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Characterization of catalytic partial oxidation of methane with carbon dioxide utilization and excess enthalpy recovery

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  • Chen, Wei-Hsin
  • Lin, Shih-Cheng

Abstract

The characteristics of catalytic partial oxidation of methane (CPOM) under CO2 addition and excess enthalpy recovery are investigated where a rhodium-based catalyst is employed. The influences of O2/CH4 and CO2/O2 molar ratios, in the ranges of 0.4–0.7 and 0–2, respectively, on CPOM performance are emphasized. The energy efficiency of the Swiss-roll reactor is also studied. The results reveal that the O2/CH4 ratio plays a crucial role in methane conversion, whereas it is insensitive to the CO2/O2 ratio. The H2 contributed by steam reforming is pronounced at higher O2/CH4 ratios; on the other hand, H2 produced from dry reforming is significant at lower O2/CH4 ratios and high CO2/O2 ratios. The H2/CO ratio in the product gas is between 1 and 2, and the values depends on the O2/CH4 and CO2/O2 ratios. Increasing CO2/O2 ratio substantially increases CO2 consumption, but leads to a decrease in CO2 conversion. Within the investigated ranges of O2/CH4 and CO2/O2 ratios, at least 18.2% and up to 77.0% of CO2 in the feed gas is converted to CO. The energy efficiency of the reaction system with considering CH4 conversion is between 83.5% and 89.9%. Overall, CPOM performed at O2/CH4=0.6 is recommended in that it provides higher CH4 conversion, syngas production, CO2 consumption, and system energy efficiency.

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  • Chen, Wei-Hsin & Lin, Shih-Cheng, 2016. "Characterization of catalytic partial oxidation of methane with carbon dioxide utilization and excess enthalpy recovery," Applied Energy, Elsevier, vol. 162(C), pages 1141-1152.
    • Handle: RePEc:eee:appene:v:162:y:2016:i:c:p:1141-1152
    DOI: 10.1016/j.apenergy.2015.01.056
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    2. Chen, Wei-Hsin & Lin, Shih-Cheng, 2018. "Biogas partial oxidation in a heat recirculation reactor for syngas production and CO2 utilization," Applied Energy, Elsevier, vol. 217(C), pages 113-125.
    3. Luu, Minh Tri & Milani, Dia & Sharma, Manish & Zeaiter, Joseph & Abbas, Ali, 2016. "Model-based analysis of CO2 revalorization for di-methyl ether synthesis driven by solar catalytic reforming," Applied Energy, Elsevier, vol. 177(C), pages 863-878.
    4. Siang, T.J. & Jalil, A.A. & Abdulrasheed, A.A. & Hambali, H.U. & Nabgan, Walid, 2020. "Thermodynamic equilibrium study of altering methane partial oxidation for Fischer–Tropsch synfuel production," Energy, Elsevier, vol. 198(C).
    5. Chen, Wei-Hsin & Guo, Yu-Zhi & Chen, Chih-Chun, 2018. "Methanol partial oxidation accompanied by heat recirculation in a Swiss-roll reactor," Applied Energy, Elsevier, vol. 232(C), pages 79-88.
    6. Ding, Jing & Wang, Yarong & Gu, Rong & Wang, Weilong & Lu, Jianfeng, 2019. "Thermochemical storage performance of methane reforming with carbon dioxide using high temperature slag," Applied Energy, Elsevier, vol. 250(C), pages 1270-1279.
    7. Woo, Seungchul & Kim, Woongil & Lee, Jungkoo & Lee, Kihyung, 2022. "Performance evaluation of the LPG engine applied to catalytic reforming system for producing hydrogen," Applied Energy, Elsevier, vol. 312(C).
    8. Chen, Xuejing & Jiang, Jianguo & Li, Kaimin & Tian, Sicong & Yan, Feng, 2017. "Energy-efficient biogas reforming process to produce syngas: The enhanced methane conversion by O2," Applied Energy, Elsevier, vol. 185(P1), pages 687-697.
    9. Jalali, Ramin & Rezaei, Mehran & Nematollahi, Behzad & Baghalha, Morteza, 2020. "Preparation of Ni/MeAl2O4-MgAl2O4 (Me=Fe, Co, Ni, Cu, Zn, Mg) nanocatalysts for the syngas production via combined dry reforming and partial oxidation of methane," Renewable Energy, Elsevier, vol. 149(C), pages 1053-1067.

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