yiran & Zhou, Jizhi & Kreutter, William & Lopez, Hugo Cortes & Singer, Simcha & Zitomer, Daniel & McNamara, Patrick, 2022. "Paper mill sludge biochar to enhance energy recovery from pyrolysis: A comprehensive evaluation and comparison," Energy, Elsevier, vol. 239(PA).
    8. Xie, Yongmin & Xiao, Jie & Liu, Qingsheng & Wang, Xiaoqiang & Liu, Jiang & Wu, Peijia & Ouyang, Shaobo, 2021. "Highly efficient utilization of walnut shell biochar through a facile designed portable direct carbon solid oxide fuel cell stack," Energy, Elsevier, vol. 227(C).
    9. Yek, Peter Nai Yuh & Chen, Xiangmeng & Peng, Wanxi & Liew, Rock Keey & Cheng, Chin Kui & Sonne, Christian & Sii, How Sing & Lam, Su Shiung, 2021. "Microwave co-torrefaction of waste oil and biomass pellets for simultaneous recovery of waste and co-firing fuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    10. Ma, Jiao & Kong, Wenwen & Di, Weiqiang & Zhang, Zhikun & Wang, Zhuozhi & Feng, Shuo & Shen, Boxiong & Mu, Lan, 2022. "Synergistic effect of bulking agents and biodegradation on the pyrolysis of biodried products derived from municipal organic wastes: Product distribution and biochar physicochemical characteristics," Energy, Elsevier, vol. 248(C).
    11. Chang, Chun & Liu, Zihan & Li, Pan & Wang, Xianhua & Song, Jiande & Fang, Shuqi & Pang, Shusheng, 2021. "Study on products characteristics from catalytic fast pyrolysis of biomass based on the effects of modified biochars," Energy, Elsevier, vol. 229(C).
    12. Anna Poskart & Magdalena Skrzyniarz & Marcin Sajdak & Monika Zajemska & Andrzej Skibiński, 2021. "Management of Lignocellulosic Waste towards Energy Recovery by Pyrolysis in the Framework of Circular Economy Strategy," Energies, MDPI, vol. 14(18), pages 1-17, September.
    13. Liu, Haolin & Ye, Chao & Xu, Yousheng & Wang, Qisong, 2022. "Effect of activation conditions and iron loading content on the catalytic cracking of toluene by biochar," Energy, Elsevier, vol. 247(C).
    14. Atinafu, Dimberu G. & Wi, Seunghwan & Yun, Beom Yeol & Kim, Sumin, 2021. "Engineering biochar with multiwalled carbon nanotube for efficient phase change material encapsulation and thermal energy storage," Energy, Elsevier, vol. 216(C).
    15. Lazaroiu, Gheorghe & Pop, Elena & Negreanu, Gabriel & Pisa, Ionel & Mihaescu, Lucian & Bondrea, Andreya & Berbece, Viorel, 2017. "Biomass combustion with hydrogen injection for energy applications," Energy, Elsevier, vol. 127(C), pages 351-357.
    16. Goyal, H.B. & Seal, Diptendu & Saxena, R.C., 2008. "Bio-fuels from thermochemical conversion of renewable resources: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(2), pages 504-517, February.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Sadeghi Darvazeh, Saeed & Mansoori Mooseloo, Farzaneh & Gholian-Jouybari, Fatemeh & Amiri, Maghsoud & Bonakdari, Hossein & Hajiaghaei-Keshteli, Mostafa, 2024. "Data-driven robust optimization to design an integrated sustainable forest biomass-to-electricity network under disjunctive uncertainties," Applied Energy, Elsevier, vol. 356(C).
    2. Marcin Sajdak & Artur Majewski & Francesca Di Gruttola & Grzegorz Gałko & Edyta Misztal & Michał Rejdak & Andreas Hornung & Miloud Ouadi, 2023. "Evaluation of the Feasibility of Using TCR-Derived Chars from Selected Biomass Wastes and MSW Fractions in CO 2 Sequestration on Degraded and Post-Industrial Areas," Energies, MDPI, vol. 16(7), pages 1-14, March.
    3. Roksana Muzyka & Szymon Sobek & Mariusz Dudziak & Miloud Ouadi & Marcin Sajdak, 2023. "A Comparative Analysis of Waste Biomass Pyrolysis in Py-GC-MS and Fixed-Bed Reactors," Energies, MDPI, vol. 16(8), pages 1-15, April.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Fernandez, Enara & Santamaria, Laura & Amutio, Maider & Artetxe, Maite & Arregi, Aitor & Lopez, Gartzen & Bilbao, Javier & Olazar, Martin, 2022. "Role of temperature in the biomass steam pyrolysis in a conical spouted bed reactor," Energy, Elsevier, vol. 238(PC).
    2. Bhoi, P.R. & Ouedraogo, A.S. & Soloiu, V. & Quirino, R., 2020. "Recent advances on catalysts for improving hydrocarbon compounds in bio-oil of biomass catalytic pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    3. Cai, Junmeng & He, Yifeng & Yu, Xi & Banks, Scott W. & Yang, Yang & Zhang, Xingguang & Yu, Yang & Liu, Ronghou & Bridgwater, Anthony V., 2017. "Review of physicochemical properties and analytical characterization of lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 309-322.
    4. Kawale, Harshal D. & Kishore, Nanda, 2020. "Comparative study on pyrolysis of Delonix Regia, Pinewood sawdust and their co-feed for plausible bio-fuels production," Energy, Elsevier, vol. 203(C).
    5. Mohsin Raza & Abrar Inayat & Basim Abu-Jdayil, 2021. "Crude Glycerol as a Potential Feedstock for Future Energy via Thermochemical Conversion Processes: A Review," Sustainability, MDPI, vol. 13(22), pages 1-27, November.
    6. Bai, Jing & Gao, Hang & Xu, Junhao & Li, Lefei & Zheng, Peng & Li, Pan & Song, Jiande & Chang, Chun & Pang, Shusheng, 2022. "Comprehensive study on the pyrolysis product characteristics of tobacco stems based on a novel nitrogen-enriched pyrolysis method," Energy, Elsevier, vol. 242(C).
    7. Amelia Carolina Sparavigna, 2023. "Multifunctional Porosity in Biochar," International Journal of Sciences, Office ijSciences, vol. 12(07), pages 41-54, July.
    8. Mohsin Raza & Abrar Inayat & Ashfaq Ahmed & Farrukh Jamil & Chaouki Ghenai & Salman R. Naqvi & Abdallah Shanableh & Muhammad Ayoub & Ammara Waris & Young-Kwon Park, 2021. "Progress of the Pyrolyzer Reactors and Advanced Technologies for Biomass Pyrolysis Processing," Sustainability, MDPI, vol. 13(19), pages 1-42, October.
    9. Feng, Qunjie & Lin, Yunqin, 2017. "Integrated processes of anaerobic digestion and pyrolysis for higher bioenergy recovery from lignocellulosic biomass: A brief review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 1272-1287.
    10. Jayanto Kumar Sarkar & Qingyue Wang, 2020. "Different Pyrolysis Process Conditions of South Asian Waste Coconut Shell and Characterization of Gas, Bio-Char, and Bio-Oil," Energies, MDPI, vol. 13(8), pages 1-14, April.
    11. Anna Poskart & Magdalena Skrzyniarz & Marcin Sajdak & Monika Zajemska & Andrzej Skibiński, 2021. "Management of Lignocellulosic Waste towards Energy Recovery by Pyrolysis in the Framework of Circular Economy Strategy," Energies, MDPI, vol. 14(18), pages 1-17, September.
    12. Gholizadeh, Mortaza & Hu, Xun & Liu, Qing, 2019. "A mini review of the specialties of the bio-oils produced from pyrolysis of 20 different biomasses," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    13. Ong, Hwai Chyuan & Chen, Wei-Hsin & Farooq, Abid & Gan, Yong Yang & Lee, Keat Teong & Ashokkumar, Veeramuthu, 2019. "Catalytic thermochemical conversion of biomass for biofuel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    14. Brigljević, Boris & Žuvela, Petar & Liu, J. Jay & Woo, Hee-Chul & Choi, Jae Hyung, 2018. "Development of an automated method for modelling of bio-crudes originating from biofuel production processes based on thermochemical conversion," Applied Energy, Elsevier, vol. 215(C), pages 670-678.
    15. Naqvi, Salman Raza & Jamshaid, Sana & Naqvi, Muhammad & Farooq, Wasif & Niazi, Muhammad Bilal Khan & Aman, Zaeem & Zubair, Muhammad & Ali, Majid & Shahbaz, Muhammad & Inayat, Abrar & Afzal, Waheed, 2018. "Potential of biomass for bioenergy in Pakistan based on present case and future perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1247-1258.
    16. Aboagye, D. & Banadda, N. & Kiggundu, N. & Kabenge, I., 2017. "Assessment of orange peel waste availability in ghana and potential bio-oil yield using fast pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 814-821.
    17. JoungDu Shin & SangWon Park & Changyoon Jeong, 2020. "Assessment of Agro-Environmental Impacts for Supplemented Methods to Biochar Manure Pellets during Rice ( Oryza sativa L.) Cultivation," Energies, MDPI, vol. 13(8), pages 1-14, April.
    18. Jun Sheng Teh & Yew Heng Teoh & Heoy Geok How & Thanh Danh Le & Yeoh Jun Jie Jason & Huu Tho Nguyen & Dong Lin Loo, 2021. "The Potential of Sustainable Biomass Producer Gas as a Waste-to-Energy Alternative in Malaysia," Sustainability, MDPI, vol. 13(7), pages 1-31, April.
    19. Liu, Zihan & Li, Pan & Chang, Chun & Wang, Xianhua & Song, Jiande & Fang, Shuqi & Pang, Shusheng, 2022. "Influence of metal chloride modified biochar on products characteristics from biomass catalytic pyrolysis," Energy, Elsevier, vol. 250(C).
    20. Małgorzata Sieradzka & Cezary Kirczuk & Izabela Kalemba-Rec & Agata Mlonka-Mędrala & Aneta Magdziarz, 2022. "Pyrolysis of Biomass Wastes into Carbon Materials," Energies, MDPI, vol. 15(5), pages 1-12, March.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:263:y:2023:i:pe:s0360544222030146. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.