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Enhancing piezoelectric coefficient and thermal stability in lead-free piezoceramics: insights at the atomic-scale

Author

Listed:
  • Jinzhu Zou

    (Central South University)

  • Miao Song

    (Central South University)

  • Xuefan Zhou

    (Central South University)

  • Wenchao Chi

    (Central South University)

  • Tongxin Wei

    (Central South University)

  • Kechao Zhou

    (Central South University)

  • Dou Zhang

    (Central South University)

  • Shujun Zhang

    (University of Wollongong)

Abstract

Given the highly temperature-sensitive nature of the polymorphic phase boundaries, attaining excellent piezoelectric coefficient with superior temperature stability in lead-free piezoceramics via direct compositional design remains a formidable challenge. We demonstrate the synergistic improvement of piezoelectric coefficient and thermal stability in lead-free piezoceramics via atomic-scale local ferroelectric structure design. Via modulation of the local Landau energy barrier at doping sites, we effectively mitigate fluctuations in piezoelectric d33. Our approach achieves an impressive d33 of ~430 pC/N with a minimal temperature fluctuation range (△d33 ~ 7%) across the room temperature to 100 °C in potassium sodium niobate ceramics. Further optimization through annealing extends this temperature up to 150 °C (△d33 ~ 8%) while maintaining a high d33 of ~380 pC/N, rivaling the performance of classic temperature stable lead zirconate titanate. This work establishes a framework for addressing the dilemma between high piezoelectric coefficient and inadequate temperature stability in lead-free piezoceramics.

Suggested Citation

  • Jinzhu Zou & Miao Song & Xuefan Zhou & Wenchao Chi & Tongxin Wei & Kechao Zhou & Dou Zhang & Shujun Zhang, 2024. "Enhancing piezoelectric coefficient and thermal stability in lead-free piezoceramics: insights at the atomic-scale," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-53020-y
    DOI: 10.1038/s41467-024-53020-y
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    1. Mao-Hua Zhang & Chen Shen & Changhao Zhao & Mian Dai & Fang-Zhou Yao & Bo Wu & Jian Ma & Hu Nan & Dawei Wang & Qibin Yuan & Lucas Lemos Silva & Lovro Fulanović & Alexander Schökel & Peitao Liu & Hongb, 2022. "Deciphering the phase transition-induced ultrahigh piezoresponse in (K,Na)NbO3-based piezoceramics," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Muhtar Ahart & Maddury Somayazulu & R. E. Cohen & P. Ganesh & Przemyslaw Dera & Ho-kwang Mao & Russell J. Hemley & Yang Ren & Peter Liermann & Zhigang Wu, 2008. "Origin of morphotropic phase boundaries in ferroelectrics," Nature, Nature, vol. 451(7178), pages 545-548, January.
    3. Yasuyoshi Saito & Hisaaki Takao & Toshihiko Tani & Tatsuhiko Nonoyama & Kazumasa Takatori & Takahiko Homma & Toshiatsu Nagaya & Masaya Nakamura, 2004. "Lead-free piezoceramics," Nature, Nature, vol. 432(7013), pages 84-87, November.
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