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Effect of gas diffusion layer parameters on cold start of PEMFCs with metal foam flow field

Author

Listed:
  • Tao, Xingxiao
  • Sun, Kai
  • Chen, Rui
  • Li, Qifeng
  • Liu, Huaiyu
  • Zhang, Wenzhe
  • Che, Zhizhao
  • Wang, Tianyou

Abstract

Metal foam (MF) flow field has extensive potential in proton exchange membrane fuel cells (PEMFCs). Under its influences on the internal flow and heat/mass transfer in PEMFCs, the original electrode structure base on the “channel-rib” flow field could be no longer suitable. In this study, the effects of gas diffusion layer (GDL) parameters on the cold start of PEMFCs with MF flow fields are studied experimentally. We focus on the pore size distribution and hydrophobicity of the GDL and investigate their effects on the cold start performance, the cell impedance, and the cell degradation. The results show that GDLs with large pore diameter and smooth pore size gradient are helpful to enhance the cold start performance and reduce the cell degradation due to the small mass-transfer resistance and excellent water/ice-storage capacity. In addition, the cell of GDL with moderate hydrophobicity has the best cold start performance at -5 °C as it can well balance the resistance of water transfer in GDL and from CL into GDL. Below -5 °C, a stronger GDL hydrophobicity can lead to a longer cell operating time and better cell stability. This is mainly because the GDL hydrophobicity can significantly affect the reactant flow path and the internal water freezing. The results of this study provide physical insight into the electrode optimization for improving the cold start of PEMFCs with MF flow fields.

Suggested Citation

  • Tao, Xingxiao & Sun, Kai & Chen, Rui & Li, Qifeng & Liu, Huaiyu & Zhang, Wenzhe & Che, Zhizhao & Wang, Tianyou, 2024. "Effect of gas diffusion layer parameters on cold start of PEMFCs with metal foam flow field," Applied Energy, Elsevier, vol. 364(C).
    • Handle: RePEc:eee:appene:v:364:y:2024:i:c:s0306261924005695
    DOI: 10.1016/j.apenergy.2024.123186
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    References listed on IDEAS

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    1. Tiancai Ma & Weikang Lin & Yanbo Yang & Ming Cong & Zhuoping Yu & Qiongqiong Zhou, 2019. "Research on Control Algorithm of Proton Exchange Membrane Fuel Cell Cooling System," Energies, MDPI, vol. 12(19), pages 1-15, September.
    2. Wei Jiang & Ke Song & Bailin Zheng & Yongchuan Xu & Ruoshi Fang, 2020. "Study on Fast Cold Start-Up Method of Proton Exchange Membrane Fuel Cell Based on Electric Heating Technology," Energies, MDPI, vol. 13(17), pages 1-26, August.
    3. Chunjuan Shen & Sichuan Xu & Lei Pan & Yuan Gao, 2021. "A High-Efficiency Cooperative Control Strategy of Active and Passive Heating for a Proton Exchange Membrane Fuel Cell," Energies, MDPI, vol. 14(21), pages 1-11, November.
    4. Yang, Zirong & Jiao, Kui & Wu, Kangcheng & Shi, Weilong & Jiang, Shangfeng & Zhang, Longhai & Du, Qing, 2021. "Numerical investigations of assisted heating cold start strategies for proton exchange membrane fuel cell systems," Energy, Elsevier, vol. 222(C).
    5. Zhong, Di & Lin, Rui & Jiang, Zhenghua & Zhu, Yike & Liu, Dengchen & Cai, Xin & Chen, Liang, 2020. "Low temperature durability and consistency analysis of proton exchange membrane fuel cell stack based on comprehensive characterizations," Applied Energy, Elsevier, vol. 264(C).
    6. Dafalla, Ahmed Mohmed & Wei, Lin & Liao, Zihao & Guo, Jian & Jiang, Fangming, 2023. "Influence of cathode channel blockages on the cold start performance of proton exchange membrane fuel cell: A numerical study," Energy, Elsevier, vol. 263(PA).
    7. Lin, Rui & Zhong, Di & Lan, Shunbo & Guo, Rong & Ma, Yunyang & Cai, Xin, 2021. "Experimental validation for enhancement of PEMFC cold start performance: Based on the optimization of micro porous layer," Applied Energy, Elsevier, vol. 300(C).
    8. Yuan, Wei & Tang, Yong & Yang, Xiaojun & Wan, Zhenping, 2012. "Porous metal materials for polymer electrolyte membrane fuel cells – A review," Applied Energy, Elsevier, vol. 94(C), pages 309-329.
    9. Pengcheng Liu & Sichuan Xu, 2022. "Experimental Research on the Dynamic Characteristics and Voltage Uniformity of a PEMFC Stack under Subzero Temperatures," Energies, MDPI, vol. 15(9), pages 1-14, April.
    10. Knorr, Florian & Sanchez, Daniel Garcia & Schirmer, Johannes & Gazdzicki, Pawel & Friedrich, K.A., 2019. "Methanol as antifreeze agent for cold start of automotive polymer electrolyte membrane fuel cells," Applied Energy, Elsevier, vol. 238(C), pages 1-10.
    11. Huo, Sen & Cooper, Nathanial James & Smith, Travis Lee & Park, Jae Wan & Jiao, Kui, 2017. "Experimental investigation on PEM fuel cell cold start behavior containing porous metal foam as cathode flow distributor," Applied Energy, Elsevier, vol. 203(C), pages 101-114.
    12. Guozhuo Wang & Yoshio Utaka & Shixue Wang, 2020. "Effect of Dual Porous Layers with Patterned Wettability on Low-Temperature Start Performance of Polymer Electrolyte Membrane Fuel Cell," Energies, MDPI, vol. 13(14), pages 1-16, July.
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