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Lattice pinning in MoO3 via coherent interface with stabilized Li+ intercalation

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  • Shuo Sun

    (Nanjing University of Science and Technology)

  • Zhen Han

    (Institute of Physics, Chinese Academy of Sciences)

  • Wei Liu

    (Nanjing University of Science and Technology)

  • Qiuying Xia

    (Nanjing University of Science and Technology)

  • Liang Xue

    (Nanjing University of Science and Technology)

  • Xincheng Lei

    (Institute of Physics, Chinese Academy of Sciences)

  • Teng Zhai

    (Nanjing University of Science and Technology)

  • Dong Su

    (Institute of Physics, Chinese Academy of Sciences)

  • Hui Xia

    (Nanjing University of Science and Technology)

Abstract

Large lattice expansion/contraction with Li+ intercalation/deintercalation of electrode active materials results in severe structural degradation to electrodes and can negatively impact the cycle life of solid-state lithium-based batteries. In case of the layered orthorhombic MoO3 (α-MoO3), its large lattice variation along the b axis during Li+ insertion/extraction induces irreversible phase transition and structural degradation, leading to undesirable cycle life. Herein, we propose a lattice pinning strategy to construct a coherent interface between α-MoO3 and η-Mo4O11 with epitaxial intergrowth structure. Owing to the minimal lattice change of η-Mo4O11 during Li+ insertion/extraction, η-Mo4O11 domains serve as pin centers that can effectively suppress the lattice expansion of α-MoO3, evidenced by the noticeably decreased lattice expansion from about 16% to 2% along the b direction. The designed α-MoO3/η-Mo4O11 intergrown heterostructure enables robust structural stability during cycling (about 81% capacity retention after 3000 cycles at a specific current of 2 A g−1 and 298 ± 2 K) by harnessing the merits of epitaxial stabilization and the pinning effect. Finally, benefiting from the stable positive electrode–solid electrolyte interface, a highly durable and flexible all-solid-state thin-film lithium microbattery is further demonstrated. This work advances the fundamental understanding of the unstable structure evolution for α-MoO3, and may offer a rational strategy to develop highly stable electrode materials for advanced batteries.

Suggested Citation

  • Shuo Sun & Zhen Han & Wei Liu & Qiuying Xia & Liang Xue & Xincheng Lei & Teng Zhai & Dong Su & Hui Xia, 2023. "Lattice pinning in MoO3 via coherent interface with stabilized Li+ intercalation," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-42335-x
    DOI: 10.1038/s41467-023-42335-x
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