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Assessment and comparison of different catalytic coupling exothermic and endothermic reactions: A review

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  • Rahimpour, M.R.
  • Dehnavi, M.R.
  • Allahgholipour, F.
  • Iranshahi, D.
  • Jokar, S.M.

Abstract

Coupling exothermic with endothermic reactions is proposed as a significant improvement in reactor performance and energy integration. Furthermore, it forms an initial step for process optimization using pinch method. Through coupling of the exothermic reaction with endothermic one, oxidation with reduction, dehydrogenation with hydrogenation, hydration with dehydration, and even a series of tandem reactions, the utilization of energy and materials can be optimized. The underlying goal of this paper is to provide an extensive review through the years 1994–2011 of coupling exothermic and endothermic reactions as an important measure in process integration and intensifying. Developments in coupled reactions, classifying suitable reactors for couplings and categorizing several types of coupling exothermic and endothermic reactions are investigated in this study. Finally, various information concerning coupled reactions are presented in tables. Superiorities of novel models (coupled configurations) to the conventional configurations are clarified. Ultimately, various suggestions are proposed for further work. Results show that the short distance between heat sink and heat source can increase the efficiency of the heat transfer meanwhile incorporating two separated processes with coupled reactors can reduce the size of equipment.

Suggested Citation

  • Rahimpour, M.R. & Dehnavi, M.R. & Allahgholipour, F. & Iranshahi, D. & Jokar, S.M., 2012. "Assessment and comparison of different catalytic coupling exothermic and endothermic reactions: A review," Applied Energy, Elsevier, vol. 99(C), pages 496-512.
    • Handle: RePEc:eee:appene:v:99:y:2012:i:c:p:496-512
    DOI: 10.1016/j.apenergy.2012.04.003
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    References listed on IDEAS

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    1. Rahimpour, M.R. & Bahmanpour, A.M., 2011. "Optimization of hydrogen production via coupling of the Fischer-Tropsch synthesis reaction and dehydrogenation of cyclohexane in GTL technology," Applied Energy, Elsevier, vol. 88(6), pages 2027-2036, June.
    2. Vakili, R. & Pourazadi, E. & Setoodeh, P. & Eslamloueyan, R. & Rahimpour, M.R., 2011. "Direct dimethyl ether (DME) synthesis through a thermally coupled heat exchanger reactor," Applied Energy, Elsevier, vol. 88(4), pages 1211-1223, April.
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    1. Rahimpour, Mohammad Reza & Jafari, Mitra & Iranshahi, Davood, 2013. "Progress in catalytic naphtha reforming process: A review," Applied Energy, Elsevier, vol. 109(C), pages 79-93.
    2. Kang, Sanggyu & Lee, Kanghun & Yu, Sangseok & Lee, Sang Min & Ahn, Kook-Young, 2014. "Development of a coupled reactor with a catalytic combustor and steam reformer for a 5kW solid oxide fuel cell system," Applied Energy, Elsevier, vol. 114(C), pages 114-123.
    3. Junjie Chen & Baofang Liu & Xuhui Gao & Deguang Xu, 2018. "RETRACTED: Production of Hydrogen by Methane Steam Reforming Coupled with Catalytic Combustion in Integrated Microchannel Reactors," Energies, MDPI, vol. 11(8), pages 1, August.
    4. Feng, Yu & Liu, Yuna & Cao, Yong & Gong, Keyu & Liu, Shuyuan & Qin, Jiang, 2020. "Thermal management evaluation for advanced aero-engines using catalytic steam reforming of hydrocarbon fuels," Energy, Elsevier, vol. 193(C).
    5. Ghaebi, Hadi & Yari, Mortaza & Gargari, Saeed Ghavami & Rostamzadeh, Hadi, 2019. "Thermodynamic modeling and optimization of a combined biogas steam reforming system and organic Rankine cycle for coproduction of power and hydrogen," Renewable Energy, Elsevier, vol. 130(C), pages 87-102.
    6. Ribeirinha, P. & Abdollahzadeh, M. & Boaventura, M. & Mendes, A., 2017. "H2 production with low carbon content via MSR in packed bed membrane reactors for high-temperature polymeric electrolyte membrane fuel cell," Applied Energy, Elsevier, vol. 188(C), pages 409-419.
    7. Hajjaji, Noureddine & Chahbani, Amna & Khila, Zouhour & Pons, Marie-Noëlle, 2014. "A comprehensive energy–exergy-based assessment and parametric study of a hydrogen production process using steam glycerol reforming," Energy, Elsevier, vol. 64(C), pages 473-483.
    8. Hajjaji, Noureddine & Baccar, Ines & Pons, Marie-Noëlle, 2014. "Energy and exergy analysis as tools for optimization of hydrogen production by glycerol autothermal reforming," Renewable Energy, Elsevier, vol. 71(C), pages 368-380.
    9. Zhang, Xiaosong & Jin, Hongguang, 2013. "Thermodynamic analysis of chemical-looping hydrogen generation," Applied Energy, Elsevier, vol. 112(C), pages 800-807.
    10. Li, Chunlin & Xu, Hengyong & Hou, Shoufu & Sun, Jian & Meng, Fanqiong & Ma, Junguo & Tsubaki, Noritatsu, 2013. "SiC foam monolith catalyst for pressurized adiabatic methane reforming," Applied Energy, Elsevier, vol. 107(C), pages 297-303.
    11. Ström, Henrik, 2017. "Computational optimization of catalyst distributions at the nano-scale," Applied Energy, Elsevier, vol. 185(P2), pages 2224-2231.
    12. He, Li & Fan, Yilin & Bellettre, Jérôme & Yue, Jun & Luo, Lingai, 2020. "A review on catalytic methane combustion at low temperatures: Catalysts, mechanisms, reaction conditions and reactor designs," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).

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