IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-42335-x.html
   My bibliography  Save this article

Lattice pinning in MoO3 via coherent interface with stabilized Li+ intercalation

Author

Listed:
  • Shuo Sun

    (Nanjing University of Science and Technology)

  • Zhen Han

    (Institute of Physics, Chinese Academy of Sciences)

  • Wei Liu

    (Nanjing University of Science and Technology)

  • Qiuying Xia

    (Nanjing University of Science and Technology)

  • Liang Xue

    (Nanjing University of Science and Technology)

  • Xincheng Lei

    (Institute of Physics, Chinese Academy of Sciences)

  • Teng Zhai

    (Nanjing University of Science and Technology)

  • Dong Su

    (Institute of Physics, Chinese Academy of Sciences)

  • Hui Xia

    (Nanjing University of Science and Technology)

Abstract

Large lattice expansion/contraction with Li+ intercalation/deintercalation of electrode active materials results in severe structural degradation to electrodes and can negatively impact the cycle life of solid-state lithium-based batteries. In case of the layered orthorhombic MoO3 (α-MoO3), its large lattice variation along the b axis during Li+ insertion/extraction induces irreversible phase transition and structural degradation, leading to undesirable cycle life. Herein, we propose a lattice pinning strategy to construct a coherent interface between α-MoO3 and η-Mo4O11 with epitaxial intergrowth structure. Owing to the minimal lattice change of η-Mo4O11 during Li+ insertion/extraction, η-Mo4O11 domains serve as pin centers that can effectively suppress the lattice expansion of α-MoO3, evidenced by the noticeably decreased lattice expansion from about 16% to 2% along the b direction. The designed α-MoO3/η-Mo4O11 intergrown heterostructure enables robust structural stability during cycling (about 81% capacity retention after 3000 cycles at a specific current of 2 A g−1 and 298 ± 2 K) by harnessing the merits of epitaxial stabilization and the pinning effect. Finally, benefiting from the stable positive electrode–solid electrolyte interface, a highly durable and flexible all-solid-state thin-film lithium microbattery is further demonstrated. This work advances the fundamental understanding of the unstable structure evolution for α-MoO3, and may offer a rational strategy to develop highly stable electrode materials for advanced batteries.

Suggested Citation

  • Shuo Sun & Zhen Han & Wei Liu & Qiuying Xia & Liang Xue & Xincheng Lei & Teng Zhai & Dong Su & Hui Xia, 2023. "Lattice pinning in MoO3 via coherent interface with stabilized Li+ intercalation," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-42335-x
    DOI: 10.1038/s41467-023-42335-x
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-42335-x
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-023-42335-x?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Mao-Hua Zhang & Chen Shen & Changhao Zhao & Mian Dai & Fang-Zhou Yao & Bo Wu & Jian Ma & Hu Nan & Dawei Wang & Qibin Yuan & Lucas Lemos Silva & Lovro Fulanović & Alexander Schökel & Peitao Liu & Hongb, 2022. "Deciphering the phase transition-induced ultrahigh piezoresponse in (K,Na)NbO3-based piezoceramics," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Xiaohui Zhu & Fanqi Meng & Qinghua Zhang & Liang Xue & He Zhu & Si Lan & Qi Liu & Jing Zhao & Yuhang Zhuang & Qiubo Guo & Bo Liu & Lin Gu & Xia Lu & Yang Ren & Hui Xia, 2021. "LiMnO2 cathode stabilized by interfacial orbital ordering for sustainable lithium-ion batteries," Nature Sustainability, Nature, vol. 4(5), pages 392-401, May.
    3. Tianyi Wang & Yanbin Li & Jinqiang Zhang & Kang Yan & Pauline Jaumaux & Jian Yang & Chengyin Wang & Devaraj Shanmukaraj & Bing Sun & Michel Armand & Yi Cui & Guoxiu Wang, 2020. "Immunizing lithium metal anodes against dendrite growth using protein molecules to achieve high energy batteries," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    4. Ang Gao & Qinghua Zhang & Xinyan Li & Tongtong Shang & Zhexin Tang & Xia Lu & Yanhong Luo & Jiarun Ding & Wang Hay Kan & Huaican Chen & Wen Yin & Xuefeng Wang & Dongdong Xiao & Dong Su & Hong Li & Xia, 2022. "Topologically protected oxygen redox in a layered manganese oxide cathode for sustainable batteries," Nature Sustainability, Nature, vol. 5(3), pages 214-224, March.
    5. Junmin Ge & Ling Fan & Apparao M. Rao & Jiang Zhou & Bingan Lu, 2022. "Surface-substituted Prussian blue analogue cathode for sustainable potassium-ion batteries," Nature Sustainability, Nature, vol. 5(3), pages 225-234, March.
    6. Chaojiang Niu & Dianying Liu & Joshua A. Lochala & Cassidy S. Anderson & Xia Cao & Mark E. Gross & Wu Xu & Ji-Guang Zhang & M. Stanley Whittingham & Jie Xiao & Jun Liu, 2021. "Balancing interfacial reactions to achieve long cycle life in high-energy lithium metal batteries," Nature Energy, Nature, vol. 6(7), pages 723-732, July.
    7. Xianhu Sun & Dongxiang Wu & Lianfeng Zou & Stephen D. House & Xiaobo Chen & Meng Li & Dmitri N. Zakharov & Judith C. Yang & Guangwen Zhou, 2022. "Dislocation-induced stop-and-go kinetics of interfacial transformations," Nature, Nature, vol. 607(7920), pages 708-713, July.
    8. Hui Xia & Xiaohui Zhu & Jizi Liu & Qi Liu & Si Lan & Qinghua Zhang & Xinyu Liu & Joon Kyo Seo & Tingting Chen & Lin Gu & Ying Shirley Meng, 2018. "A monoclinic polymorph of sodium birnessite for ultrafast and ultrastable sodium ion storage," Nature Communications, Nature, vol. 9(1), pages 1-10, December.
    9. Gebrekidan Gebresilassie Eshetu & Heng Zhang & Xabier Judez & Henry Adenusi & Michel Armand & Stefano Passerini & Egbert Figgemeier, 2021. "Production of high-energy Li-ion batteries comprising silicon-containing anodes and insertion-type cathodes," Nature Communications, Nature, vol. 12(1), pages 1-14, December.
    10. Qing Chen & Yi Pei & Houwen Chen & Yan Song & Liang Zhen & Cheng-Yan Xu & Penghao Xiao & Graeme Henkelman, 2020. "Highly reversible oxygen redox in layered compounds enabled by surface polyanions," Nature Communications, Nature, vol. 11(1), pages 1-12, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhuangzhuang Cui & Zhuangzhuang Jia & Digen Ruan & Qingshun Nian & Jiajia Fan & Shunqiang Chen & Zixu He & Dazhuang Wang & Jinyu Jiang & Jun Ma & Xing Ou & Shuhong Jiao & Qingsong Wang & Xiaodi Ren, 2024. "Molecular anchoring of free solvents for high-voltage and high-safety lithium metal batteries," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Hyeokjin Kwon & Hyun-Ji Choi & Jung-kyu Jang & Jinhong Lee & Jinkwan Jung & Wonjun Lee & Youngil Roh & Jaewon Baek & Dong Jae Shin & Ju-Hyuk Lee & Nam-Soon Choi & Ying Shirley Meng & Hee-Tak Kim, 2023. "Weakly coordinated Li ion in single-ion-conductor-based composite enabling low electrolyte content Li-metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Jun-Hyuk Song & Seungju Yu & Byunghoon Kim & Donggun Eum & Jiung Cho & Ho-Young Jang & Sung-O Park & Jaekyun Yoo & Youngmin Ko & Kyeongsu Lee & Myeong Hwan Lee & Byungwook Kang & Kisuk Kang, 2023. "Slab gliding, a hidden factor that induces irreversibility and redox asymmetry of lithium-rich layered oxide cathodes," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    4. Jiaqi Cao & Yuansheng Shi & Aosong Gao & Guangyuan Du & Muhtar Dilxat & Yongfei Zhang & Mohang Cai & Guoyu Qian & Xueyi Lu & Fangyan Xie & Yang Sun & Xia Lu, 2024. "Hierarchical Li electrochemistry using alloy-type anode for high-energy-density Li metal batteries," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    5. Guangzhao Zhang & Jian Chang & Liguang Wang & Jiawei Li & Chaoyang Wang & Ruo Wang & Guoli Shi & Kai Yu & Wei Huang & Honghe Zheng & Tianpin Wu & Yonghong Deng & Jun Lu, 2023. "A monofluoride ether-based electrolyte solution for fast-charging and low-temperature non-aqueous lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    6. Bo Wu & Huijing Zheng & Yan-Qi Wu & Zhicheng Huang & Hao-Cheng Thong & Hong Tao & Jian Ma & Chunlin Zhao & Ze Xu & Yi-Xuan Liu & Zhipeng Xing & Naixin Liang & Fang-Zhou Yao & Chao-Feng Wu & Ke Wang & , 2024. "Origin of ultrahigh-performance barium titanate-based piezoelectrics: Stannum-induced intrinsic and extrinsic contributions," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    7. Zhi Chang & Huijun Yang & Anqiang Pan & Ping He & Haoshen Zhou, 2022. "An improved 9 micron thick separator for a 350 Wh/kg lithium metal rechargeable pouch cell," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    8. Xuemu Li & Zhuomin Zhang & Zehua Peng & Xiaodong Yan & Ying Hong & Shiyuan Liu & Weikang Lin & Yao Shan & Yuanyi Wang & Zhengbao Yang, 2023. "Fast and versatile electrostatic disc microprinting for piezoelectric elements," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    9. Yao Zhang & Zezhou Li & Xing Tong & Zhiheng Xie & Siwei Huang & Yue-E Zhang & Hai-Bo Ke & Wei-Hua Wang & Jihan Zhou, 2024. "Three-dimensional atomic insights into the metal-oxide interface in Zr-ZrO2 nanoparticles," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    10. Joseph Paul Baboo & Mudasir A. Yatoo & Matthew Dent & Elaheh Hojaji Najafabadi & Constantina Lekakou & Robert Slade & Steven J. Hinder & John F. Watts, 2022. "Exploring Different Binders for a LiFePO 4 Battery, Battery Testing, Modeling and Simulations," Energies, MDPI, vol. 15(7), pages 1-22, March.
    11. Yangyang Zhang & Yanxu Chen & Xiaowen Wang & Yafei Feng & Zechuan Dai & Mingyu Cheng & Genqiang Zhang, 2024. "Low-coordinated copper facilitates the *CH2CO affinity at enhanced rectifying interface of Cu/Cu2O for efficient CO2-to-multicarbon alcohols conversion," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    12. Xinhua Zheng & Zaichun Liu & Jifei Sun & Ruihao Luo & Kui Xu & Mingyu Si & Ju Kang & Yuan Yuan & Shuang Liu & Touqeer Ahmad & Taoli Jiang & Na Chen & Mingming Wang & Yan Xu & Mingyan Chuai & Zhengxin , 2023. "Constructing robust heterostructured interface for anode-free zinc batteries with ultrahigh capacities," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    13. Zhaoheng Liang & Fei Tian & Gongzheng Yang & Chengxin Wang, 2023. "Enabling long-cycling aqueous sodium-ion batteries via Mn dissolution inhibition using sodium ferrocyanide electrolyte additive," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    14. Jinfeng Lin & Jin Qian & Guanglong Ge & Yuxuan Yang & Jiangfan Li & Xiao Wu & Guohui Li & Simin Wang & Yingchun Liu & Jialiang Zhang & Jiwei Zhai & Xiaoming Shi & Haijun Wu, 2024. "Multiscale reconfiguration induced highly saturated poling in lead-free piezoceramics for giant energy conversion," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    15. Junyeob Moon & Dong Ok Kim & Lieven Bekaert & Munsoo Song & Jinkyu Chung & Danwon Lee & Annick Hubin & Jongwoo Lim, 2022. "Non-fluorinated non-solvating cosolvent enabling superior performance of lithium metal negative electrode battery," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    16. Bo Wu & Lin Zhao & Jiaqing Feng & Yiting Zhang & Xilong Song & Jian Ma & Hong Tao & Ze Xu & Yi-Xuan Liu & Shidong Wang & Jingtong Lu & Fangyuan Zhu & Bing Han & Ke Wang, 2024. "Contribution of irreversible non-180° domain to performance for multiphase coexisted potassium sodium niobate ceramics," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    17. Ban Seok Lee & Sang-Hwan Oh & Yoon Jeong Choi & Min-Jeong Yi & So Hee Kim & Shin-Yeong Kim & Yung-Eun Sung & Sun Young Shin & Yongju Lee & Seung-Ho Yu, 2023. "SiO-induced thermal instability and interplay between graphite and SiO in graphite/SiO composite anode," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    18. Tianwei Cui & Jialiang Xu & Xin Wang & Longxiang Liu & Yuxuan Xiang & Hong Zhu & Xiang Li & Yongzhu Fu, 2024. "Highly reversible transition metal migration in superstructure-free Li-rich oxide boosting voltage stability and redox symmetry," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    19. Hyeokjin Kwon & Hongsin Kim & Jaemin Hwang & Wonsik Oh & Youngil Roh & Dongseok Shin & Hee-Tak Kim, 2024. "Borate–pyran lean electrolyte-based Li-metal batteries with minimal Li corrosion," Nature Energy, Nature, vol. 9(1), pages 57-69, January.
    20. Zishuai Zhang & Yilong Zhu & Miao Yu & Yan Jiao & Yan Huang, 2022. "Development of long lifespan high-energy aqueous organic||iodine rechargeable batteries," Nature Communications, Nature, vol. 13(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-42335-x. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.