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Applicability of the SOFC technology for coupling with biomass-gasifier systems: Short- and long-term experimental study on SOFC performance and degradation behaviour

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  • Subotić, Vanja
  • Baldinelli, Arianna
  • Barelli, Linda
  • Scharler, Robert
  • Pongratz, Gernot
  • Hochenauer, Christoph
  • Anca-Couce, Andrés

Abstract

Coupling biomass gasification with high temperature Solid Oxide Fuel Cells (SOFCs) is a promising solution to increase the share of renewables and reduce emissions. The quality of the producer gas used can, however, significantly impact the SOFC durability and reliability. The great challenge is to ensure undisturbed operation of such system and to find a trade-off between optimal SOFC operating temperature and system thermal integration, which may limit the overall efficiency. Thus, this study focuses on experimental investigation of commercial SOFC single cells of industrial size fueled with different representative producer gas compositions of industrial relevance at two relevant operating temperatures. The extensive experimental and numerical analyses performed showed that feeding SOFC with a producer gas from a downdraft gasifier, with hot gas cleaning, at an operating temperature of 750 °C represents the most favorable setting, considering system integration and the highest fuel utilization. Additionally, a 120 h long-term test was carried out, showing that a long-term operation is possible under stated operating conditions. Local degradation took place, which can be detected at an early stage using appropriate online-monitoring tools.

Suggested Citation

  • Subotić, Vanja & Baldinelli, Arianna & Barelli, Linda & Scharler, Robert & Pongratz, Gernot & Hochenauer, Christoph & Anca-Couce, Andrés, 2019. "Applicability of the SOFC technology for coupling with biomass-gasifier systems: Short- and long-term experimental study on SOFC performance and degradation behaviour," Applied Energy, Elsevier, vol. 256(C).
    • Handle: RePEc:eee:appene:v:256:y:2019:i:c:s0306261919315910
    DOI: 10.1016/j.apenergy.2019.113904
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    1. Sadeghi, M. & Mehr, A.S. & Zar, M. & Santarelli, M., 2018. "Multi-objective optimization of a novel syngas fed SOFC power plant using a downdraft gasifier," Energy, Elsevier, vol. 148(C), pages 16-31.
    2. Anis, Samsudin & Zainal, Z.A., 2011. "Tar reduction in biomass producer gas via mechanical, catalytic and thermal methods: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(5), pages 2355-2377, June.
    3. D.F. Chuahy, Flavio & Kokjohn, Sage L., 2019. "Solid oxide fuel cell and advanced combustion engine combined cycle: A pathway to 70% electrical efficiency," Applied Energy, Elsevier, vol. 235(C), pages 391-408.
    4. Perna, Alessandra & Minutillo, Mariagiovanna & Jannelli, Elio & Cigolotti, Viviana & Nam, Suk Woo & Yoon, Kyung Joong, 2018. "Performance assessment of a hybrid SOFC/MGT cogeneration power plant fed by syngas from a biomass down-draft gasifier," Applied Energy, Elsevier, vol. 227(C), pages 80-91.
    5. Ud Din, Zia & Zainal, Z.A., 2017. "The fate of SOFC anodes under biomass producer gas contaminants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 1050-1066.
    6. Azizi, Mohammad Ali & Brouwer, Jacob, 2018. "Progress in solid oxide fuel cell-gas turbine hybrid power systems: System design and analysis, transient operation, controls and optimization," Applied Energy, Elsevier, vol. 215(C), pages 237-289.
    7. Cavalli, A. & Kunze, M. & Aravind, P.V., 2018. "Cross-influence of toluene as tar model compound and HCl on Solid Oxide Fuel Cell anodes in Integrated Biomass Gasifier SOFC Systems," Applied Energy, Elsevier, vol. 231(C), pages 1-11.
    8. Shayan, E. & Zare, V. & Mirzaee, I., 2019. "On the use of different gasification agents in a biomass fueled SOFC by integrated gasifier: A comparative exergo-economic evaluation and optimization," Energy, Elsevier, vol. 171(C), pages 1126-1138.
    9. Silva-Mosqueda, Dulce María & Elizalde-Blancas, Francisco & Pumiglia, Davide & Santoni, Francesca & Boigues-Muñoz, Carlos & McPhail, Stephen J., 2019. "Intermediate temperature solid oxide fuel cell under internal reforming: Critical operating conditions, associated problems and their impact on the performance," Applied Energy, Elsevier, vol. 235(C), pages 625-640.
    10. Liu, Ming & van der Kleij, A. & Verkooijen, A.H.M. & Aravind, P.V., 2013. "An experimental study of the interaction between tar and SOFCs with Ni/GDC anodes," Applied Energy, Elsevier, vol. 108(C), pages 149-157.
    11. Jia, Junxi & Abudula, Abuliti & Wei, Liming & Sun, Baozhi & Shi, Yue, 2015. "Thermodynamic modeling of an integrated biomass gasification and solid oxide fuel cell system," Renewable Energy, Elsevier, vol. 81(C), pages 400-410.
    12. Baldinelli, Arianna & Barelli, Linda & Bidini, Gianni, 2015. "Performance characterization and modelling of syngas-fed SOFCs (solid oxide fuel cells) varying fuel composition," Energy, Elsevier, vol. 90(P2), pages 2070-2084.
    13. Subotić, Vanja & Stoeckl, Bernhard & Lawlor, Vincent & Strasser, Johannes & Schroettner, Hartmuth & Hochenauer, Christoph, 2018. "Towards a practical tool for online monitoring of solid oxide fuel cell operation: An experimental study and application of advanced data analysis approaches," Applied Energy, Elsevier, vol. 222(C), pages 748-761.
    14. Ravenni, Giulia & Sárossy, Zsuzsa & Ahrenfeldt, Jesper & Henriksen, Ulrik Birk, 2018. "Activity of chars and activated carbons for removal and decomposition of tar model compounds – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 1044-1056.
    15. Fryda, L. & Panopoulos, K.D. & Karl, J. & Kakaras, E., 2008. "Exergetic analysis of solid oxide fuel cell and biomass gasification integration with heat pipes," Energy, Elsevier, vol. 33(2), pages 292-299.
    16. Gadsbøll, Rasmus Østergaard & Vivar Garcia, Adrian & Ahrenfeldt, Jesper & Henriksen, Ulrik Birk, 2019. "Solid oxide fuel cell stack coupled with an oxygen-blown TwoStage gasifier using minimal gas cleaning," Renewable Energy, Elsevier, vol. 139(C), pages 1255-1262.
    17. Alvaro Fernandes & Joerg Brabandt & Oliver Posdziech & Ali Saadabadi & Mayra Recalde & Liyuan Fan & Eva O. Promes & Ming Liu & Theo Woudstra & Purushothaman Vellayan Aravind, 2018. "Design, Construction, and Testing of a Gasifier-Specific Solid Oxide Fuel Cell System," Energies, MDPI, vol. 11(8), pages 1-17, July.
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