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High-performance microfluidic electrochemical reactor for efficient hydrogen evolution

Author

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  • Shi, Tong
  • Feng, Hao
  • Liu, Dong
  • Zhang, Ying
  • Li, Qiang

Abstract

Hydrogen production from water electrolysis provides an effective bridge between the existing energy system and the layout of green renewable energy. Electrochemical hydrogen gas evolution on the electrode surface will occupy the limited active sites thus significantly increasing the reaction overpotential. It is crucial to study and optimize the bubble behavior on the electrode surface to improve reaction efficiency and lower the energy loss. Herein, a microfluidic electrochemical reactor (MER) has been constructed to optimize the surface gas-liquid two-phase flow behavior during the gas evolution process. The obtained results demonstrate the feasibility of microfluidic design in manipulating the bubble behavior at the electrode interface accompanied with the self-generated gas-liquid two-phase flow, which can directly reduce the overpotentials by facilitating the mass transfer and refreshing catalytic active sites. Compared with conventional H-cell, state-of-the-art efficient and stable performance of hydrogen evolution has been achieved, where the increase in current density was more than 5 times. This work reveals a new strategy for guiding the design of the electrochemical reactor for water splitting.

Suggested Citation

  • Shi, Tong & Feng, Hao & Liu, Dong & Zhang, Ying & Li, Qiang, 2022. "High-performance microfluidic electrochemical reactor for efficient hydrogen evolution," Applied Energy, Elsevier, vol. 325(C).
    • Handle: RePEc:eee:appene:v:325:y:2022:i:c:s0306261922011515
    DOI: 10.1016/j.apenergy.2022.119887
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    References listed on IDEAS

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    1. Ju, HyungKuk & Badwal, Sukhvinder & Giddey, Sarbjit, 2018. "A comprehensive review of carbon and hydrocarbon assisted water electrolysis for hydrogen production," Applied Energy, Elsevier, vol. 231(C), pages 502-533.
    2. Katharina Brinkert & Matthias H. Richter & Ömer Akay & Janine Liedtke & Michael Giersig & Katherine T. Fountaine & Hans-Joachim Lewerenz, 2018. "Efficient solar hydrogen generation in microgravity environment," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    3. Guo, Liejin & Chen, Yubin & Su, Jinzhan & Liu, Maochang & Liu, Ya, 2019. "Obstacles of solar-powered photocatalytic water splitting for hydrogen production: A perspective from energy flow and mass flow," Energy, Elsevier, vol. 172(C), pages 1079-1086.
    4. Fang Yu & Haiqing Zhou & Yufeng Huang & Jingying Sun & Fan Qin & Jiming Bao & William A. Goddard & Shuo Chen & Zhifeng Ren, 2018. "High-performance bifunctional porous non-noble metal phosphide catalyst for overall water splitting," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    5. Darband, Ghasem Barati & Aliofkhazraei, Mahmood & Shanmugam, Sangaraju, 2019. "Recent advances in methods and technologies for enhancing bubble detachment during electrochemical water splitting," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    6. Samir De, Biswajit & Cunningham, Joshua & Khare, Neeraj & Luo, Jing-Li & Elias, Anastasia & Basu, Suddhasatwa, 2022. "Hydrogen generation and utilization in a two-phase flow membraneless microfluidic electrolyzer-fuel cell tandem operation for micropower application," Applied Energy, Elsevier, vol. 305(C).
    7. Jakob Kibsgaard & Ib Chorkendorff, 2019. "Considerations for the scaling-up of water splitting catalysts," Nature Energy, Nature, vol. 4(6), pages 430-433, June.
    8. Kang, Zhenye & Wang, Hao & Liu, Yanrong & Mo, Jingke & Wang, Min & Li, Jing & Tian, Xinlong, 2022. "Exploring and understanding the internal voltage losses through catalyst layers in proton exchange membrane water electrolysis devices," Applied Energy, Elsevier, vol. 317(C).
    9. Kaya, Mehmet Fatih & Demir, Nesrin & Rees, Neil V. & El-Kharouf, Ahmad, 2020. "Improving PEM water electrolyser’s performance by magnetic field application," Applied Energy, Elsevier, vol. 264(C).
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