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Key parameters of active layers affecting proton exchange membrane (PEM) fuel cell performance

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  • Thepkaew, Jarupuk
  • Therdthianwong, Apichai
  • Therdthianwong, Supaporn

Abstract

The 2n full factorial design was applied to identify the key parameters of the active layer affecting the performance of a proton exchange membrane (PEM) fuel cell. Three main selected parameters were considered: carbon-type (Vulcan XC 72R and Black Pearls 2000 conducting furnace blacks, Cabot Corporation Boston, MA), Pt loading (0.1 and 0.5mg/cm2), and Nafion™ sulfonic acid fluoropolymer (Du Pont de Nemours, Wilmington, DE) ionomer content (10% and 60%) for variables A, B, and C, respectively. The results from full factorial analysis indicated that the key factors affecting the exchange current density or activation loss were Pt loading whereas the key factors controlling the resistance due to ohmic loss were Nafion content and carbon type. In addition, there are the interactions between these parameters controlling the thin-film active layer performance, especially the interaction of carbon type and Nafion content. From cyclic voltammograms and cell performance testing, a Nafion content of 30% in a catalyst layer consisting of 0.5mg/cm2 Pt on Vulcan XC 72R is optimal.

Suggested Citation

  • Thepkaew, Jarupuk & Therdthianwong, Apichai & Therdthianwong, Supaporn, 2008. "Key parameters of active layers affecting proton exchange membrane (PEM) fuel cell performance," Energy, Elsevier, vol. 33(12), pages 1794-1800.
    • Handle: RePEc:eee:energy:v:33:y:2008:i:12:p:1794-1800
    DOI: 10.1016/j.energy.2008.08.008
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    References listed on IDEAS

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    1. Therdthianwong, Apichai & Manomayidthikarn, Phochan & Therdthianwong, Supaporn, 2007. "Investigation of membrane electrode assembly (MEA) hot-pressing parameters for proton exchange membrane fuel cell," Energy, Elsevier, vol. 32(12), pages 2401-2411.
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    1. Afra, Mehran & Nazari, Mohsen & Kayhani, Mohammad Hasan & Sharifpur, M. & Meyer, J.P., 2019. "3D experimental visualization of water flooding in proton exchange membrane fuel cells," Energy, Elsevier, vol. 175(C), pages 967-977.
    2. Rahnavard, Aylin & Rowshanzamir, Soosan & Parnian, Mohammad Javad & Amirkhanlou, Gholam Reza, 2015. "The effect of sulfonated poly (ether ether ketone) as the electrode ionomer for self-humidifying nanocomposite proton exchange membrane fuel cells," Energy, Elsevier, vol. 82(C), pages 746-757.
    3. Mirzaei, Farokh & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2017. "Durability investigation and performance study of hydrothermal synthesized platinum-multi walled carbon nanotube nanocomposite catalyst for proton exchange membrane fuel cell," Energy, Elsevier, vol. 138(C), pages 696-705.
    4. Boyaci San, Fatma Gül & Isik-Gulsac, Isil & Okur, Osman, 2013. "Analysis of the polymer composite bipolar plate properties on the performance of PEMFC (polymer electrolyte membrane fuel cells) by RSM (response surface methodology)," Energy, Elsevier, vol. 55(C), pages 1067-1075.
    5. Huang, Yu-Xian & Cheng, Chin-Hsiang & Wang, Xiao-Dong & Jang, Jiin-Yuh, 2010. "Effects of porosity gradient in gas diffusion layers on performance of proton exchange membrane fuel cells," Energy, Elsevier, vol. 35(12), pages 4786-4794.
    6. Huang, Zhen-Ming & Su, Ay & Liu, Ying-Chieh, 2013. "Hydrogen generator system using Ru catalyst for PEMFC (proton exchange membrane fuel cell) applications," Energy, Elsevier, vol. 51(C), pages 230-236.
    7. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    8. Laoun, Brahim & Kasat, Harshal A. & Ahmad, Riaz & Kannan, Arunachala M., 2018. "Gas diffusion layer development using design of experiments for the optimization of a proton exchange membrane fuel cell performance," Energy, Elsevier, vol. 151(C), pages 689-695.
    9. Xing, Lei & Mamlouk, Mohamed & Scott, Keith, 2013. "A two dimensional agglomerate model for a proton exchange membrane fuel cell," Energy, Elsevier, vol. 61(C), pages 196-210.
    10. San Martin, J.I. & Zamora, I. & San Martin, J.J. & Aperribay, V. & Torres, E. & Eguia, P., 2010. "Influence of the rated power in the performance of different proton exchange membrane (PEM) fuel cells," Energy, Elsevier, vol. 35(5), pages 1898-1907.
    11. Boyacı San, Fatma Gül & Okur, Osman & İyigün Karadağ, Çiğdem & Isik-Gulsac, Isil & Okumuş, Emin, 2014. "Evaluation of operating conditions on DBFC (direct borohydride fuel cell) performance with PtRu anode catalyst by response surface method," Energy, Elsevier, vol. 71(C), pages 160-169.
    12. Gao, Y. & Sun, G.Q. & Wang, S.L. & Zhu, S., 2010. "Carbon nanotubes based gas diffusion layers in direct methanol fuel cells," Energy, Elsevier, vol. 35(3), pages 1455-1459.
    13. Sayadi, Parvin & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Study of hydrogen crossover and proton conductivity of self-humidifying nanocomposite proton exchange membrane based on sulfonated poly (ether ether ketone)," Energy, Elsevier, vol. 94(C), pages 292-303.
    14. Ren, Zhijun & Zhang, Dongming & Wang, Zaiyi, 2012. "Stacks with TiN/titanium as the bipolar plate for PEMFCs," Energy, Elsevier, vol. 48(1), pages 577-581.
    15. Gong, Wenyin & Cai, Zhihua, 2013. "Accelerating parameter identification of proton exchange membrane fuel cell model with ranking-based differential evolution," Energy, Elsevier, vol. 59(C), pages 356-364.
    16. Lin, Rui & Wang, Hong & Zhu, Yu, 2021. "Optimizing the structural design of cathode catalyst layer for PEM fuel cells for improving mass-specific power density," Energy, Elsevier, vol. 221(C).
    17. Fofana, Daouda & Natarajan, Sadesh Kumar & Hamelin, Jean & Benard, Pierre, 2014. "Low platinum, high limiting current density of the PEMFC (proton exchange membrane fuel cell) based on multilayer cathode catalyst approach," Energy, Elsevier, vol. 64(C), pages 398-403.
    18. Zhiani, Mohammad & Majidi, Somayeh & Silva, Valter Bruno & Gharibi, Hussein, 2016. "Comparison of the performance and EIS (electrochemical impedance spectroscopy) response of an activated PEMFC (proton exchange membrane fuel cell) under low and high thermal and pressure stresses," Energy, Elsevier, vol. 97(C), pages 560-567.
    19. Alipour Moghaddam, Jafar & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2018. "Preparation, characterization, and electrochemical properties investigation of recycled proton exchange membrane for fuel cell applications," Energy, Elsevier, vol. 161(C), pages 699-709.

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