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Durability investigation and performance study of hydrothermal synthesized platinum-multi walled carbon nanotube nanocomposite catalyst for proton exchange membrane fuel cell

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  • Mirzaei, Farokh
  • Parnian, Mohammad Javad
  • Rowshanzamir, Soosan

Abstract

In this work, a highly dispersed Pt nanoparticles on multi-walled carbon nanotubes catalyst was prepared by hydrothermal method. The synthesized Pt/MWCNT nanocomposite electrocatalyst was characterized using XRD, XRF, FESEM, TEM, and EDX. In the first step, the electrochemical activity and stability of the Pt/MWCNT and Pt/C catalysts were investigated in half cell condition using cyclic voltammetry for 4000 cycles. The Pt/C catalyst showed no activity after 2000 potential cycles, conversely, the Pt/MWCNT catalyst was more active after a potential cycling of 4000 cycles. The cyclic voltammetry results of the first, 1000th, 2000th, 3000th, and 4000th cycle for synthesized Pt/MWCNTs and commercial Pt/C catalysts showed the Pt/MWCNTs was more stable. Then, the membrane electrode assemblies (MEAs) were fabricated for each catalyst. The accelerated durability test (ADT) was done for the MEAs in the high potential operation in the fuel cell test station. The morphology of the fabricated MEAs was determined by FESEM before and after the accelerated degradation test. The polarization test, impedance, and cyclic voltammetry results for MEAs before and after degradation test in fuel cell test station were reported and the results showed the synthesized Pt/MWCNT is more stable catalyst than commercial Pt/C.

Suggested Citation

  • Mirzaei, Farokh & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2017. "Durability investigation and performance study of hydrothermal synthesized platinum-multi walled carbon nanotube nanocomposite catalyst for proton exchange membrane fuel cell," Energy, Elsevier, vol. 138(C), pages 696-705.
    • Handle: RePEc:eee:energy:v:138:y:2017:i:c:p:696-705
    DOI: 10.1016/j.energy.2017.07.098
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    4. Ji, Zhaoqi & Perez-Page, Maria & Chen, Jianuo & Rodriguez, Romeo Gonzalez & Cai, Rongsheng & Haigh, Sarah J. & Holmes, Stuart M., 2021. "A structured catalyst support combining electrochemically exfoliated graphene oxide and carbon black for enhanced performance and durability in low-temperature hydrogen fuel cells," Energy, Elsevier, vol. 226(C).
    5. Taner, Tolga, 2018. "Energy and exergy analyze of PEM fuel cell: A case study of modeling and simulations," Energy, Elsevier, vol. 143(C), pages 284-294.
    6. V., Vijayalekshmi & Khastgir, Dipak, 2018. "Fabrication and comprehensive investigation of physicochemical and electrochemical properties of chitosan-silica supported silicotungstic acid nanocomposite membranes for fuel cell applications," Energy, Elsevier, vol. 142(C), pages 313-330.
    7. Yazmín Yorely Rivera-Lugo & Kevin Isaac Pérez-Muñoz & Balter Trujillo-Navarrete & Carolina Silva-Carrillo & Edgar Alonso Reynoso-Soto & Julio Cesar Calva Yañez & Shui Wai Lin & José Roberto Flores-Her, 2020. "PtPd Hybrid Composite Catalysts as Cathodes for Proton Exchange Membrane Fuel Cells," Energies, MDPI, vol. 13(2), pages 1-12, January.
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