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Optimization of the catalyst loading for the direct borohydride fuel cell

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  • Boyacı San, Fatma Gül
  • İyigün Karadağ, Çiğdem
  • Okur, Osman
  • Okumuş, Emin

Abstract

Direct borohydride fuel cells (DBFC) are considered as attractive energy suppliers because of their high electrochemical activity, open circuit potential, energy storage capacity, and power performance at ambient temperature. For the successful commercialization of the DBFCs, cost effective and high performance cells should be produced. In this study, the analysis and optimization of the DBFC operation conditions are carried out with Design Expert software central composite tool. Power density is chosen as a response (dependent) parameter and cell temperature, borohydride concentration, anode and cathode flow rates and catalyst loading are chosen as independent parameters. Based on ANOVA (analysis of variance) analyses, the maximum power density of 108.5 mW cm−2 is obtained at cell temperature of 79.8 °C, borohydride concentration of 1.5 M, anode flow rate of 5 cm3 min−1, cathode flow rate of 0.1 dm3 min−1and PtRu/C catalyst loading of 0.7 mg cm−2.

Suggested Citation

  • Boyacı San, Fatma Gül & İyigün Karadağ, Çiğdem & Okur, Osman & Okumuş, Emin, 2016. "Optimization of the catalyst loading for the direct borohydride fuel cell," Energy, Elsevier, vol. 114(C), pages 214-224.
    • Handle: RePEc:eee:energy:v:114:y:2016:i:c:p:214-224
    DOI: 10.1016/j.energy.2016.07.158
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    Cited by:

    1. Hosseini, M.G. & Mahmoodi, R. & Sadeghi Amjadi, M., 2017. "Carbon supported Ni1Pt1 nanocatalyst as superior electrocatalyst with increased power density in direct borohydride-hydrogen peroxide and investigation of cell impedance at different temperatures and ," Energy, Elsevier, vol. 131(C), pages 137-148.
    2. El-Hay, Enas A. & El-Hameed, Mohamed A. & El-Fergany, Attia A., 2018. "Performance enhancement of autonomous system comprising proton exchange membrane fuel cells and switched reluctance motor," Energy, Elsevier, vol. 163(C), pages 699-711.

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