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The fate of SOFC anodes under biomass producer gas contaminants

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  • Ud Din, Zia
  • Zainal, Z.A.

Abstract

Biomass gasification integrated with Solid Oxide Fuel Cells (SOFCs) offers a tremendous opportunity to generate highly efficient power in sustainable and environmental friendly manner. The comprehensive survey of the up-to-date literature on the influence of producer gas contaminants (particulates, alkali metals, tar, H2S and HCl) on SOFC anodes presented in this review reveals that state-of-the-art Ni/YSZ anodes are less tolerant to the contaminants and more stringent cleaning is required for them as compared to Ni/GDC anodes, while other anodes have been scarcely studied. The most striking finding is that Ni/GDC anodes seem to be rather more tolerant to the contaminants as recently understood. This remarkable opportunity needs to be further explored via detailed experiments which would lead to design the economically viable gas cleaning systems. The available gas cleaning technologies are also analysed and the most suitable cleaning options for each of the contaminant are suggested.

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  • Ud Din, Zia & Zainal, Z.A., 2017. "The fate of SOFC anodes under biomass producer gas contaminants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 1050-1066.
    • Handle: RePEc:eee:rensus:v:72:y:2017:i:c:p:1050-1066
    DOI: 10.1016/j.rser.2016.10.012
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    5. Kupecki, Jakub & Papurello, Davide & Lanzini, Andrea & Naumovich, Yevgeniy & Motylinski, Konrad & Blesznowski, Marcin & Santarelli, Massimo, 2018. "Numerical model of planar anode supported solid oxide fuel cell fed with fuel containing H2S operated in direct internal reforming mode (DIR-SOFC)," Applied Energy, Elsevier, vol. 230(C), pages 1573-1584.
    6. Subotić, Vanja & Baldinelli, Arianna & Barelli, Linda & Scharler, Robert & Pongratz, Gernot & Hochenauer, Christoph & Anca-Couce, Andrés, 2019. "Applicability of the SOFC technology for coupling with biomass-gasifier systems: Short- and long-term experimental study on SOFC performance and degradation behaviour," Applied Energy, Elsevier, vol. 256(C).
    7. Lv, Xiuqing & Chen, Huili & Zhou, Wei & Cheng, Fangqin & Li, Si-Dian & Shao, Zongping, 2020. "Direct-methane solid oxide fuel cells with an in situ formed Ni–Fe alloy composite catalyst layer over Ni–YSZ anodes," Renewable Energy, Elsevier, vol. 150(C), pages 334-341.
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