IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v89y2015icp500-510.html
   My bibliography  Save this article

Platinum–boron doped graphene intercalated by carbon black for cathode catalyst in proton exchange membrane fuel cell

Author

Listed:
  • Yang, H.N.
  • Lee, D.C.
  • Park, K.W.
  • Kim, W.J.

Abstract

In order to enhance the electrochemical properties, especially durability and cell performance in proton exchange membrane fuel cell, electron deficient boron is doped into graphene, followed by deposition of Pt nanoparticles. Successful synthesis of Pt-boron doped graphene (Pt–B–Gr) by pyrolytic process is confirmed by X-ray diffraction, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, Raman spectroscopy and Transmission electron microscopy analyses. Pt–B–Gr is intercalated by different amount of CB (carbon black) based on Pt–B–Gr/CBx (x = 0.0, 0.2, 0.3, 0.4) and applied to cathode in proton exchange membrane fuel cell. The ECSA (electrochemical active surface area) is increased with CB content up to 30 wt.% of Pt–B–Gr from 21.4 to 33.6 m2 g−1 beyond which it is rather slightly decreased to 29.6 m2 g−1. The ADT (accelerated durability test) is conducted where the ECSA is compared at every 400 cycles up to 1200 cycles for durability. The result exhibits that boron doping into graphene significantly enhances the durability. It might be attributed to more tight binding between Pt and B due to the electron transfer from graphene to boron. The cell performance is enhanced and it is attributed to the combined effect of B-doping and intercalation.

Suggested Citation

  • Yang, H.N. & Lee, D.C. & Park, K.W. & Kim, W.J., 2015. "Platinum–boron doped graphene intercalated by carbon black for cathode catalyst in proton exchange membrane fuel cell," Energy, Elsevier, vol. 89(C), pages 500-510.
    • Handle: RePEc:eee:energy:v:89:y:2015:i:c:p:500-510
    DOI: 10.1016/j.energy.2015.06.019
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544215007306
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2015.06.019?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chou, Chang-Chen & Liu, Cheng-Hong & Chen, Bing-Hung, 2014. "Effects of reduction temperature and pH value of polyol process on reduced graphene oxide supported Pt electrocatalysts for oxygen reduction reaction," Energy, Elsevier, vol. 70(C), pages 231-238.
    2. Avasarala, Bharat & Haldar, Pradeep, 2013. "Durability and degradation mechanism of titanium nitride based electrocatalysts for PEM (proton exchange membrane) fuel cell applications," Energy, Elsevier, vol. 57(C), pages 545-553.
    3. Flamant, Gilles & Robert, Jean François & Marty, Stephan & Gineste, Jean Michel & Giral, Joseph & Rivoire, Bruno & Laplaze, Daniel, 2004. "Solar reactor scaling up:," Energy, Elsevier, vol. 29(5), pages 801-809.
    4. Lee, Seul-Yi & Kim, Byung-Ju & Park, Soo-Jin, 2014. "Influence of H2O2 treatment on electrochemical activity of mesoporous carbon-supported Pt–Ru catalysts," Energy, Elsevier, vol. 66(C), pages 70-76.
    5. Esmaeilifar, A. & Rowshanzamir, S. & Eikani, M.H. & Ghazanfari, E., 2010. "Synthesis methods of low-Pt-loading electrocatalysts for proton exchange membrane fuel cell systems," Energy, Elsevier, vol. 35(9), pages 3941-3957.
    6. Wang, Kai & Li, Liwei & Zhang, Tiezhu & Liu, Zaifei, 2014. "Nitrogen-doped graphene for supercapacitor with long-term electrochemical stability," Energy, Elsevier, vol. 70(C), pages 612-617.
    7. González Palencia, Juan C. & Furubayashi, Takaaki & Nakata, Toshihiko, 2012. "Energy use and CO2 emissions reduction potential in passenger car fleet using zero emission vehicles and lightweight materials," Energy, Elsevier, vol. 48(1), pages 548-565.
    8. Jhan, Jing-Yi & Huang, Yu-Wei & Hsu, Chun-Han & Teng, Hsisheng & Kuo, Daniel & Kuo, Ping-Lin, 2013. "Three-dimensional network of graphene grown with carbon nanotubes as carbon support for fuel cells," Energy, Elsevier, vol. 53(C), pages 282-287.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    2. Pan, Siyu & Cai, Zhuang & Yang, Liu & Tang, Bo & Xu, Xin & Chen, Hun & Ran, Lingling & Jing, Baojian & Zou, Jinlong, 2018. "Exposure of sufficient edge sites on well-crystallized MoSe2 induced by nitrogen doping (Mo−Nx) for Pt: Enhanced co-catalytic activity and methanol tolerance for oxygen reduction," Energy, Elsevier, vol. 159(C), pages 11-20.
    3. Han, Chaoling & Chen, Zhenqian, 2021. "Study on the synergism of thermal transport and electrochemical of PEMFC based on N, P co-doped graphene substrate electrode," Energy, Elsevier, vol. 214(C).
    4. Dasari, Bhagya Lakshmi & Nouri, Jamshid M. & Brabazon, Dermot & Naher, Sumsun, 2017. "Graphene and derivatives – Synthesis techniques, properties and their energy applications," Energy, Elsevier, vol. 140(P1), pages 766-778.
    5. Kiyani, Roya & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Nitrogen doped graphene supported palladium-cobalt as a promising catalyst for methanol oxidation reaction: Synthesis, characterization and electrocatalytic performance," Energy, Elsevier, vol. 113(C), pages 1162-1173.
    6. Beltrán-Gastélum, M. & Salazar-Gastélum, M.I. & Flores-Hernández, J.R. & Botte, G.G. & Pérez-Sicairos, S. & Romero-Castañon, T. & Reynoso-Soto, E. & Félix-Navarro, R.M., 2019. "Pt-Au nanoparticles on graphene for oxygen reduction reaction: Stability and performance on proton exchange membrane fuel cell," Energy, Elsevier, vol. 181(C), pages 1225-1234.
    7. Ji, Zhaoqi & Perez-Page, Maria & Chen, Jianuo & Rodriguez, Romeo Gonzalez & Cai, Rongsheng & Haigh, Sarah J. & Holmes, Stuart M., 2021. "A structured catalyst support combining electrochemically exfoliated graphene oxide and carbon black for enhanced performance and durability in low-temperature hydrogen fuel cells," Energy, Elsevier, vol. 226(C).
    8. Yazmín Yorely Rivera-Lugo & Kevin Isaac Pérez-Muñoz & Balter Trujillo-Navarrete & Carolina Silva-Carrillo & Edgar Alonso Reynoso-Soto & Julio Cesar Calva Yañez & Shui Wai Lin & José Roberto Flores-Her, 2020. "PtPd Hybrid Composite Catalysts as Cathodes for Proton Exchange Membrane Fuel Cells," Energies, MDPI, vol. 13(2), pages 1-12, January.
    9. Liu, Zhenning & Li, Zhiyuan & Ma, Jian & Dong, Xu & Ku, Wen & Wang, Mi & Sun, Hang & Liang, Song & Lu, Guolong, 2018. "Nitrogen and cobalt-doped porous biocarbon materials derived from corn stover as efficient electrocatalysts for aluminum-air batteries," Energy, Elsevier, vol. 162(C), pages 453-459.
    10. Yang, H.N. & Lee, W.H. & Choi, B.S. & Ko, Y.D. & Yi, S.C. & Kim, W.J., 2017. "Self-humidifying Pt-C/Pt-TiO2 dual-catalyst electrode membrane assembly for proton-exchange membrane fuel cells," Energy, Elsevier, vol. 120(C), pages 12-19.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mirzaei, Farokh & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2017. "Durability investigation and performance study of hydrothermal synthesized platinum-multi walled carbon nanotube nanocomposite catalyst for proton exchange membrane fuel cell," Energy, Elsevier, vol. 138(C), pages 696-705.
    2. Chou, Chang-Chen & Liu, Cheng-Hong & Chen, Bing-Hung, 2014. "Effects of reduction temperature and pH value of polyol process on reduced graphene oxide supported Pt electrocatalysts for oxygen reduction reaction," Energy, Elsevier, vol. 70(C), pages 231-238.
    3. Li, Li & Zheng, Keqing & Ni, Meng & Leung, Michael K.H. & Xuan, Jin, 2015. "Partial modification of flow-through porous electrodes in microfluidic fuel cell," Energy, Elsevier, vol. 88(C), pages 563-571.
    4. Ismail, M.S. & Ingham, D.B. & Ma, L. & Hughes, K.J. & Pourkashanian, M., 2017. "Effects of catalyst agglomerate shape in polymer electrolyte fuel cells investigated by a multi-scale modelling framework," Energy, Elsevier, vol. 122(C), pages 420-430.
    5. Roudbari, Mohsen Najafi & Ojani, Reza & Raoof, Jahan Bakhsh, 2019. "Performance improvement of polymer fuel cell by simultaneously inspection of catalyst loading, catalyst content and ionomer using home-made cathodic half-cell and response surface method," Energy, Elsevier, vol. 173(C), pages 151-161.
    6. Rivera-Lugo, Yazmín Y. & Salazar-Gastélum, Moisés I. & López-Rosas, Deisly M. & Reynoso-Soto, Edgar A. & Pérez-Sicairos, Sergio & Velraj, Samgopiraj & Flores-Hernández, José R. & Félix-Navarro, Rosa M, 2018. "Effect of template, reaction time and platinum concentration in the synthesis of PtCu/CNT catalyst for PEMFC applications," Energy, Elsevier, vol. 148(C), pages 561-570.
    7. Lee, W.H. & Yang, H.N. & Park, K.W. & Choi, B.S. & Yi, S.C. & Kim, W.J., 2016. "Synergistic effect of boron/nitrogen co-doping into graphene and intercalation of carbon black for Pt-BCN-Gr/CB hybrid catalyst on cell performance of polymer electrolyte membrane fuel cell," Energy, Elsevier, vol. 96(C), pages 314-324.
    8. Kakaei, Karim & Gharibi, Hussien, 2014. "Palladium nanoparticle catalysts synthesis on graphene in sodium dodecyl sulfate for oxygen reduction reaction," Energy, Elsevier, vol. 65(C), pages 166-171.
    9. Stoševski, Ivan & Krstić, Jelena & Milikić, Jadranka & Šljukić, Biljana & Kačarević-Popović, Zorica & Mentus, Slavko & Miljanić, Šćepan, 2016. "Radiolitically synthesized nano Ag/C catalysts for oxygen reduction and borohydride oxidation reactions in alkaline media, for potential applications in fuel cells," Energy, Elsevier, vol. 101(C), pages 79-90.
    10. Sahoo, Madhumita & Ramaprabhu, S., 2017. "Nitrogen and sulfur co-doped porous carbon – is an efficient electrocatalyst as platinum or a hoax for oxygen reduction reaction in acidic environment PEM fuel cell?," Energy, Elsevier, vol. 119(C), pages 1075-1083.
    11. Cox, Brian & Bauer, Christian & Mendoza Beltran, Angelica & van Vuuren, Detlef P. & Mutel, Christopher L., 2020. "Life cycle environmental and cost comparison of current and future passenger cars under different energy scenarios," Applied Energy, Elsevier, vol. 269(C).
    12. Poder, Thomas G. & He, Jie, 2017. "Willingness to pay for a cleaner car: The case of car pollution in Quebec and France," Energy, Elsevier, vol. 130(C), pages 48-54.
    13. Kuzmenko, Volodymyr & Naboka, Olga & Haque, Mazharul & Staaf, Henrik & Göransson, Gert & Gatenholm, Paul & Enoksson, Peter, 2015. "Sustainable carbon nanofibers/nanotubes composites from cellulose as electrodes for supercapacitors," Energy, Elsevier, vol. 90(P2), pages 1490-1496.
    14. Raoof, Jahan-Bakhsh & Hosseini, Sayed Reza & Ojani, Reza & Mandegarzad, Sakineh, 2015. "MOF-derived Cu/nanoporous carbon composite and its application for electro-catalysis of hydrogen evolution reaction," Energy, Elsevier, vol. 90(P1), pages 1075-1081.
    15. Shaari, N. & Kamarudin, S.K., 2017. "Graphene in electrocatalyst and proton conductiong membrane in fuel cell applications: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 862-870.
    16. Meng, Jinhao & Cai, Lei & Stroe, Daniel-Ioan & Luo, Guangzhao & Sui, Xin & Teodorescu, Remus, 2019. "Lithium-ion battery state-of-health estimation in electric vehicle using optimized partial charging voltage profiles," Energy, Elsevier, vol. 185(C), pages 1054-1062.
    17. Ma, Mina & Wang, Yu & Duan, Qiangling & Wu, Tangqin & Sun, Jinhua & Wang, Qingsong, 2018. "Fault detection of the connection of lithium-ion power batteries in series for electric vehicles based on statistical analysis," Energy, Elsevier, vol. 164(C), pages 745-756.
    18. Ribau, João P. & Sousa, João M.C. & Silva, Carla M., 2015. "Reducing the carbon footprint of urban bus fleets using multi-objective optimization," Energy, Elsevier, vol. 93(P1), pages 1089-1104.
    19. Rahnavard, Aylin & Rowshanzamir, Soosan & Parnian, Mohammad Javad & Amirkhanlou, Gholam Reza, 2015. "The effect of sulfonated poly (ether ether ketone) as the electrode ionomer for self-humidifying nanocomposite proton exchange membrane fuel cells," Energy, Elsevier, vol. 82(C), pages 746-757.
    20. Miao, Fujun & Shao, Changlu & Li, Xinghua & Lu, Na & Wang, Kexin & Zhang, Xin & Liu, Yichun, 2016. "Polyaniline-coated electrospun carbon nanofibers with high mass loading and enhanced capacitive performance as freestanding electrodes for flexible solid-state supercapacitors," Energy, Elsevier, vol. 95(C), pages 233-241.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:89:y:2015:i:c:p:500-510. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.