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Tuning dry reforming of methane for F-T syntheses: A thermodynamic approach

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  • Cao, Pengfei
  • Adegbite, Stephen
  • Zhao, Haitao
  • Lester, Edward
  • Wu, Tao

Abstract

In this research, a thermodynamic equilibrium model was established using FactSage to study the way to tune H2/CO ratio of syngas produced via dry (CO2) reforming of methane (DRM) for various F-T syntheses aiming at eliminating the use of a water–gas-shift unit. The effects of operating conditions, such as temperature, pressure and CH4/CO2 mole ratio, on CH4 and CO2 conversion, H2 and CO yield, and solid carbon yield in DRM were investigated. These operating conditions were studied in a wide range, i.e., 550–1200°C for temperature, 0.05–5MPa for pressure and 0.5–2 for CH4/CO2 mole ratio. The results showed that lower CH4/CO2 ratios favoured high CH4 conversion and CO selectivity, but hampered CO2 conversion and H2 selectivity. However, the increase in pressure hindered CH4 conversion, CO2 conversion, H2 selectivity and CO selectivity except for carbon yield. Since the deactivation of catalyst associated with coke formation is the major obstacle for the industrialization of DRM process, a carbon-free regime of DRM was identified as CH4/CO2 mole ratio=1 and pressure=0.1MPa and temperature >1000°C. Although the H2/CO ratio could be adjusted by adjusting CH4/CO2 mole ratio and/or pressure to satisfy the requirements of different F-T processes, the adjustment of CH4/CO2 mole ratio was found to be a more efficient way of tuning H2/CO mole ratio than adjusting operating pressure. The dependence of H2/CO ratio in syngas on operating conditions of the DRM process was also revealed in this research. With the assistance of this relationship, optimal operating conditions for DRM could be quickly determined based on the required H2/CO mole ratio for various typical F-T processes. It is shown that when the operating temperature of DRM was raised to over 700°C, the H2/CO ratio obtained at CH4/CO2≤1 and P=0.1MPa was preferable for the synthesis of olefins, heavy hydrocarbons and oxygenated compounds. Otherwise the syngas was more suitable for the production of alkanes (C1–C5).

Suggested Citation

  • Cao, Pengfei & Adegbite, Stephen & Zhao, Haitao & Lester, Edward & Wu, Tao, 2018. "Tuning dry reforming of methane for F-T syntheses: A thermodynamic approach," Applied Energy, Elsevier, vol. 227(C), pages 190-197.
    • Handle: RePEc:eee:appene:v:227:y:2018:i:c:p:190-197
    DOI: 10.1016/j.apenergy.2017.08.007
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    1. Shu, Gequn & Shi, Lingfeng & Tian, Hua & Li, Xiaoya & Huang, Guangdai & Chang, Liwen, 2016. "An improved CO2-based transcritical Rankine cycle (CTRC) used for engine waste heat recovery," Applied Energy, Elsevier, vol. 176(C), pages 171-182.
    2. Hu, Yukun & Yan, Jinyue & Li, Hailong, 2012. "Effects of flue gas recycle on oxy-coal power generation systems," Applied Energy, Elsevier, vol. 97(C), pages 255-263.
    3. Atsonios, Konstantinos & Kougioumtzis, Michael-Alexander & D. Panopoulos, Kyriakos & Kakaras, Emmanuel, 2015. "Alternative thermochemical routes for aviation biofuels via alcohols synthesis: Process modeling, techno-economic assessment and comparison," Applied Energy, Elsevier, vol. 138(C), pages 346-366.
    4. Usman, Muhammad & Wan Daud, W.M.A. & Abbas, Hazzim F., 2015. "Dry reforming of methane: Influence of process parameters—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 45(C), pages 710-744.
    5. Jang, Won-Jun & Jeong, Dae-Woon & Shim, Jae-Oh & Kim, Hak-Min & Roh, Hyun-Seog & Son, In Hyuk & Lee, Seung Jae, 2016. "Combined steam and carbon dioxide reforming of methane and side reactions: Thermodynamic equilibrium analysis and experimental application," Applied Energy, Elsevier, vol. 173(C), pages 80-91.
    6. Dutta, Champa Bati & Das, Debasish Kumar, 2016. "Does disaggregated CO2 emission matter for growth? Evidence from thirty countries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 66(C), pages 825-833.
    7. Luu, Minh Tri & Milani, Dia & Sharma, Manish & Zeaiter, Joseph & Abbas, Ali, 2016. "Model-based analysis of CO2 revalorization for di-methyl ether synthesis driven by solar catalytic reforming," Applied Energy, Elsevier, vol. 177(C), pages 863-878.
    8. Jiang, Dongyue & Yang, Wenming & Tang, Aikun, 2016. "A refractory selective solar absorber for high performance thermochemical steam reforming," Applied Energy, Elsevier, vol. 170(C), pages 286-292.
    9. Yu, Tao & Yuan, Qinyuan & Lu, Jianfeng & Ding, Jing & Lu, Yanling, 2017. "Thermochemical storage performances of methane reforming with carbon dioxide in tubular and semi-cavity reactors heated by a solar dish system," Applied Energy, Elsevier, vol. 185(P2), pages 1994-2004.
    10. Antzara, Andy & Heracleous, Eleni & Lemonidou, Angeliki A., 2016. "Energy efficient sorption enhanced-chemical looping methane reforming process for high-purity H2 production: Experimental proof-of-concept," Applied Energy, Elsevier, vol. 180(C), pages 457-471.
    11. Singha, Rajib Kumar & Shukla, Astha & Yadav, Aditya & Adak, Shubhadeep & Iqbal, Zafar & Siddiqui, Nazia & Bal, Rajaram, 2016. "Energy efficient methane tri-reforming for synthesis gas production over highly coke resistant nanocrystalline Ni–ZrO2 catalyst," Applied Energy, Elsevier, vol. 178(C), pages 110-125.
    12. Tang, Mingchen & Xu, Long & Fan, Maohong, 2015. "Progress in oxygen carrier development of methane-based chemical-looping reforming: A review," Applied Energy, Elsevier, vol. 151(C), pages 143-156.
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