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Valorization of Prosopis juliflora Woody Biomass in Northeast Brazilian through Dry Torrefaction

Author

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  • José Airton de Mattos Carneiro-Junior

    (Department of Biofuels, Federal Institute of Education, Science and Technology of Bahia, Irecê-BA 44900-000, Brazil)

  • Giulyane Felix de Oliveira

    (Department of Inorganic Chemistry, Federal University of Bahia, Salvador-BA 40170-115, Brazil)

  • Carine Tondo Alves

    (Department of Energy Engineering, Federal University of the Reconcavo of Bahia, Feira de Santana-BA 44085-132, Brazil)

  • Heloysa Martins Carvalho Andrade

    (Department of Inorganic Chemistry, Federal University of Bahia, Salvador-BA 40170-115, Brazil
    Interdisciplinary Center in Energy and Environment, Federal University of Bahia, Salvador-BA 40170-115, Brazil)

  • Silvio Alexandre Beisl Vieira de Melo

    (Interdisciplinary Center in Energy and Environment, Federal University of Bahia, Salvador-BA 40170-115, Brazil
    Industrial Engineering Program, Federal University of Bahia, Salvador-BA 40210-630, Brazil)

  • Ednildo Andrade Torres

    (Interdisciplinary Center in Energy and Environment, Federal University of Bahia, Salvador-BA 40170-115, Brazil
    Industrial Engineering Program, Federal University of Bahia, Salvador-BA 40210-630, Brazil)

Abstract

Torrefaction has been investigated to improve the desirable properties of biomass as solid biofuel, usually used in natura as firewood in several countries. This paper has the main objective to present a broad characterization of the biomass Prosopis juliflora ( P. juliflora ), investigating its potential as a solid biofuel after its torrefaction process. The methodology was based on different procedures. The experimental runs were carried out at 230, 270, and 310 °C for 30 min, using a bench-scale torrefaction apparatus, with an inert atmosphere. In order to investigate the effect of temperature in constant time, torrefaction parameters were calculated, such as mass yield, energy yield, calorific value, base-to-acid ratio (B/A), and the alkaline index (AI). The physicochemical properties of the torrefied samples were determined and thermogravimetric analysis was used to determine the kinetic parameters at four different heating rates of 5, 10, 20, and 30 °C/min. Pyrolysis kinetics was investigated using the Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS) isoconversional methods. Highly thermally stable biofuels were obtained due to the great degradation of hemicellulose and cellulose during torrefaction at higher temperatures. The highest heating value (HHV) of the samples varied between 18.3 and 23.1 MJ/kg, and the energy yield between 81.1 and 96.2%. The results indicate that P. juliflora torrefied becomes a more attractive and competitive solid biofuel alternative in the generation of heat and energy in northeast Brazil.

Suggested Citation

  • José Airton de Mattos Carneiro-Junior & Giulyane Felix de Oliveira & Carine Tondo Alves & Heloysa Martins Carvalho Andrade & Silvio Alexandre Beisl Vieira de Melo & Ednildo Andrade Torres, 2021. "Valorization of Prosopis juliflora Woody Biomass in Northeast Brazilian through Dry Torrefaction," Energies, MDPI, vol. 14(12), pages 1-17, June.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:12:p:3465-:d:573307
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    References listed on IDEAS

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    1. Antonios Nazos & Dorothea Politi & Georgios Giakoumakis & Dimitrios Sidiras, 2022. "Simulation and Optimization of Lignocellulosic Biomass Wet- and Dry-Torrefaction Process for Energy, Fuels and Materials Production: A Review," Energies, MDPI, vol. 15(23), pages 1-35, November.

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