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Enhancing the performance of all-vanadium redox flow batteries by decorating carbon felt electrodes with SnO2 nanoparticles

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  • Mehboob, Sheeraz
  • Ali, Ghulam
  • Shin, Hyun-Jin
  • Hwang, Jinyeon
  • Abbas, Saleem
  • Chung, Kyung Yoon
  • Ha, Heung Yong

Abstract

An all-vanadium redox flow battery (VRFB) is an attractive candidate as an electrochemical energy storage system that uses conversion technology for applications that range from those requiring only a few kilowatts to those that must perform on a megawatt scale. Issues to be resolved, however, include problems with increasing the rates of charge/discharge (due to an increase in overpotentials) and cycling stability (due to the irreversibility of redox reactions at the electrodes as well as crossover of the vanadium species) that have prevented a broader market penetration of VRFB systems. One of the strategies to overcome these problems may be the introduction of electrocatalysts to the electrode surface to improve the reaction kinetics of the positive and negative redox couples, thus enabling the achievement of higher levels of power density. Therefore, carbon felt electrodes decorated with SnO2 nanoparticles were evaluated in this study. The performance of VRFBs at a high current density of 150 mA cm−2 with SnO2-deposited carbon felts returned an energy efficiency of 77.3%, with a corresponding increase in discharge capacity of 23.7% over a pristine electrode. Cycling stability of the system was also improved almost 2.7-fold compared with that of a pristine electrode at 50 mA cm−2. The electrocatalytic activity of SnO2 nanoparticles facilitates a reduction in the overpotentials, which enables charge/discharge reactions at faster rates, which was confirmed by cyclic voltammetry and electrochemical impedance spectroscopy. Furthermore, confirmation of the formation of clusters of SnO2 nanocrystals as well as their chemical and physical stability after cycling (as probed by various characterization techniques including synchrotron-based X-ray absorption) supports their feasibility as a stable, efficient and cost-effective electrocatalyst for use in VRFB systems.

Suggested Citation

  • Mehboob, Sheeraz & Ali, Ghulam & Shin, Hyun-Jin & Hwang, Jinyeon & Abbas, Saleem & Chung, Kyung Yoon & Ha, Heung Yong, 2018. "Enhancing the performance of all-vanadium redox flow batteries by decorating carbon felt electrodes with SnO2 nanoparticles," Applied Energy, Elsevier, vol. 229(C), pages 910-921.
  • Handle: RePEc:eee:appene:v:229:y:2018:i:c:p:910-921
    DOI: 10.1016/j.apenergy.2018.08.047
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    1. McPherson, Madeleine & Johnson, Nils & Strubegger, Manfred, 2018. "The role of electricity storage and hydrogen technologies in enabling global low-carbon energy transitions," Applied Energy, Elsevier, vol. 216(C), pages 649-661.
    2. Di Blasi, A. & Busaccaa, C. & Di Blasia, O. & Briguglioa, N. & Squadritoa, G. & Antonuccia, V., 2017. "Synthesis of flexible electrodes based on electrospun carbon nanofibers with Mn3O4 nanoparticles for vanadium redox flow battery application," Applied Energy, Elsevier, vol. 190(C), pages 165-171.
    3. Gunnar Luderer & Robert C. Pietzcker & Samuel Carrara & Harmen-Sytze de Boer & Shinichiro Fujimori & Nils Johnson & Silvana Mima & Douglas Arent, 2017. "Assessment of wind and solar power in global low-carbon energy scenarios: An introduction," Post-Print hal-01515408, HAL.
    4. Luderer, Gunnar & Pietzcker, Robert C. & Carrara, Samuel & de Boer, Harmen Sytze & Fujimori, Shinichiro & Johnson, Nils & Mima, Silvana & Arent, Douglas, 2017. "Assessment of wind and solar power in global low-carbon energy scenarios: An introduction," Energy Economics, Elsevier, vol. 64(C), pages 542-551.
    5. Flox, Cristina & Skoumal, Marcel & Rubio-Garcia, Javier & Andreu, Teresa & Morante, Juan Ramón, 2013. "Strategies for enhancing electrochemical activity of carbon-based electrodes for all-vanadium redox flow batteries," Applied Energy, Elsevier, vol. 109(C), pages 344-351.
    6. Luo, Xing & Wang, Jihong & Dooner, Mark & Clarke, Jonathan, 2015. "Overview of current development in electrical energy storage technologies and the application potential in power system operation," Applied Energy, Elsevier, vol. 137(C), pages 511-536.
    7. Wei, L. & Zhao, T.S. & Zhao, G. & An, L. & Zeng, L., 2016. "A high-performance carbon nanoparticle-decorated graphite felt electrode for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 176(C), pages 74-79.
    8. Zhang, Yunong & Liu, Le & Xi, Jingyu & Wu, Zenghua & Qiu, Xinping, 2017. "The benefits and limitations of electrolyte mixing in vanadium flow batteries," Applied Energy, Elsevier, vol. 204(C), pages 373-381.
    9. Wei, L. & Zhao, T.S. & Zeng, L. & Zhou, X.L. & Zeng, Y.K., 2016. "Copper nanoparticle-deposited graphite felt electrodes for all vanadium redox flow batteries," Applied Energy, Elsevier, vol. 180(C), pages 386-391.
    10. Wei, L. & Zhao, T.S. & Xu, Q. & Zhou, X.L. & Zhang, Z.H., 2017. "In-situ investigation of hydrogen evolution behavior in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 190(C), pages 1112-1118.
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    1. Manshu Kapoor & Anil Verma, 2022. "Technical benchmarking and challenges of kilowatt scale vanadium redox flow battery," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 11(5), September.

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