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Diesel autothermal reforming with hydrogen peroxide for low-oxygen environments

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  • Han, Gwangwoo
  • Lee, Sangho
  • Bae, Joongmyeon

Abstract

To operate fuel cells effectively in low-oxygen environments, such as in submarines and unmanned underwater vehicles, a hydrogen source with high hydrogen storage density is required. In this paper, diesel autothermal reforming (ATR) with hydrogen peroxide as an alternative oxidant is proposed as a hydrogen production method. Diesel fuel has higher hydrogen density than metal hydrides or other hydrocarbons. In addition, hydrogen peroxide can decompose into steam and oxygen, which are required for diesel ATR. Moreover, both diesel fuel and hydrogen peroxide are liquid states, enabling easy storage for submarine applications. Hydrogen peroxide exhibited the same characteristics as steam and oxygen when used as an oxidant in diesel reforming when pre-decomposition method was used. The thermodynamically calculated operating conditions were a steam-to-carbon ratio (SCR) of 3.0, an oxygen-to-carbon ratio (OCR) of 0.5, and temperatures below 700°C to account for safety issues associated with hydrogen peroxide use and exothermic reactions. Catalytic activity and stability tests over Ni–Ru (19.5–0.5wt.%)/Ce0.9Gd0.1O2−x were conducted using various diesel compounds. Furthermore, long-term diesel ATR tests were conducted for 200h using Korean commercial diesel. The degradation rate was 3.67%/100h without the production of ethylene.

Suggested Citation

  • Han, Gwangwoo & Lee, Sangho & Bae, Joongmyeon, 2015. "Diesel autothermal reforming with hydrogen peroxide for low-oxygen environments," Applied Energy, Elsevier, vol. 156(C), pages 99-106.
    • Handle: RePEc:eee:appene:v:156:y:2015:i:c:p:99-106
    DOI: 10.1016/j.apenergy.2015.06.036
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    References listed on IDEAS

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    3. Samsun, Remzi Can & Prawitz, Matthias & Tschauder, Andreas & Meißner, Jan & Pasel, Joachim & Peters, Ralf, 2020. "Reforming of diesel and jet fuel for fuel cells on a systems level: Steady-state and transient operation," Applied Energy, Elsevier, vol. 279(C).
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    6. Hafizi, A. & Rahimpour, M.R. & Hassanajili, Sh., 2016. "Hydrogen production via chemical looping steam methane reforming process: Effect of cerium and calcium promoters on the performance of Fe2O3/Al2O3 oxygen carrier," Applied Energy, Elsevier, vol. 165(C), pages 685-694.

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