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Rate-based modelling of combined SO2 removal and NH3 recycling integrated with an aqueous NH3-based CO2 capture process

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  • Li, Kangkang
  • Yu, Hai
  • Qi, Guojie
  • Feron, Paul
  • Tade, Moses
  • Yu, Jingwen
  • Wang, Shujuan

Abstract

To reduce the costs of controlling emissions from coal-fired power stations, we propose an advanced and effective process of combined SO2 removal and NH3 recycling, which can be integrated with the aqueous NH3-based CO2 capture process to simultaneously achieve SO2 and CO2 removal, NH3 recycling and flue gas cooling in one process. A rigorous, rate-based model for an NH3–CO2–SO2–H2O system was developed and used to simulate the proposed process. The model was thermodynamically and kinetically validated by experimental results from the open literature and pilot-plant trials, respectively. Under typical flue gas conditions, the proposed process has SO2 removal and NH3 reuse efficiencies of >99.9%. The process is strongly adaptable to different scenarios such as high SO2 levels in flue gas, high NH3 levels from the CO2 absorber and high flue gas temperatures, and has a low energy requirement. Because the process simplifies flue gas desulphurisation and resolves the problems of NH3 loss and SO2 removal, it could significantly reduce the cost of CO2 and SO2 capture by aqueous NH3.

Suggested Citation

  • Li, Kangkang & Yu, Hai & Qi, Guojie & Feron, Paul & Tade, Moses & Yu, Jingwen & Wang, Shujuan, 2015. "Rate-based modelling of combined SO2 removal and NH3 recycling integrated with an aqueous NH3-based CO2 capture process," Applied Energy, Elsevier, vol. 148(C), pages 66-77.
    • Handle: RePEc:eee:appene:v:148:y:2015:i:c:p:66-77
    DOI: 10.1016/j.apenergy.2015.03.060
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    1. Qi, Guojie & Wang, Shujuan, 2017. "Experimental study and rate-based modeling on combined CO2 and SO2 absorption using aqueous NH3 in packed column," Applied Energy, Elsevier, vol. 206(C), pages 1532-1543.
    2. Cheng, Chin-hung & Li, Kangkang & Yu, Hai & Jiang, Kaiqi & Chen, Jian & Feron, Paul, 2018. "Amine-based post-combustion CO2 capture mediated by metal ions: Advancement of CO2 desorption using copper ions," Applied Energy, Elsevier, vol. 211(C), pages 1030-1038.
    3. Jiang, Kaiqi & Yu, Hai & Chen, Linghong & Fang, Mengxiang & Azzi, Merched & Cottrell, Aaron & Li, Kangkang, 2020. "An advanced, ammonia-based combined NOx/SOx/CO2 emission control process towards a low-cost, clean coal technology," Applied Energy, Elsevier, vol. 260(C).
    4. Wang, Fu & Zhao, Jun & Miao, He & Zhao, Jiapei & Zhang, Houcheng & Yuan, Jinliang & Yan, Jinyue, 2018. "Current status and challenges of the ammonia escape inhibition technologies in ammonia-based CO2 capture process," Applied Energy, Elsevier, vol. 230(C), pages 734-749.
    5. Ma, Shuangchen & Chen, Gongda & Zhu, Sijie & Wen, Jiaqi & Gao, Ran & Ma, Lan & Chai, Jin, 2016. "Experimental study of mixed additive of Ni(II) and piperazine on ammonia escape in CO2 capture using ammonia solution," Applied Energy, Elsevier, vol. 169(C), pages 597-606.
    6. Chen, Long & Xu, Guiyin & Rui, Zhenhua & Alshawabkeh, Akram N., 2019. "Demonstration of a feasible energy-water-environment nexus: Waste sulfur dioxide for water treatment," Applied Energy, Elsevier, vol. 250(C), pages 1011-1022.
    7. Chu, Fengming & Yang, Lijun & Du, Xiaoze & Yang, Yongping, 2017. "Mass transfer and energy consumption for CO2 absorption by ammonia solution in bubble column," Applied Energy, Elsevier, vol. 190(C), pages 1068-1080.
    8. Si, Tong & Wang, Chunbo & Yan, Xuenan & Zhang, Yue & Ren, Yujie & Hu, Jian & Anthony, Edward J., 2019. "Simultaneous removal of SO2 and NOx by a new combined spray-and-scattered-bubble technology based on preozonation: From lab scale to pilot scale," Applied Energy, Elsevier, vol. 242(C), pages 1528-1538.
    9. Li, Kangkang & Jiang, Kaiqi & Jones, Timothy W. & Feron, Paul H.M. & Bennett, Robert D. & Hollenkamp, Anthony F., 2019. "CO2 regenerative battery for energy harvesting from ammonia-based post-combustion CO2 capture," Applied Energy, Elsevier, vol. 247(C), pages 417-425.
    10. Xu, Yin & Jin, Baosheng & Zhao, Yongling & Hu, Eric J. & Chen, Xiaole & Li, Xiaochuan, 2018. "Numerical simulation of aqueous ammonia-based CO2 absorption in a sprayer tower: An integrated model combining gas-liquid hydrodynamics and chemistry," Applied Energy, Elsevier, vol. 211(C), pages 318-333.
    11. Jiang, Kaiqi & Li, Kangkang & Yu, Hai & Chen, Zuliang & Wardhaugh, Leigh & Feron, Paul, 2017. "Advancement of ammonia based post-combustion CO2 capture using the advanced flash stripper process," Applied Energy, Elsevier, vol. 202(C), pages 496-506.
    12. Qi, Guojie & Wang, Shujuan, 2017. "Thermodynamic modeling of NH3-CO2-SO2-K2SO4-H2O system for combined CO2 and SO2 capture using aqueous NH3," Applied Energy, Elsevier, vol. 191(C), pages 549-558.
    13. Ji, Long & Yu, Hai & Li, Kangkang & Yu, Bing & Grigore, Mihaela & Yang, Qi & Wang, Xiaolong & Chen, Zuliang & Zeng, Ming & Zhao, Shuaifei, 2018. "Integrated absorption-mineralisation for low-energy CO2 capture and sequestration," Applied Energy, Elsevier, vol. 225(C), pages 356-366.
    14. Wang, Changhong & Jiang, Kaiqi & Yu, Hai & Yang, Shenghai & Li, Kangkang, 2022. "Copper electrowinning-coupled CO2 capture in solvent based post-combustion capture," Applied Energy, Elsevier, vol. 316(C).
    15. Wang, Yuelan & Ma, Zengyi & Shen, Yueliang & Tang, Yijun & Ni, Mingjiang & Chi, Yong & Yan, Jianhua & Cen, Kefa, 2016. "A power-saving control strategy for reducing the total pressure applied by the primary air fan of a coal-fired power plant," Applied Energy, Elsevier, vol. 175(C), pages 380-388.
    16. Yifang Liu & Fengming Chu & Lijun Yang & Xiaoze Du & Yongping Yang, 2018. "CO2 absorption characteristics in a random packed column with various geometric structures and working conditions," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(1), pages 120-132, February.
    17. Hai Yu & Nan Yang & Marcel Maeder & Paul Feron, 2018. "Kinetics of the reversible reaction of CO2(aq) with taurate in aqueous solution," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(4), pages 672-685, August.
    18. Li, Kangkang & Leigh, Wardhaugh & Feron, Paul & Yu, Hai & Tade, Moses, 2016. "Systematic study of aqueous monoethanolamine (MEA)-based CO2 capture process: Techno-economic assessment of the MEA process and its improvements," Applied Energy, Elsevier, vol. 165(C), pages 648-659.
    19. Chu, Fengming & Liu, Yifang & Yang, Lijun & Du, Xiaoze & Yang, Yongping, 2017. "Ammonia escape mass transfer and heat transfer characteristics of CO2 absorption in packed absorbing column," Applied Energy, Elsevier, vol. 205(C), pages 1596-1604.
    20. Chen, Hao & Dong, Sheying & Zhang, Yaojun & He, Panyang, 2022. "A comparative study on energy efficient CO2 capture using amine grafted solid sorbent: Materials characterization, isotherms, kinetics and thermodynamics," Energy, Elsevier, vol. 239(PD).

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    Keywords

    CO2 capture; SO2 removal; NH3 recycling; Aqueous NH3;
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