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Syngas production on a Ni-enhanced Fe2O3/Al2O3 oxygen carrier via chemical looping partial oxidation with dry reforming of methane

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  • Kang, Dohyung
  • Lim, Hyun Suk
  • Lee, Minbeom
  • Lee, Jae W.

Abstract

A novel chemical looping process was introduced by combining partial oxidation and dry reforming of methane on a cost-effective iron-based oxygen carrier to produce high-purity syngas with a H2/CO ratio of 2. The rationale for the proposed chemical looping process was substantiated with the thermodynamic data, which showed increased syngas purity and an H2/CO ratio close to 2 by introducing the CH4-CO2 mixture feed. Compared with the general chemical looping process, the calculated carbon deposition with the CO2 emission of the proposed process was dramatically decreased by using CO2 as a co-feed with CH4. Due to the exothermic heat from the oxidation reaction of the oxygen carrier, the net heat duty of the novel chemical looping process was much lower than that of the dry reforming process. To validate the thermodynamic results, a Ni entrapped Fe2O3/Al2O3 oxygen carrier was synthesized by increasing the metal-support interaction through a sol-gel route. It is striking that the formation of Ni aluminate phase in the Ni-reinforced oxygen carrier facilitated dry reforming with partial oxidation while suppressing methane decomposition. By supplying a nonstoichiometric CH4-CO2 mixture feed (CO2/CH4 ratio = 0.38) to the 1 wt% Ni-entrapped Fe2O3/Al2O3 oxygen carrier at 900 °C, an H2/CO ratio of 2.09 and high CO selectivity of 96.76% were achieved with minimized carbon deposition. These results were close to the calculated equilibrium value while a Ni-impregnated Fe2O3/Al2O3 oxygen carrier showed an increased H2/CO ratio of 2.36 with severe carbon deposition by the promoted methane decomposition. In addition, the Ni-reinforced oxygen carrier also showed stable redox activity during successive reduction and oxidation cycles.

Suggested Citation

  • Kang, Dohyung & Lim, Hyun Suk & Lee, Minbeom & Lee, Jae W., 2018. "Syngas production on a Ni-enhanced Fe2O3/Al2O3 oxygen carrier via chemical looping partial oxidation with dry reforming of methane," Applied Energy, Elsevier, vol. 211(C), pages 174-186.
    • Handle: RePEc:eee:appene:v:211:y:2018:i:c:p:174-186
    DOI: 10.1016/j.apenergy.2017.11.018
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    11. Ahn, Yuchan & Kim, Junghwan & Kwon, Joseph Sang-Il, 2020. "Optimal design of supply chain network with carbon dioxide injection for enhanced shale gas recovery," Applied Energy, Elsevier, vol. 274(C).
    12. Nadgouda, Sourabh G. & Guo, Mengqing & Tong, Andrew & Fan, L.-S., 2019. "High purity syngas and hydrogen coproduction using copper-iron oxygen carriers in chemical looping reforming process," Applied Energy, Elsevier, vol. 235(C), pages 1415-1426.
    13. Zhao, Yunlei & Jin, Bo & Luo, Xiao & Liang, Zhiwu, 2021. "Thermodynamic evaluation and experimental investigation of CaO-assisted Fe-based chemical looping reforming process for syngas production," Applied Energy, Elsevier, vol. 288(C).
    14. Fredrik Hildor & Tobias Mattisson & Carl Linderholm & Henrik Leion, 2023. "Metal impregnation on steel converter slag as an oxygen carrier," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 13(4), pages 509-519, August.
    15. Gaber, Christian & Demuth, Martin & Prieler, René & Schluckner, Christoph & Schroettner, Hartmuth & Fitzek, Harald & Hochenauer, Christoph, 2019. "Experimental investigation of thermochemical regeneration using oxy-fuel exhaust gases," Applied Energy, Elsevier, vol. 236(C), pages 1115-1124.
    16. Jalali, Ramin & Rezaei, Mehran & Nematollahi, Behzad & Baghalha, Morteza, 2020. "Preparation of Ni/MeAl2O4-MgAl2O4 (Me=Fe, Co, Ni, Cu, Zn, Mg) nanocatalysts for the syngas production via combined dry reforming and partial oxidation of methane," Renewable Energy, Elsevier, vol. 149(C), pages 1053-1067.
    17. Chein, Rei-Yu & Hsu, Wen-Huai, 2019. "Thermodynamic analysis of syngas production via chemical looping dry reforming of methane," Energy, Elsevier, vol. 180(C), pages 535-547.
    18. Shuai, Yong & Zhang, Hao & Guene Lougou, Bachirou & Jiang, Boshu & Mustafa, Azeem & Wang, Chi-Hwa & Wang, Fuqiang & Zhao, Jiupeng, 2021. "Solar-driven thermochemical redox cycles of ZrO2 supported NiFe2O4 for CO2 reduction into chemical energy," Energy, Elsevier, vol. 223(C).
    19. Siang, T.J. & Jalil, A.A. & Abdulrasheed, A.A. & Hambali, H.U. & Nabgan, Walid, 2020. "Thermodynamic equilibrium study of altering methane partial oxidation for Fischer–Tropsch synfuel production," Energy, Elsevier, vol. 198(C).
    20. Abdulrasheed, Abdulrahman & Jalil, Aishah Abdul & Gambo, Yahya & Ibrahim, Maryam & Hambali, Hambali Umar & Shahul Hamid, Muhamed Yusuf, 2019. "A review on catalyst development for dry reforming of methane to syngas: Recent advances," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 175-193.

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