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Reforming of diesel and jet fuel for fuel cells on a systems level: Steady-state and transient operation

Author

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  • Samsun, Remzi Can
  • Prawitz, Matthias
  • Tschauder, Andreas
  • Meißner, Jan
  • Pasel, Joachim
  • Peters, Ralf

Abstract

The operation of fuel cell systems using liquid fuels widens the application possibilities of this promising energy conversion technology. However, systems utilizing diesel and jet fuel reforming are fairly complex and suffer from poor stability and limited dynamics. To address these challenges, this paper investigates the steady-state and transient operation of a 28 kWth fuel processor on the systems level. With the help of experiments that make use of the developed prototype, suitable operating parameters are sought to maximize the simultaneous fuel conversion in the reformer and CO conversion in the shift reactor. Furthermore, a load change strategy is developed with the aim of keeping the CO concentration at the fuel cell anode inlet below the target concentration of 1% of the wet product gas at all times. The identified parameters enable very high conversions (>99.95%) and CO concentrations even lower than the target during steady-state operation using three commercial fuels under full load. The developed load change strategy was validated during 90 min tests, including 16 load change cycles with loads between 40% and 100%. As well as providing excess steam during load change, the selection and control of optimal O2/C and H2O/C ratios and temperature levels proved to be of key importance. In order to minimize the CO concentration, it is recommended to operate the reformer at the identified parameters for each fuel and keep the shift outlet temperature between 295 and 300 °C by adjusting the water feed. The proposed fuel processor concept and the experimentally-validated operating strategies in this work can enable the successful implementation of fuel cell technology in different application areas, including auxiliary power units, remote power systems and range extenders.

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  • Samsun, Remzi Can & Prawitz, Matthias & Tschauder, Andreas & Meißner, Jan & Pasel, Joachim & Peters, Ralf, 2020. "Reforming of diesel and jet fuel for fuel cells on a systems level: Steady-state and transient operation," Applied Energy, Elsevier, vol. 279(C).
    • Handle: RePEc:eee:appene:v:279:y:2020:i:c:s0306261920313532
    DOI: 10.1016/j.apenergy.2020.115882
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    1. D.F. Chuahy, Flavio & Kokjohn, Sage L., 2017. "High efficiency dual-fuel combustion through thermochemical recovery and diesel reforming," Applied Energy, Elsevier, vol. 195(C), pages 503-522.
    2. Walluk, Mark R. & Lin, Jiefeng & Waller, Michael G. & Smith, Daniel F. & Trabold, Thomas A., 2014. "Diesel auto-thermal reforming for solid oxide fuel cell systems: Anode off-gas recycle simulation," Applied Energy, Elsevier, vol. 130(C), pages 94-102.
    3. Hanyu Chen & Xi Wang & Zhixiang Pan & Hongming Xu, 2019. "Numerical Simulation and Experimental Investigation of Diesel Fuel Reforming over a Pt/CeO 2 -Al 2 O 3 Catalyst," Energies, MDPI, vol. 12(6), pages 1-14, March.
    4. Pasel, Joachim & Samsun, Remzi Can & Tschauder, Andreas & Peters, Ralf & Stolten, Detlef, 2017. "Advances in autothermal reformer design," Applied Energy, Elsevier, vol. 198(C), pages 88-98.
    5. Peters, R. & Samsun, R.C., 2013. "Evaluation of multifunctional fuel cell systems in aviation using a multistep process analysis methodology," Applied Energy, Elsevier, vol. 111(C), pages 46-63.
    6. Wierzbicki, Teresa A. & Lee, Ivan C. & Gupta, Ashwani K., 2016. "Recent advances in catalytic oxidation and reformation of jet fuels," Applied Energy, Elsevier, vol. 165(C), pages 904-918.
    7. Samsun, Remzi Can & Pasel, Joachim & Janßen, Holger & Lehnert, Werner & Peters, Ralf & Stolten, Detlef, 2014. "Design and test of a 5kWe high-temperature polymer electrolyte fuel cell system operated with diesel and kerosene," Applied Energy, Elsevier, vol. 114(C), pages 238-249.
    8. Bizon, Nicu, 2019. "Real-time optimization strategies of Fuel Cell Hybrid Power Systems based on Load-following control: A new strategy, and a comparative study of topologies and fuel economy obtained," Applied Energy, Elsevier, vol. 241(C), pages 444-460.
    9. Krekel, Daniel & Samsun, Remzi Can & Pasel, Joachim & Prawitz, Matthias & Peters, Ralf & Stolten, Detlef, 2016. "Operating strategies for fuel processing systems with a focus on water–gas shift reactor stability," Applied Energy, Elsevier, vol. 164(C), pages 540-552.
    10. Samsun, Remzi Can & Prawitz, Matthias & Tschauder, Andreas & Pasel, Joachim & Pfeifer, Peter & Peters, Ralf & Stolten, Detlef, 2018. "An integrated diesel fuel processing system with thermal start-up for fuel cells," Applied Energy, Elsevier, vol. 226(C), pages 145-159.
    11. Xu, Xinhai & Li, Peiwen & Shen, Yuesong, 2013. "Small-scale reforming of diesel and jet fuels to make hydrogen and syngas for fuel cells: A review," Applied Energy, Elsevier, vol. 108(C), pages 202-217.
    12. Tribioli, Laura & Cozzolino, Raffaello & Chiappini, Daniele & Iora, Paolo, 2016. "Energy management of a plug-in fuel cell/battery hybrid vehicle with on-board fuel processing," Applied Energy, Elsevier, vol. 184(C), pages 140-154.
    13. Martinez, Andrew S. & Brouwer, Jacob & Samuelsen, G. Scott, 2015. "Comparative analysis of SOFC–GT freight locomotive fueled by natural gas and diesel with onboard reformation," Applied Energy, Elsevier, vol. 148(C), pages 421-438.
    14. Pregelj, Boštjan & Micor, Michał & Dolanc, Gregor & Petrovčič, Janko & Jovan, Vladimir, 2016. "Impact of fuel cell and battery size to overall system performance – A diesel fuel-cell APU case study," Applied Energy, Elsevier, vol. 182(C), pages 365-375.
    15. Ercolino, Giuliana & Ashraf, Muhammad A. & Specchia, Vito & Specchia, Stefania, 2015. "Performance evaluation and comparison of fuel processors integrated with PEM fuel cell based on steam or autothermal reforming and on CO preferential oxidation or selective methanation," Applied Energy, Elsevier, vol. 143(C), pages 138-153.
    16. Han, Gwangwoo & Lee, Sangho & Bae, Joongmyeon, 2015. "Diesel autothermal reforming with hydrogen peroxide for low-oxygen environments," Applied Energy, Elsevier, vol. 156(C), pages 99-106.
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    Cited by:

    1. Remzi Can Samsun & Matthias Prawitz & Andreas Tschauder & Stefan Weiske & Joachim Pasel & Ralf Peters, 2021. "A Compact, Self-Sustaining Fuel Cell Auxiliary Power Unit Operated on Diesel Fuel," Energies, MDPI, vol. 14(18), pages 1-28, September.
    2. Pan, Zehua & Shen, Jian & Wang, Jingyi & Xu, Xinhai & Chan, Wei Ping & Liu, Siyu & Zhou, Yexin & Yan, Zilin & Jiao, Zhenjun & Lim, Teik-Thye & Zhong, Zheng, 2022. "Thermodynamic analyses of a standalone diesel-fueled distributed power generation system based on solid oxide fuel cells," Applied Energy, Elsevier, vol. 308(C).

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