IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v283y2021ics0306261920317487.html
   My bibliography  Save this article

Performance assessment and evaluation of SOC stacks designed for application in a reversible operated 150 kW rSOC power plant

Author

Listed:
  • Königshofer, Benjamin
  • Boškoski, Pavle
  • Nusev, Gjorgji
  • Koroschetz, Markus
  • Hochfellner, Martin
  • Schwaiger, Marcel
  • Juričić, Đani
  • Hochenauer, Christoph
  • Subotić, Vanja

Abstract

The coupling of renewable energy sources with reversible operated high temperature solid oxide cells (rSOC) seems to be a promising option to store and supply clean energy in the future. This work provides the results of experimental investigations on the performance of a rSOC stack as a main unit of a large-scale module installed at a real industrial power plant. In order to determine the requirements as well as to propose strategies for safe and stable operation of the large-scale module the stack was tested under system relevant gas mixtures and operational conditions. Hereby, the focus was on steam electrolysis (EC) and fuel cell (FC) operation utilizing a H2/H2O/CO/CO2/N2 gas mixture, predefined by the reformer installed within the module at the power plant. Furthermore, the alternating operation between EC and FC mode was analyzed. The comprehensive analysis of the performance of the stack includes polarization curves, electrochemical impedance spectroscopy (EIS), distribution of relaxation times (DRT), gas analysis and temperature measurements. Thus, numerous combinations of operational parameters are linked to the individual processes within the stack. During EC operation higher hydrogen partial pressures presented significantly lower diffusion losses especially at low current densities, whereby in FC mode low fuel flows presented increased concentration losses. During alternating operation, prolonged voltage stabilization periods with increasing operation time were observed. Additionally, the processes represented by the peaks calculated from the DRT showed enhanced unstable behavior and presented a significant shift towards higher frequencies compared to constant mode operation.

Suggested Citation

  • Königshofer, Benjamin & Boškoski, Pavle & Nusev, Gjorgji & Koroschetz, Markus & Hochfellner, Martin & Schwaiger, Marcel & Juričić, Đani & Hochenauer, Christoph & Subotić, Vanja, 2021. "Performance assessment and evaluation of SOC stacks designed for application in a reversible operated 150 kW rSOC power plant," Applied Energy, Elsevier, vol. 283(C).
    • Handle: RePEc:eee:appene:v:283:y:2021:i:c:s0306261920317487
    DOI: 10.1016/j.apenergy.2020.116372
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261920317487
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2020.116372?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Preininger, Michael & Stoeckl, Bernhard & Subotić, Vanja & Mittmann, Frank & Hochenauer, Christoph, 2019. "Performance of a ten-layer reversible Solid Oxide Cell stack (rSOC) under transient operation for autonomous application," Applied Energy, Elsevier, vol. 254(C).
    2. Kupecki, Jakub & Papurello, Davide & Lanzini, Andrea & Naumovich, Yevgeniy & Motylinski, Konrad & Blesznowski, Marcin & Santarelli, Massimo, 2018. "Numerical model of planar anode supported solid oxide fuel cell fed with fuel containing H2S operated in direct internal reforming mode (DIR-SOFC)," Applied Energy, Elsevier, vol. 230(C), pages 1573-1584.
    3. Subotić, Vanja & Stoeckl, Bernhard & Lawlor, Vincent & Strasser, Johannes & Schroettner, Hartmuth & Hochenauer, Christoph, 2018. "Towards a practical tool for online monitoring of solid oxide fuel cell operation: An experimental study and application of advanced data analysis approaches," Applied Energy, Elsevier, vol. 222(C), pages 748-761.
    4. Guk, Erdogan & Kim, Jung-Sik & Ranaweera, Manoj & Venkatesan, Vijay & Jackson, Lisa, 2018. "In-situ monitoring of temperature distribution in operating solid oxide fuel cell cathode using proprietary sensory techniques versus commercial thermocouples," Applied Energy, Elsevier, vol. 230(C), pages 551-562.
    5. Srikanth, S. & Heddrich, M.P. & Gupta, S. & Friedrich, K.A., 2018. "Transient reversible solid oxide cell reactor operation – Experimentally validated modeling and analysis," Applied Energy, Elsevier, vol. 232(C), pages 473-488.
    6. Subotić, Vanja & Baldinelli, Arianna & Barelli, Linda & Scharler, Robert & Pongratz, Gernot & Hochenauer, Christoph & Anca-Couce, Andrés, 2019. "Applicability of the SOFC technology for coupling with biomass-gasifier systems: Short- and long-term experimental study on SOFC performance and degradation behaviour," Applied Energy, Elsevier, vol. 256(C).
    7. Al-Masri, A. & Peksen, M. & Blum, L. & Stolten, D., 2014. "A 3D CFD model for predicting the temperature distribution in a full scale APU SOFC short stack under transient operating conditions," Applied Energy, Elsevier, vol. 135(C), pages 539-547.
    8. Frank, Matthias & Deja, Robert & Peters, Roland & Blum, Ludger & Stolten, Detlef, 2018. "Bypassing renewable variability with a reversible solid oxide cell plant," Applied Energy, Elsevier, vol. 217(C), pages 101-112.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yao, Yue & Ma, Yue & Wang, Chenpeng & Ye, Hao & Liu, Yinglong & Liu, Jiawei & Zhao, Xiaobo & Tao, Tao & Yao, Yingbang & Lu, Shengguo & Yang, Huazheng & Liang, Bo, 2022. "A cofuel channel microtubular solid oxide fuel/electrolysis cell," Applied Energy, Elsevier, vol. 327(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Preininger, Michael & Stoeckl, Bernhard & Subotić, Vanja & Mittmann, Frank & Hochenauer, Christoph, 2019. "Performance of a ten-layer reversible Solid Oxide Cell stack (rSOC) under transient operation for autonomous application," Applied Energy, Elsevier, vol. 254(C).
    2. Pongratz, G. & Subotić, V. & Schroettner, H. & Hochenauer, C. & Skrzypkiewicz, M. & Kupecki, Jakub & Anca-Couce, A. & Scharler, R., 2021. "Analysis of H2S-related short-term degradation and regeneration of anode- and electrolyte supported solid oxide fuel cells fueled with biomass steam gasifier product gas," Energy, Elsevier, vol. 218(C).
    3. Guk, Erdogan & Venkatesan, Vijay & Babar, Shumaila & Jackson, Lisa & Kim, Jung-Sik, 2019. "Parameters and their impacts on the temperature distribution and thermal gradient of solid oxide fuel cell," Applied Energy, Elsevier, vol. 241(C), pages 164-173.
    4. Zarabi Golkhatmi, Sanaz & Asghar, Muhammad Imran & Lund, Peter D., 2022. "A review on solid oxide fuel cell durability: Latest progress, mechanisms, and study tools," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).
    5. Wang, Yang & Wu, Chengru & Zhao, Siyuan & Wang, Jian & Zu, Bingfeng & Han, Minfang & Du, Qing & Ni, Meng & Jiao, Kui, 2022. "Coupling deep learning and multi-objective genetic algorithms to achieve high performance and durability of direct internal reforming solid oxide fuel cell," Applied Energy, Elsevier, vol. 315(C).
    6. Sun, Yi & Qian, Tang & Zhu, Jingdong & Zheng, Nan & Han, Yu & Xiao, Gang & Ni, Meng & Xu, Haoran, 2023. "Dynamic simulation of a reversible solid oxide cell system for efficient H2 production and power generation," Energy, Elsevier, vol. 263(PA).
    7. Wang, Chaoyang & Chen, Ming & Liu, Ming & Yan, Junjie, 2020. "Dynamic modeling and parameter analysis study on reversible solid oxide cells during mode switching transient processes," Applied Energy, Elsevier, vol. 263(C).
    8. Guk, Erdogan & Ranaweera, Manoj & Venkatesan, Vijay & Kim, Jung-Sik & Jung, WooChul, 2020. "In-situ temperature monitoring directly from cathode surface of an operating solid oxide fuel cell," Applied Energy, Elsevier, vol. 280(C).
    9. Dai, Huidong & Besser, R.S., 2022. "Understanding hydrogen sulfide impact on a portable, commercial, propane-powered solid-oxide fuel cell," Applied Energy, Elsevier, vol. 307(C).
    10. Wang, Chao & Liao, Mingzheng & Liang, Bo & Jiang, Zhiqiang & Zhong, Weilin & Chen, Ying & Luo, Xianglong & Shu, Riyang & Tian, Zhipeng & Lei, Libin, 2021. "Enhancement effect of catalyst support on indirect hydrogen production from propane partial oxidation towards commercial solid oxide fuel cell (SOFC) applications," Applied Energy, Elsevier, vol. 288(C).
    11. Zhao, Xinyue & Chen, Heng & Zheng, Qiwei & Liu, Jun & Pan, Peiyuan & Xu, Gang & Zhao, Qinxin & Jiang, Xue, 2023. "Thermo-economic analysis of a novel hydrogen production system using medical waste and biogas with zero carbon emission," Energy, Elsevier, vol. 265(C).
    12. Vitale, F. & Rispoli, N. & Sorrentino, M. & Rosen, M.A. & Pianese, C., 2021. "On the use of dynamic programming for optimal energy management of grid-connected reversible solid oxide cell-based renewable microgrids," Energy, Elsevier, vol. 225(C).
    13. Petrone, Giovanni & Zamboni, Walter & Spagnuolo, Giovanni, 2019. "An interval arithmetic-based method for parametric identification of a fuel cell equivalent circuit model," Applied Energy, Elsevier, vol. 242(C), pages 1226-1236.
    14. Zhong, Like & Yao, Erren & Zou, Hansen & Xi, Guang, 2022. "Thermodynamic and economic analysis of a directly solar-driven power-to-methane system by detailed distributed parameter method," Applied Energy, Elsevier, vol. 312(C).
    15. Frank, Matthias & Deja, Robert & Peters, Roland & Blum, Ludger & Stolten, Detlef, 2018. "Bypassing renewable variability with a reversible solid oxide cell plant," Applied Energy, Elsevier, vol. 217(C), pages 101-112.
    16. Xiao, Gang & Sun, Anwei & Liu, Hongwei & Ni, Meng & Xu, Haoran, 2023. "Thermal management of reversible solid oxide cells in the dynamic mode switching," Applied Energy, Elsevier, vol. 331(C).
    17. Zeng, Hongyu & Wang, Yuqing & Shi, Yixiang & Cai, Ningsheng & Yuan, Dazhong, 2018. "Highly thermal integrated heat pipe-solid oxide fuel cell," Applied Energy, Elsevier, vol. 216(C), pages 613-619.
    18. Xing, Xuetao & Lin, Jin & Song, Yonghua & Hu, Qiang & Zhou, You & Mu, Shujun, 2018. "Optimization of hydrogen yield of a high-temperature electrolysis system with coordinated temperature and feed factors at various loading conditions: A model-based study," Applied Energy, Elsevier, vol. 232(C), pages 368-385.
    19. Marek Skrzypkiewicz & Michal Wierzbicki & Stanislaw Jagielski & Yevgeniy Naumovich & Konrad Motylinski & Jakub Kupecki & Agnieszka Zurawska & Magdalena Kosiorek, 2022. "Influence of the Contamination of Fuel with Fly Ash Originating from Biomass Gasification on the Performance of the Anode-Supported SOFC," Energies, MDPI, vol. 15(4), pages 1-17, February.
    20. Ferreira, Victor J. & Wolff, Deidre & Hornés, Aitor & Morata, Alex & Torrell, M. & Tarancón, Albert & Corchero, Cristina, 2021. "5 kW SOFC stack via 3D printing manufacturing: An evaluation of potential environmental benefits," Applied Energy, Elsevier, vol. 291(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:283:y:2021:i:c:s0306261920317487. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.