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Study of bio-oil properties and ageing through fractionation and ternary mixtures with the heavy fraction as the main component

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  • Ribeiro, Luiz Augusto Badan
  • Martins, Robson Cristiano
  • Mesa-Pérez, Juan Miguel
  • Bizzo, Waldir Antonio

Abstract

Bio-oil produced by fast pyrolysis of eucalyptus sawdust in a bubbling fluidised bed reactor with temperature between 450 and 550 °C was divided into two fractions: heavy bio-oil (HBO) and light bio-oil (LBO). These fractions were mixed with ethanol (EtOH) in order to obtain seven ternary mixtures. These mixtures were characterised according to the following properties: viscosity, lower heating value (LHV), higher heating value (HHV), water content, solids content, acidity, flash point, pour point, density and ultimate analysis. Fractions also had their properties determined. Viscosity, due to its peculiarity, was monitored until 90 days and each mixture had its viscosity profile as a function of time and temperature. Ultimate analysis, heating values, acidity and water content were determined at two different moments to provide an understanding into mixtures ageing. Some properties were analysed through the ternary diagram. Overall, mixtures presented good fuel characteristics with lower water content and acidity and higher heating values and carbon content than typical bio-oil. Nevertheless, choosing HBO as the main component had its drawbacks like viscosities unexpectedly high. Except for viscosity, ageing promoted beneficial changes like lowering water content to a minimum of 0.93% and raising HHV to a maximum of 24.6 MJ kg−1.

Suggested Citation

  • Ribeiro, Luiz Augusto Badan & Martins, Robson Cristiano & Mesa-Pérez, Juan Miguel & Bizzo, Waldir Antonio, 2019. "Study of bio-oil properties and ageing through fractionation and ternary mixtures with the heavy fraction as the main component," Energy, Elsevier, vol. 169(C), pages 344-355.
  • Handle: RePEc:eee:energy:v:169:y:2019:i:c:p:344-355
    DOI: 10.1016/j.energy.2018.12.042
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    References listed on IDEAS

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    1. Guo, Xiujuan & Wang, Shurong & Guo, Zuogang & Liu, Qian & Luo, Zhongyang & Cen, Kefa, 2010. "Pyrolysis characteristics of bio-oil fractions separated by molecular distillation," Applied Energy, Elsevier, vol. 87(9), pages 2892-2898, September.
    2. Yang, Zixu & Kumar, Ajay & Huhnke, Raymond L., 2015. "Review of recent developments to improve storage and transportation stability of bio-oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 859-870.
    3. Kan, Tao & Strezov, Vladimir & Evans, Tim J., 2016. "Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1126-1140.
    4. Xiu, Shuangning & Shahbazi, Abolghasem, 2012. "Bio-oil production and upgrading research: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4406-4414.
    5. Krutof, Anke & Hawboldt, Kelly, 2016. "Blends of pyrolysis oil, petroleum, and other bio-based fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 406-419.
    6. Tanneru, Sathish K. & Parapati, Divya R. & Steele, Philip H., 2014. "Pretreatment of bio-oil followed by upgrading via esterification to boiler fuel," Energy, Elsevier, vol. 73(C), pages 214-220.
    7. Shen, Dekui & Jin, Wei & Hu, Jun & Xiao, Rui & Luo, Kaihong, 2015. "An overview on fast pyrolysis of the main constituents in lignocellulosic biomass to valued-added chemicals: Structures, pathways and interactions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 761-774.
    8. Collard, François-Xavier & Blin, Joël, 2014. "A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 594-608.
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