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Energy-efficient biogas reforming process to produce syngas: The enhanced methane conversion by O2

Author

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  • Chen, Xuejing
  • Jiang, Jianguo
  • Li, Kaimin
  • Tian, Sicong
  • Yan, Feng

Abstract

We report an energy-efficient biogas reforming process with high and stable methane conversions by O2 presence. During this biogas reforming process, the effects of various O2 concentrations in biogas on initial conversions and stability at various temperatures on a Ni/SiO2 catalyst were detailed investigated. In addition, theoretical energy consumption and conversions were calculated based on the Gibbs energy minimization method to compare with experimental results. Carbon formation and sintering during the reforming process were characterized by thermal gravity analysis, the Brunauer-Emmett-Teller method, X-ray diffraction, and high-resolution transmission electron microscopy to investigate the feasibility of applying this process to an inexpensive nickel catalyst. The results showed that 5% O2 in biogas improved the CH4 conversion and stability of biogas reforming. The enhancement of stability was attributed to the inhibited sintering, our first finding, and the reduced carbon deposition at the same time, which sustained a stable conversion of CH4, and proved the applicability of base Ni catalyst to this process. Higher O2 concentrations (⩾10%) in biogas resulted in severe decrease in CO2 conversion and greater H2O productivity. Our proposed biogas reforming process, with a high and stable conversion of CH4, reduced energy input, and the applicability to inexpensive base metal catalyst, offers a good choice for biogas reforming with low O2 concentrations (⩽5%) to produce syngas with high energy efficiency.

Suggested Citation

  • Chen, Xuejing & Jiang, Jianguo & Li, Kaimin & Tian, Sicong & Yan, Feng, 2017. "Energy-efficient biogas reforming process to produce syngas: The enhanced methane conversion by O2," Applied Energy, Elsevier, vol. 185(P1), pages 687-697.
    • Handle: RePEc:eee:appene:v:185:y:2017:i:p1:p:687-697
    DOI: 10.1016/j.apenergy.2016.10.114
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    References listed on IDEAS

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    1. Chen, Wei-Hsin & Lin, Shih-Cheng, 2016. "Characterization of catalytic partial oxidation of methane with carbon dioxide utilization and excess enthalpy recovery," Applied Energy, Elsevier, vol. 162(C), pages 1141-1152.
    2. Choudhary, Vasant R. & Mondal, Kartick C., 2006. "CO2 reforming of methane combined with steam reforming or partial oxidation of methane to syngas over NdCoO3 perovskite-type mixed metal-oxide catalyst," Applied Energy, Elsevier, vol. 83(9), pages 1024-1032, September.
    3. Chen, Lihong & Li, Xiaobing & Wen, Wanyu & Jia, Jingdun & Li, Guoqing & Deng, Fei, 2012. "The status, predicament and countermeasures of biomass secondary energy production in China," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 6212-6219.
    4. Antzara, Andy & Heracleous, Eleni & Lemonidou, Angeliki A., 2016. "Energy efficient sorption enhanced-chemical looping methane reforming process for high-purity H2 production: Experimental proof-of-concept," Applied Energy, Elsevier, vol. 180(C), pages 457-471.
    5. Hahn, Henning & Krautkremer, Bernd & Hartmann, Kilian & Wachendorf, Michael, 2014. "Review of concepts for a demand-driven biogas supply for flexible power generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 383-393.
    6. Singha, Rajib Kumar & Shukla, Astha & Yadav, Aditya & Adak, Shubhadeep & Iqbal, Zafar & Siddiqui, Nazia & Bal, Rajaram, 2016. "Energy efficient methane tri-reforming for synthesis gas production over highly coke resistant nanocrystalline Ni–ZrO2 catalyst," Applied Energy, Elsevier, vol. 178(C), pages 110-125.
    7. Tang, Mingchen & Xu, Long & Fan, Maohong, 2015. "Progress in oxygen carrier development of methane-based chemical-looping reforming: A review," Applied Energy, Elsevier, vol. 151(C), pages 143-156.
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    Cited by:

    1. Yan, Xiangyu & Lu, Buchu & Dong, Hao & Liu, Qibin, 2023. "Solar-promoted photo-thermal CH4 reforming with CO2 over Ni/CeO2 catalyst: Experimental and mechanism studies," Applied Energy, Elsevier, vol. 348(C).
    2. Hakawati, Rawan & Smyth, Beatrice M. & McCullough, Geoffrey & De Rosa, Fabio & Rooney, David, 2017. "What is the most energy efficient route for biogas utilization: Heat, electricity or transport?," Applied Energy, Elsevier, vol. 206(C), pages 1076-1087.
    3. Mulu, Elshaday & M'Arimi, Milton M. & Ramkat, Rose C., 2021. "A review of recent developments in application of low cost natural materials in purification and upgrade of biogas," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    4. Lu, Peng & Sun, Jian & Shen, Dongming & Yang, Ruiqin & Xing, Chuang & Lu, Chengxue & Tsubaki, Noritatsu & Shan, Shengdao, 2018. "Direct syngas conversion to liquefied petroleum gas: Importance of a multifunctional metal-zeolite interface," Applied Energy, Elsevier, vol. 209(C), pages 1-7.
    5. Choi, Dongho & Oh, Jeong-Ik & Baek, Kitae & Lee, Jechan & Kwon, Eilhann E., 2018. "Compositional modification of products from Co-Pyrolysis of chicken manure and biomass by shifting carbon distribution from pyrolytic oil to syngas using CO2," Energy, Elsevier, vol. 153(C), pages 530-538.
    6. Meng, Fanzhi & Meng, Yuan & Ju, Tongyao & Han, Siyu & Lin, Li & Jiang, Jianguo, 2022. "Research progress of aqueous amine solution for CO2 capture: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    7. Zain, Munirah Md & Mohamed, Abdul Rahman, 2018. "An overview on conversion technologies to produce value added products from CH4 and CO2 as major biogas constituents," Renewable and Sustainable Energy Reviews, Elsevier, vol. 98(C), pages 56-63.
    8. Pasel, Joachim & Samsun, Remzi Can & Tschauder, Andreas & Peters, Ralf & Stolten, Detlef, 2017. "Advances in autothermal reformer design," Applied Energy, Elsevier, vol. 198(C), pages 88-98.
    9. Ha Jin Kim & Young Nam Chun, 2020. "Conversion of Biogas to Renewable Energy by Microwave Reforming," Energies, MDPI, vol. 13(16), pages 1-11, August.
    10. Ekaterina Matus & Mikhail Kerzhentsev & Ilyas Ismagilov & Andrey Nikitin & Sergey Sozinov & Zinfer Ismagilov, 2023. "Hydrogen Production from Biogas: Development of an Efficient Nickel Catalyst by the Exsolution Approach," Energies, MDPI, vol. 16(7), pages 1-21, March.

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    More about this item

    Keywords

    Syngas; Biogas; Dry reforming; Energy efficiency; O2 effect;
    All these keywords.

    JEL classification:

    • O2 - Economic Development, Innovation, Technological Change, and Growth - - Development Planning and Policy

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