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Study on products characteristics from catalytic fast pyrolysis of biomass based on the effects of modified biochars

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  • Chang, Chun
  • Liu, Zihan
  • Li, Pan
  • Wang, Xianhua
  • Song, Jiande
  • Fang, Shuqi
  • Pang, Shusheng

Abstract

Biochar was produced from peanut shells pyrolysis and then modified by HCl and MnCl2, and the effects of modified biochars on the pyrolysis products characteristics were investigated. The catalytic effect of the biochar prepared at 650 °C is more suitable, and the products under 650 °C have lower acid content and higher phenol content than that under other temperatures. It was found that the modification effect of low concentration of MnCl2 was not obvious, which manifested as a higher phenol content under the catalysis of the HCl modified biochar. Then, different concentrations of MnCl2 were adopted and the highest phenol yield was obtained at 1.5 mol/L, which was higher than that of direct pyrolysis, about 78.9%. Besides, its acid yield was also the lowest, and the reduction was about 37.5%. The phenol products were analyzed under different concentrations of MnCl2 modified biochar and the results showed that the selectivity of alkylated phenol substances was greatly improved. When MnCl2 is 0.8 mol/L, the CO2 content was lowest, while the H2 content was highest, the increment was up to about 92.8% compared with that of direct pyrolysis. Therefore, the co-modified biochar with HCl and MnCl2 can better promote lignin cracking and generate more phenols.

Suggested Citation

  • Chang, Chun & Liu, Zihan & Li, Pan & Wang, Xianhua & Song, Jiande & Fang, Shuqi & Pang, Shusheng, 2021. "Study on products characteristics from catalytic fast pyrolysis of biomass based on the effects of modified biochars," Energy, Elsevier, vol. 229(C).
    • Handle: RePEc:eee:energy:v:229:y:2021:i:c:s0360544221010665
    DOI: 10.1016/j.energy.2021.120818
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    References listed on IDEAS

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    2. Shi, Xiaopeng & Wang, Biao & Hu, Junhao & Chen, Wei & Chang, Chun & Pang, Shusheng & Li, Pan, 2023. "Investigating the synergistic driving action of microwave and char-based multi-catalysts on biomass catalytic pyrolysis into value-added bio-products," Renewable Energy, Elsevier, vol. 219(P2).
    3. Bai, Jing & Gao, Hang & Xu, Junhao & Li, Lefei & Zheng, Peng & Li, Pan & Song, Jiande & Chang, Chun & Pang, Shusheng, 2022. "Comprehensive study on the pyrolysis product characteristics of tobacco stems based on a novel nitrogen-enriched pyrolysis method," Energy, Elsevier, vol. 242(C).
    4. Xinna Liu & Jie Zhang & Qian Wang & Hiba Shaghaleh & Tingting Chang & Yousef Alhaj Hamoud, 2022. "Modification of Soil Physical Properties by Maize Straw Biochar and Earthworm Manure to Enhance Hydraulic Characteristics under Greenhouse Condition," Sustainability, MDPI, vol. 14(20), pages 1-12, October.
    5. Xu, Donghua & Lin, Junhao & Ma, Rui & Fang, Lin & Sun, Shichang & Luo, Juan, 2022. "Microwave pyrolysis of biomass for low-oxygen bio-oil: Mechanisms of CO2-assisted in-situ deoxygenation," Renewable Energy, Elsevier, vol. 184(C), pages 124-133.
    6. Muzyka, Roksana & Misztal, Edyta & Hrabak, Joanna & Banks, Scott W. & Sajdak, Marcin, 2023. "Various biomass pyrolysis conditions influence the porosity and pore size distribution of biochar," Energy, Elsevier, vol. 263(PE).
    7. Wang, Biao & Chen, Yasen & Chen, Wei & Hu, Junhao & Chang, Chun & Pang, Shusheng & Li, Pan, 2024. "Enhancement of aromatics and syngas production by co-pyrolysis of biomass and plastic waste using biochar-based catalysts in microwave field," Energy, Elsevier, vol. 293(C).

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