IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v277y2020ics0306261920311016.html
   My bibliography  Save this article

Enhanced performance of copper ore oxygen carrier by red mud modification for chemical looping combustion

Author

Listed:
  • Gu, Zhenhua
  • Zhang, Ling
  • Lu, Chunqiang
  • Qing, Shan
  • Li, Kongzhai

Abstract

Copper ore has been considered as a promising low-cost oxygen carrier candidate for chemical looping combustion (CLC) due to its high reactivity, but pure Cu ore suffers from serious deactivation during long term redox cycling. The present work proposes to combine Cu ore with red mud, an abundant polluting waste of aluminum industry, to improve the reactivity and stability of Cu ore for CLC of methane. Characterizations, redox experiment and kinetic analysis are performed on the mixed oxygen carriers to study the relationship between the physiochemical properties and the redox activity. The results show that the addition of a suitable proportion of red mud (30 wt%) significantly improves the reactivity of Cu ore. Specifically, the average CH4 conversion increases from 67% to 86%, and the actual oxygen carrying capacity rises from 8.2% to 13.8%. In addition, the activation energy for the reduction of Cu ore oxygen carrier by methane decreases from 76.6 kJ/mol to 58.5 kJ/mol after modification. The synergy among CuO in copper ore, Fe2O3 and other components (e.g., Na+, Ca2+, SiO2 and Al2O3) in red mud play an important role in this enhancement. The interaction between CuO and Fe2O3 promotes the reducibility of oxygen carrier via forming a more active oxide (CuFe2O4), and the presence of foreign ions (Na+ and Ca2+) and inert oxides (Al2O3 and SiO2) contributes to the enhanced redox stability of oxygen carrier via acting as supports or additives.

Suggested Citation

  • Gu, Zhenhua & Zhang, Ling & Lu, Chunqiang & Qing, Shan & Li, Kongzhai, 2020. "Enhanced performance of copper ore oxygen carrier by red mud modification for chemical looping combustion," Applied Energy, Elsevier, vol. 277(C).
    • Handle: RePEc:eee:appene:v:277:y:2020:i:c:s0306261920311016
    DOI: 10.1016/j.apenergy.2020.115590
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261920311016
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2020.115590?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Mondal, Monoj Kumar & Balsora, Hemant Kumar & Varshney, Prachi, 2012. "Progress and trends in CO2 capture/separation technologies: A review," Energy, Elsevier, vol. 46(1), pages 431-441.
    2. Tian, Xin & Zhao, Haibo & Ma, Jinchen, 2017. "Cement bonded fine hematite and copper ore particles as oxygen carrier in chemical looping combustion," Applied Energy, Elsevier, vol. 204(C), pages 242-253.
    3. Ksepko, Ewelina & Babiński, Piotr & Nalbandian, Lori, 2017. "The redox reaction kinetics of Sinai ore for chemical looping combustion applications," Applied Energy, Elsevier, vol. 190(C), pages 1258-1274.
    4. Lu, Chunqiang & Li, Kongzhai & Wang, Hua & Zhu, Xing & Wei, Yonggang & Zheng, Min & Zeng, Chunhua, 2018. "Chemical looping reforming of methane using magnetite as oxygen carrier: Structure evolution and reduction kinetics," Applied Energy, Elsevier, vol. 211(C), pages 1-14.
    5. Deng, Guixian & Li, Kongzhai & Zhang, Guifang & Gu, Zhenhua & Zhu, Xing & Wei, Yonggang & Wang, Hua, 2019. "Enhanced performance of red mud-based oxygen carriers by CuO for chemical looping combustion of methane," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    6. Arjmand, Mehdi & Leion, Henrik & Mattisson, Tobias & Lyngfelt, Anders, 2014. "Investigation of different manganese ores as oxygen carriers in chemical-looping combustion (CLC) for solid fuels," Applied Energy, Elsevier, vol. 113(C), pages 1883-1894.
    7. Gu, Haiming & Shen, Laihong & Zhong, Zhaoping & Niu, Xin & Liu, Weidong & Ge, Huijun & Jiang, Shouxi & Wang, Lulu, 2015. "Cement/CaO-modified iron ore as oxygen carrier for chemical looping combustion of coal," Applied Energy, Elsevier, vol. 157(C), pages 314-322.
    8. Sun, Zhenkun & Lu, Dennis Y. & Ridha, Firas N. & Hughes, Robin W. & Filippou, Dimitrios, 2017. "Enhanced performance of ilmenite modified by CeO2, ZrO2, NiO, and Mn2O3 as oxygen carriers in chemical looping combustion," Applied Energy, Elsevier, vol. 195(C), pages 303-315.
    9. Ksepko, Ewelina & Sciazko, Marek & Babinski, Piotr, 2014. "Studies on the redox reaction kinetics of Fe2O3–CuO/Al2O3 and Fe2O3/TiO2 oxygen carriers," Applied Energy, Elsevier, vol. 115(C), pages 374-383.
    10. Tang, Mingchen & Xu, Long & Fan, Maohong, 2015. "Progress in oxygen carrier development of methane-based chemical-looping reforming: A review," Applied Energy, Elsevier, vol. 151(C), pages 143-156.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Hsiao Mun Lee & Jiahui Xiong & Xinfei Chen & Haitao Wang & Da Song & Jinlong Xie & Yan Lin & Ya Xiong & Zhen Huang & Hongyu Huang, 2023. "Evaluation of the Reactivity of Hematite Oxygen Carriers Modified Using Alkaline (Earth) Metals and Transition Metals for the Chemical Looping Conversion of Lignite," Energies, MDPI, vol. 16(6), pages 1-16, March.
    2. Di, Zichen & Yilmaz, Duygu & Biswas, Arijit & Cheng, Fangqin & Leion, Henrik, 2022. "Spinel ferrite-contained industrial materials as oxygen carriers in chemical looping combustion," Applied Energy, Elsevier, vol. 307(C).
    3. Fredrik Hildor & Tobias Mattisson & Carl Linderholm & Henrik Leion, 2023. "Metal impregnation on steel converter slag as an oxygen carrier," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 13(4), pages 509-519, August.
    4. Ma, Zhong & Liu, Guofu & Zhang, Hui & Zhang, Shuai & Lu, Yonggang, 2021. "Evaluation of pyrite cinders from sulfuric acid production as oxygen carrier for chemical looping combustion," Energy, Elsevier, vol. 233(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Lin, Shen & Gu, Zhenhua & Zhu, Xing & Wei, Yonggang & Long, Yanhui & Yang, Kun & He, Fang & Wang, Hua & Li, Kongzhai, 2020. "Synergy of red mud oxygen carrier with MgO and NiO for enhanced chemical-looping combustion," Energy, Elsevier, vol. 197(C).
    2. Lu, Chunqiang & Li, Kongzhai & Zhu, Xing & Wei, Yonggang & Li, Lei & Zheng, Min & Fan, Bingbing & He, Fang & Wang, Hua, 2020. "Improved activity of magnetite oxygen carrier for chemical looping steam reforming by ultrasonic treatment," Applied Energy, Elsevier, vol. 261(C).
    3. Di, Zichen & Yilmaz, Duygu & Biswas, Arijit & Cheng, Fangqin & Leion, Henrik, 2022. "Spinel ferrite-contained industrial materials as oxygen carriers in chemical looping combustion," Applied Energy, Elsevier, vol. 307(C).
    4. Deng, Guixian & Li, Kongzhai & Zhang, Guifang & Gu, Zhenhua & Zhu, Xing & Wei, Yonggang & Wang, Hua, 2019. "Enhanced performance of red mud-based oxygen carriers by CuO for chemical looping combustion of methane," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    5. Tian, Xin & Zhao, Haibo & Ma, Jinchen, 2017. "Cement bonded fine hematite and copper ore particles as oxygen carrier in chemical looping combustion," Applied Energy, Elsevier, vol. 204(C), pages 242-253.
    6. Cheng, Xianming & Li, Kongzhai & Zhu, Xing & Wei, Yonggang & Li, Zhouhang & Long, Yanhui & Zheng, Min & Tian, Dong & Wang, Hua, 2018. "Enhanced performance of chemical looping combustion of methane by combining oxygen carriers via optimizing the stacking sequences," Applied Energy, Elsevier, vol. 230(C), pages 696-711.
    7. Zhang, Hao & Liu, Xiangyu & Hong, Hui & Jin, Hongguang, 2018. "Characteristics of a 10 kW honeycomb reactor for natural gas fueled chemical-looping combustion," Applied Energy, Elsevier, vol. 213(C), pages 285-292.
    8. Nadgouda, Sourabh G. & Guo, Mengqing & Tong, Andrew & Fan, L.-S., 2019. "High purity syngas and hydrogen coproduction using copper-iron oxygen carriers in chemical looping reforming process," Applied Energy, Elsevier, vol. 235(C), pages 1415-1426.
    9. Chein, Rei-Yu & Hsu, Wen-Huai, 2019. "Thermodynamic analysis of syngas production via chemical looping dry reforming of methane," Energy, Elsevier, vol. 180(C), pages 535-547.
    10. Liu, Xiangyu & Zhang, Hao & Hong, Hui & Jin, Hongguang, 2020. "Experimental study on honeycomb reactor using methane via chemical looping cycle for solar syngas," Applied Energy, Elsevier, vol. 268(C).
    11. Rana, Shazadi & Sun, Zhenkun & Mehrani, Poupak & Hughes, Robin & Macchi, Arturo, 2019. "Ilmenite oxidation kinetics for pressurized chemical looping combustion of natural gas," Applied Energy, Elsevier, vol. 238(C), pages 747-759.
    12. Najmus S. Sifat & Yousef Haseli, 2019. "A Critical Review of CO 2 Capture Technologies and Prospects for Clean Power Generation," Energies, MDPI, vol. 12(21), pages 1-33, October.
    13. Do, Jeong Yeon & Son, Namgyu & Park, No-Kuk & Kwak, Byeong Sub & Baek, Jeom-In & Ryu, Ho-Jung & Kang, Misook, 2018. "Reliable oxygen transfer in MgAl2O4 spinel through the reversible formation of oxygen vacancies by Cu2+/Fe3+ anchoring," Applied Energy, Elsevier, vol. 219(C), pages 138-150.
    14. Wang, Haiming & Dou, Xiaomin & Veksha, Andrei & Liu, Wen & Giannis, Apostolos & Ge, Liya & Thye Lim, Teik & Lisak, Grzegorz, 2020. "Barium aluminate improved iron ore for the chemical looping combustion of syngas," Applied Energy, Elsevier, vol. 272(C).
    15. Huang, Liang & Tang, Mingchen & Fan, Maohong & Cheng, Hansong, 2015. "Density functional theory study on the reaction between hematite and methane during chemical looping process," Applied Energy, Elsevier, vol. 159(C), pages 132-144.
    16. Zhu, Yanyan & Jin, Nannan & Liu, Ruilin & Sun, Xueyan & Bai, Lei & Tian, Hanjing & Ma, Xiaoxun & Wang, Xiaodong, 2020. "Bimetallic BaFe2MAl9O19 (M = Mn, Ni, and Co) hexaaluminates as oxygen carriers for chemical looping dry reforming of methane," Applied Energy, Elsevier, vol. 258(C).
    17. Haider, S.K. & Azimi, G. & Duan, L. & Anthony, E.J. & Patchigolla, K. & Oakey, J.E. & Leion, H. & Mattisson, T. & Lyngfelt, A., 2016. "Enhancing properties of iron and manganese ores as oxygen carriers for chemical looping processes by dry impregnation," Applied Energy, Elsevier, vol. 163(C), pages 41-50.
    18. Wang, Zhe & Fan, Weiyu & Zhang, Guangqing & Dong, Shuang, 2016. "Exergy analysis of methane cracking thermally coupled with chemical looping combustion for hydrogen production," Applied Energy, Elsevier, vol. 168(C), pages 1-12.
    19. Jiang, Qiongqiong & Zhang, Hao & Deng, Ya'nan & Kang, Qilan & Hong, Hui & Jin, Hongguang, 2018. "Properties and reactivity of LaCuxNi1−xO3 perovskites in chemical-looping combustion for mid-temperature solar-thermal energy storage," Applied Energy, Elsevier, vol. 228(C), pages 1506-1514.
    20. Kobayashi, Makoto & Akiho, Hiroyuki & Nakao, Yoshinobu, 2015. "Performance evaluation of porous sodium aluminate sorbent for halide removal process in oxy-fuel IGCC power generation plant," Energy, Elsevier, vol. 92(P3), pages 320-327.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:277:y:2020:i:c:s0306261920311016. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.