IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-46980-8.html
   My bibliography  Save this article

Enhancement of electrocatalysis through magnetic field effects on mass transport

Author

Listed:
  • Priscila Vensaus

    (École Polytechnique Fédérale de Lausanne (EPFL)
    École Polytechnique Fédérale de Lausanne (EPFL)
    Escuela de Bio y Nanotecnologías, Universidad Nacional de San Martín, San Martín)

  • Yunchang Liang

    (École Polytechnique Fédérale de Lausanne (EPFL)
    École Polytechnique Fédérale de Lausanne (EPFL))

  • Jean-Philippe Ansermet

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Galo J. A. A. Soler-Illia

    (Escuela de Bio y Nanotecnologías, Universidad Nacional de San Martín, San Martín)

  • Magalí Lingenfelder

    (École Polytechnique Fédérale de Lausanne (EPFL)
    École Polytechnique Fédérale de Lausanne (EPFL))

Abstract

Magnetic field effects on electrocatalysis have recently gained attention due to the substantial enhancement of the oxygen evolution reaction (OER) on ferromagnetic catalysts. When detecting an enhanced catalytic activity, the effect of magnetic fields on mass transport must be assessed. In this study, we employ a specifically designed magneto-electrochemical system and non-magnetic electrodes to quantify magnetic field effects. Our findings reveal a marginal enhancement in reactions with high reactant availability, such as the OER, whereas substantial boosts exceeding 50% are observed in diffusion limited reactions, exemplified by the oxygen reduction reaction (ORR). Direct visualization and quantification of the whirling motion of ions under a magnetic field underscore the importance of Lorentz forces acting on the electrolyte ions, and demonstrate that bubbles’ movement is a secondary phenomenon. Our results advance the fundamental understanding of magnetic fields in electrocatalysis and unveil new prospects for developing more efficient and sustainable energy conversion technologies.

Suggested Citation

  • Priscila Vensaus & Yunchang Liang & Jean-Philippe Ansermet & Galo J. A. A. Soler-Illia & Magalí Lingenfelder, 2024. "Enhancement of electrocatalysis through magnetic field effects on mass transport," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-46980-8
    DOI: 10.1038/s41467-024-46980-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-46980-8
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-46980-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Tianze Wu & Xiao Ren & Yuanmiao Sun & Shengnan Sun & Guoyu Xian & Günther G. Scherer & Adrian C. Fisher & Daniel Mandler & Joel W. Ager & Alexis Grimaud & Junling Wang & Chengmin Shen & Haitao Yang & , 2021. "Spin pinning effect to reconstructed oxyhydroxide layer on ferromagnetic oxides for enhanced water oxidation," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    2. Darband, Ghasem Barati & Aliofkhazraei, Mahmood & Shanmugam, Sangaraju, 2019. "Recent advances in methods and technologies for enhancing bubble detachment during electrochemical water splitting," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    3. Felipe A. Garcés-Pineda & Marta Blasco-Ahicart & David Nieto-Castro & Núria López & José Ramón Galán-Mascarós, 2019. "Direct magnetic enhancement of electrocatalytic water oxidation in alkaline media," Nature Energy, Nature, vol. 4(6), pages 519-525, June.
    4. Yunchang Liang & Karla Banjac & Kévin Martin & Nicolas Zigon & Seunghwa Lee & Nicolas Vanthuyne & Felipe Andrés Garcés-Pineda & José R. Galán-Mascarós & Xile Hu & Narcis Avarvari & Magalí Lingenfelder, 2022. "Enhancement of electrocatalytic oxygen evolution by chiral molecular functionalization of hybrid 2D electrodes," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Aravind Vadakkayil & Caleb Clever & Karli N. Kunzler & Susheng Tan & Brian P. Bloom & David H. Waldeck, 2023. "Chiral electrocatalysts eclipse water splitting metrics through spin control," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    2. Jie Dai & Yawen Tong & Long Zhao & Zhiwei Hu & Chien-Te Chen & Chang-Yang Kuo & Guangming Zhan & Jiaxian Wang & Xingyue Zou & Qian Zheng & Wei Hou & Ruizhao Wang & Kaiyuan Wang & Rui Zhao & Xiang-Kui , 2024. "Spin polarized Fe1−Ti pairs for highly efficient electroreduction nitrate to ammonia," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Xiao Ren & Tianze Wu & Zizhao Gong & Lulu Pan & Jianling Meng & Haitao Yang & Freyja Bjork Dagbjartsdottir & Adrian Fisher & Hong-Jun Gao & Zhichuan J. Xu, 2023. "The origin of magnetization-caused increment in water oxidation," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    4. Yunchang Liang & Karla Banjac & Kévin Martin & Nicolas Zigon & Seunghwa Lee & Nicolas Vanthuyne & Felipe Andrés Garcés-Pineda & José R. Galán-Mascarós & Xile Hu & Narcis Avarvari & Magalí Lingenfelder, 2022. "Enhancement of electrocatalytic oxygen evolution by chiral molecular functionalization of hybrid 2D electrodes," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    5. Burton, N.A. & Padilla, R.V. & Rose, A. & Habibullah, H., 2021. "Increasing the efficiency of hydrogen production from solar powered water electrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    6. Shiquan Lin & Laipan Zhu & Zhen Tang & Zhong Lin Wang, 2022. "Spin-selected electron transfer in liquid–solid contact electrification," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    7. Shi, Tong & Feng, Hao & Liu, Dong & Zhang, Ying & Li, Qiang, 2022. "High-performance microfluidic electrochemical reactor for efficient hydrogen evolution," Applied Energy, Elsevier, vol. 325(C).
    8. Siran Xu & Sihua Feng & Yue Yu & Dongping Xue & Mengli Liu & Chao Wang & Kaiyue Zhao & Bingjun Xu & Jia-Nan Zhang, 2024. "Dual-site segmentally synergistic catalysis mechanism: boosting CoFeSx nanocluster for sustainable water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    9. Chengwen Li & Ying-Bo Shao & Xi Gao & Zhiyuan Ren & Chenhao Guo & Meng Li & Xin Li, 2023. "Enantioselective synthesis of chiral quinohelicenes through sequential organocatalyzed Povarov reaction and oxidative aromatization," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    10. Jonas A. Krieger & Samuel Stolz & Iñigo Robredo & Kaustuv Manna & Emily C. McFarlane & Mihir Date & Banabir Pal & Jiabao Yang & Eduardo B. Guedes & J. Hugo Dil & Craig M. Polley & Mats Leandersson & C, 2024. "Weyl spin-momentum locking in a chiral topological semimetal," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    11. Minhua Ai & Lun Pan & Chengxiang Shi & Zhen-Feng Huang & Xiangwen Zhang & Wenbo Mi & Ji-Jun Zou, 2023. "Spin selection in atomic-level chiral metal oxide for photocatalysis," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    12. Luis Camargo & Daniel Comas & Yulineth Cardenas Escorcia & Anibal Alviz-Meza & Gaylord Carrillo Caballero & Ivan Portnoy, 2022. "Bibliometric Analysis of Global Trends around Hydrogen Production Based on the Scopus Database in the Period 2011–2021," Energies, MDPI, vol. 16(1), pages 1-25, December.
    13. El-Nowihy, Ghada H. & Abdellatif, Mohammad M. & El-Deab, Mohamed S., 2024. "Magnetic field-assisted water splitting at ternary NiCoFe magnetic Nanocatalysts: Optimization study," Renewable Energy, Elsevier, vol. 226(C).
    14. Hyungsoo Lee & Chan Uk Lee & Juwon Yun & Chang-Seop Jeong & Wooyong Jeong & Jaehyun Son & Young Sun Park & Subin Moon & Soobin Lee & Jun Hwan Kim & Jooho Moon, 2024. "A dual spin-controlled chiral two-/three-dimensional perovskite artificial leaf for efficient overall photoelectrochemical water splitting," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    15. Li, Zihan & Lv, Zunhang & Liu, Xin & Wang, Guixue & Lin, Yusheng & Xie, Guangwen & Jiang, Luhua, 2021. "Magnetic-field guided synthesis of highly active Ni–S–CoFe2O4 electrocatalysts for oxygen evolution reaction," Renewable Energy, Elsevier, vol. 165(P1), pages 612-618.
    16. Marshet Getaye Sendeku & Karim Harrath & Fekadu Tsegaye Dajan & Binglan Wu & Sabir Hussain & Ning Gao & Xueying Zhan & Ying Yang & Zhenxing Wang & Chen Chen & Weiqiang Liu & Fengmei Wang & Haohong Dua, 2024. "Deciphering in-situ surface reconstruction in two-dimensional CdPS3 nanosheets for efficient biomass hydrogenation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    17. Siliu Lyu & Chenxi Guo & Jianing Wang & Zhongjian Li & Bin Yang & Lecheng Lei & Liping Wang & Jianping Xiao & Tao Zhang & Yang Hou, 2022. "Exceptional catalytic activity of oxygen evolution reaction via two-dimensional graphene multilayer confined metal-organic frameworks," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    18. Qian, Guangfu & Mo, Yanshan & Yu, Chen & Zhang, Hao & Yu, Tianqi & Luo, Lin & Yin, Shibin, 2020. "Free-standing bimetallic CoNiTe2 nanosheets as efficient catalysts with high stability at large current density for oxygen evolution reaction," Renewable Energy, Elsevier, vol. 162(C), pages 2190-2196.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-46980-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.