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Crude Glycerol as a Potential Feedstock for Future Energy via Thermochemical Conversion Processes: A Review

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  • Mohsin Raza

    (Chemical and Petroleum Engineering Department, College of Engineering, United Arab Emirates University, Al Ain 15551, United Arab Emirates)

  • Abrar Inayat

    (Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah 27272, United Arab Emirates)

  • Basim Abu-Jdayil

    (Chemical and Petroleum Engineering Department, College of Engineering, United Arab Emirates University, Al Ain 15551, United Arab Emirates
    National Water and Energy Center, United Arab Emirates University, Al Ain 15551, United Arab Emirates)

Abstract

Biodiesel is an emerging substitute for petroleum-based products. It is considered an ecologically safe and sustainable fuel. The high cost of biodiesel production is linearly related to its feedstock. Crude glycerol, which is a by-product of the biodiesel industry, is also a major challenge that must be addressed. A large volume of crude glycerol needs to be disposed of, and this involves processing, dumping, and land requirements. This increases the cost of biodiesel production. One way to decrease the cost of biodiesel production is to utilize its by-product to make valuable products. Crude glycerol can be processed to produce a variety of chemicals and products. The present utilization of crude glycerol is not enough to bring down its surplus availability. Thermochemical conversion processes can utilize crude glycerol as a starting feedstock and convert it into solid, liquid, and gaseous fuels. The utilization of crude glycerol through integrated thermochemical conversion processes could lead to an integrated biorefinery. This review paper highlights the research scope for areas where crude glycerol could be utilized as a feedstock or co-feedstock in thermochemical conversion technology. Various thermochemical conversion processes, namely, gasification, pyrolysis, combustion, catalytic steam reforming, liquefaction, and supercritical water reforming, are discussed and shown to be highly suitable for the use of crude glycerol as an economical feedstock. It is found that the integration of crude glycerol with other thermochemical conversion processes for energy production is a promising option to overcome the challenges related to biodiesel production costs. Hence, this paper provides all the necessary information on the present utilization status of crude glycerol in thermochemical conversion processes, as well as identifying possible research gaps that could be filled by future research studies.

Suggested Citation

  • Mohsin Raza & Abrar Inayat & Basim Abu-Jdayil, 2021. "Crude Glycerol as a Potential Feedstock for Future Energy via Thermochemical Conversion Processes: A Review," Sustainability, MDPI, vol. 13(22), pages 1-27, November.
  • Handle: RePEc:gam:jsusta:v:13:y:2021:i:22:p:12813-:d:683183
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    References listed on IDEAS

    as
    1. Mei, Danhua & Liu, Shiyun & Wang, Sen & Zhou, Renwu & Zhou, Rusen & Fang, Zhi & Zhang, Xianhui & Cullen, Patrick J. & Ostrikov, Kostya (Ken), 2020. "Plasma-enabled liquefaction of lignocellulosic biomass: Balancing feedstock content for maximum energy yield," Renewable Energy, Elsevier, vol. 157(C), pages 1061-1071.
    2. Gutiérrez Ortiz, F.J. & Campanario, F.J. & Aguilera, P.G. & Ollero, P., 2015. "Hydrogen production from supercritical water reforming of glycerol over Ni/Al2O3–SiO2 catalyst," Energy, Elsevier, vol. 84(C), pages 634-642.
    3. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    4. Long, Huiling & Li, Xiaobing & Wang, Hong & Jia, Jingdun, 2013. "Biomass resources and their bioenergy potential estimation: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 344-352.
    5. Tan, H.W. & Abdul Aziz, A.R. & Aroua, M.K., 2013. "Glycerol production and its applications as a raw material: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 118-127.
    6. Effendi, A. & Gerhauser, H. & Bridgwater, A.V., 2008. "Production of renewable phenolic resins by thermochemical conversion of biomass: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(8), pages 2092-2116, October.
    7. Van de Velden, Manon & Baeyens, Jan & Brems, Anke & Janssens, Bart & Dewil, Raf, 2010. "Fundamentals, kinetics and endothermicity of the biomass pyrolysis reaction," Renewable Energy, Elsevier, vol. 35(1), pages 232-242.
    8. Nayak, Sheetal N. & Bhasin, Chandra Prakash & Nayak, Milap G., 2019. "A review on microwave-assisted transesterification processes using various catalytic and non-catalytic systems," Renewable Energy, Elsevier, vol. 143(C), pages 1366-1387.
    9. Anuar, Mohd Razealy & Abdullah, Ahmad Zuhairi, 2016. "Challenges in biodiesel industry with regards to feedstock, environmental, social and sustainability issues: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 208-223.
    10. Inayat, Abrar & Inayat, Muddasser & Shahbaz, Muhammad & Sulaiman, Shaharin A. & Raza, Mohsin & Yusup, Suzana, 2020. "Parametric analysis and optimization for the catalytic air gasification of palm kernel shell using coal bottom ash as catalyst," Renewable Energy, Elsevier, vol. 145(C), pages 671-681.
    11. Adhikari, Sushil & Fernando, Sandun D. & Haryanto, Agus, 2008. "Hydrogen production from glycerin by steam reforming over nickel catalysts," Renewable Energy, Elsevier, vol. 33(5), pages 1097-1100.
    12. Dou, Binlin & Song, Yongchen & Wang, Chao & Chen, Haisheng & Xu, Yujie, 2014. "Hydrogen production from catalytic steam reforming of biodiesel byproduct glycerol: Issues and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 950-960.
    13. Hoang, Anh Tuan & Sandro Nižetić, & Olcer, Aykut I. & Ong, Hwai Chyuan & Chen, Wei-Hsin & Chong, Cheng Tung & Thomas, Sabu & Bandh, Suhaib A. & Nguyen, Xuan Phuong, 2021. "Impacts of COVID-19 pandemic on the global energy system and the shift progress to renewable energy: Opportunities, challenges, and policy implications," Energy Policy, Elsevier, vol. 154(C).
    14. Reinhard Rauch & Jitka Hrbek & Hermann Hofbauer, 2014. "Biomass gasification for synthesis gas production and applications of the syngas," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 3(4), pages 343-362, July.
    15. Tian, Xueyu & You, Fengqi, 2019. "Carbon-neutral hybrid energy systems with deep water source cooling, biomass heating, and geothermal heat and power," Applied Energy, Elsevier, vol. 250(C), pages 413-432.
    16. Gutiérrez Ortiz, F.J. & Serrera, A. & Galera, S. & Ollero, P., 2013. "Experimental study of the supercritical water reforming of glycerol without the addition of a catalyst," Energy, Elsevier, vol. 56(C), pages 193-206.
    17. Ardi, M.S. & Aroua, M.K. & Hashim, N. Awanis, 2015. "Progress, prospect and challenges in glycerol purification process: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1164-1173.
    18. Li, Hui & Liu, Fengsheng & Ma, Xiaoling & Cui, Ping & Guo, Min & Li, Yan & Gao, Yan & Zhou, Shoujun & Yu, Mingzhi, 2020. "An efficient basic heterogeneous catalyst synthesis of magnetic mesoporous Fe@C support SrO for transesterification," Renewable Energy, Elsevier, vol. 149(C), pages 816-827.
    19. Silvia Román Suero & Beatriz Ledesma & Andrés Álvarez-Murillo & Awf Al-Kassir & Talal Yusaf, 2015. "Glycerin, a Biodiesel By-Product with Potentiality to Produce Hydrogen by Steam Gasification," Energies, MDPI, vol. 8(11), pages 1-11, November.
    20. Kan, Tao & Strezov, Vladimir & Evans, Tim J., 2016. "Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1126-1140.
    21. Dou, Binlin & Song, Yongchen & Wang, Chao & Chen, Haisheng & Yang, Mingjun & Xu, Yujie, 2014. "Hydrogen production by enhanced-sorption chemical looping steam reforming of glycerol in moving-bed reactors," Applied Energy, Elsevier, vol. 130(C), pages 342-349.
    22. Atabani, A.E. & Silitonga, A.S. & Badruddin, Irfan Anjum & Mahlia, T.M.I. & Masjuki, H.H. & Mekhilef, S., 2012. "A comprehensive review on biodiesel as an alternative energy resource and its characteristics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 2070-2093.
    23. Inayat, Abrar & Raza, Mohsin, 2019. "District cooling system via renewable energy sources: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 360-373.
    24. Leoneti, Alexandre Bevilacqua & Aragão-Leoneti, Valquiria & de Oliveira, Sonia Valle Walter Borges, 2012. "Glycerol as a by-product of biodiesel production in Brazil: Alternatives for the use of unrefined glycerol," Renewable Energy, Elsevier, vol. 45(C), pages 138-145.
    25. Chen, Haisheng & Ding, Yulong & Cong, Ngoc T. & Dou, Binlin & Dupont, Valerie & Ghadiri, Mojtaba & Williams, Paul T., 2011. "A comparative study on hydrogen production from steam-glycerol reforming: thermodynamics and experimental," Renewable Energy, Elsevier, vol. 36(2), pages 779-788.
    26. Chen, Jen-Jeng & Lee, Yu-Ru, 2018. "Optimization of the transesterification reaction of microalgal Monoraphidium sp," Renewable Energy, Elsevier, vol. 129(PB), pages 717-723.
    27. Mofijur, M. & Masjuki, H.H. & Kalam, M.A. & Hazrat, M.A. & Liaquat, A.M. & Shahabuddin, M. & Varman, M., 2012. "Prospects of biodiesel from Jatropha in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5007-5020.
    28. Yang, Jie & (Sophia) He, Quan & Yang, Linxi, 2019. "A review on hydrothermal co-liquefaction of biomass," Applied Energy, Elsevier, vol. 250(C), pages 926-945.
    29. Quispe, César A.G. & Coronado, Christian J.R. & Carvalho Jr., João A., 2013. "Glycerol: Production, consumption, prices, characterization and new trends in combustion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 475-493.
    30. Sansaniwal, S.K. & Pal, K. & Rosen, M.A. & Tyagi, S.K., 2017. "Recent advances in the development of biomass gasification technology: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 363-384.
    31. Joselin Herbert, G.M. & Iniyan, S. & Sreevalsan, E. & Rajapandian, S., 2007. "A review of wind energy technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(6), pages 1117-1145, August.
    32. Roy, Poritosh & Dias, Goretty, 2017. "Prospects for pyrolysis technologies in the bioenergy sector: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 59-69.
    33. Lima-Corrêa, Renata A.B. & Castro, Cínthia S. & Damasceno, Amanda S. & Assaf, José M., 2020. "The enhanced activity of base metal modified MgAl mixed oxides from sol-gel hydrotalcite for ethylic transesterification," Renewable Energy, Elsevier, vol. 146(C), pages 1984-1990.
    34. Remón, J. & Arcelus-Arrillaga, P. & García, L. & Arauzo, J., 2018. "Simultaneous production of gaseous and liquid biofuels from the synergetic co-valorisation of bio-oil and crude glycerol in supercritical water," Applied Energy, Elsevier, vol. 228(C), pages 2275-2287.
    35. Kezhen Qian & Ajay Kumar & Krushna Patil & Danielle Bellmer & Donghai Wang & Wenqiao Yuan & Raymond L. Huhnke, 2013. "Effects of Biomass Feedstocks and Gasification Conditions on the Physiochemical Properties of Char," Energies, MDPI, vol. 6(8), pages 1-15, August.
    36. Collard, François-Xavier & Blin, Joël, 2014. "A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 594-608.
    37. Shahzad, M. Kashif & Zahid, Adeem & ur Rashid, Tanzeel & Rehan, Mirza Abdullah & Ali, Muzaffar & Ahmad, Mueen, 2017. "Techno-economic feasibility analysis of a solar-biomass off grid system for the electrification of remote rural areas in Pakistan using HOMER software," Renewable Energy, Elsevier, vol. 106(C), pages 264-273.
    38. Alberg Østergaard, Poul & Mathiesen, Brian Vad & Möller, Bernd & Lund, Henrik, 2010. "A renewable energy scenario for Aalborg Municipality based on low-temperature geothermal heat, wind power and biomass," Energy, Elsevier, vol. 35(12), pages 4892-4901.
    39. Bai, Zhang & Liu, Qibin & Lei, Jing & Hong, Hui & Jin, Hongguang, 2017. "New solar-biomass power generation system integrated a two-stage gasifier," Applied Energy, Elsevier, vol. 194(C), pages 310-319.
    40. Pascoal, C.V.P. & Oliveira, A.L.L. & Figueiredo, D.D. & Assunção, J.C.C., 2020. "Optimization and kinetic study of ultrasonic-mediated in situ transesterification for biodiesel production from the almonds of Syagrus cearensis," Renewable Energy, Elsevier, vol. 147(P1), pages 1815-1824.
    41. Goyal, H.B. & Seal, Diptendu & Saxena, R.C., 2008. "Bio-fuels from thermochemical conversion of renewable resources: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(2), pages 504-517, February.
    42. Avhad, M.R. & Marchetti, J.M., 2015. "A review on recent advancement in catalytic materials for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 696-718.
    43. Silitonga, A.S. & Atabani, A.E. & Mahlia, T.M.I. & Masjuki, H.H. & Badruddin, Irfan Anjum & Mekhilef, S., 2011. "A review on prospect of Jatropha curcas for biodiesel in Indonesia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3733-3756.
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    2. Zhang, Jianan & Wang, Yuesen & Muldoon, Valerie L. & Deng, Sili, 2022. "Crude glycerol and glycerol as fuels and fuel additives in combustion applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).

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