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Enhancement of electrocatalytic oxygen evolution by chiral molecular functionalization of hybrid 2D electrodes

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  • Yunchang Liang

    (École Polytechnique Fédérale de Lausanne (EPFL)
    Institute of Physics (IPHYS), École Polytechnique Fédérale de Lausanne (EPFL))

  • Karla Banjac

    (École Polytechnique Fédérale de Lausanne (EPFL)
    Institute of Physics (IPHYS), École Polytechnique Fédérale de Lausanne (EPFL))

  • Kévin Martin

    (Univ Angers, CNRS, MOLTECH-Anjou, SFR MATRIX)

  • Nicolas Zigon

    (Univ Angers, CNRS, MOLTECH-Anjou, SFR MATRIX)

  • Seunghwa Lee

    (École Polytechnique Fédérale de Lausanne (EPFL)
    Changwon National University)

  • Nicolas Vanthuyne

    (Aix Marseille Université, CNRS, Centrale Marseille, iSm2)

  • Felipe Andrés Garcés-Pineda

    (The Barcelona Institute of Science and Technology (BIST))

  • José R. Galán-Mascarós

    (The Barcelona Institute of Science and Technology (BIST)
    Catalan Institution for Research and Advanced Studies (ICREA))

  • Xile Hu

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Narcis Avarvari

    (Univ Angers, CNRS, MOLTECH-Anjou, SFR MATRIX)

  • Magalí Lingenfelder

    (École Polytechnique Fédérale de Lausanne (EPFL)
    Institute of Physics (IPHYS), École Polytechnique Fédérale de Lausanne (EPFL))

Abstract

A sustainable future requires highly efficient energy conversion and storage processes, where electrocatalysis plays a crucial role. The activity of an electrocatalyst is governed by the binding energy towards the reaction intermediates, while the scaling relationships prevent the improvement of a catalytic system over its volcano-plot limits. To overcome these limitations, unconventional methods that are not fully determined by the surface binding energy can be helpful. Here, we use organic chiral molecules, i.e., hetero-helicenes such as thiadiazole-[7]helicene and bis(thiadiazole)-[8]helicene, to boost the oxygen evolution reaction (OER) by up to ca. 130 % (at the potential of 1.65 V vs. RHE) at state-of-the-art 2D Ni- and NiFe-based catalysts via a spin-polarization mechanism. Our results show that chiral molecule-functionalization is able to increase the OER activity of catalysts beyond the volcano limits. A guideline for optimizing the catalytic activity via chiral molecular functionalization of hybrid 2D electrodes is given.

Suggested Citation

  • Yunchang Liang & Karla Banjac & Kévin Martin & Nicolas Zigon & Seunghwa Lee & Nicolas Vanthuyne & Felipe Andrés Garcés-Pineda & José R. Galán-Mascarós & Xile Hu & Narcis Avarvari & Magalí Lingenfelder, 2022. "Enhancement of electrocatalytic oxygen evolution by chiral molecular functionalization of hybrid 2D electrodes," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31096-8
    DOI: 10.1038/s41467-022-31096-8
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    References listed on IDEAS

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    2. Jonas A. Krieger & Samuel Stolz & Iñigo Robredo & Kaustuv Manna & Emily C. McFarlane & Mihir Date & Banabir Pal & Jiabao Yang & Eduardo B. Guedes & J. Hugo Dil & Craig M. Polley & Mats Leandersson & C, 2024. "Weyl spin-momentum locking in a chiral topological semimetal," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    3. Minhua Ai & Lun Pan & Chengxiang Shi & Zhen-Feng Huang & Xiangwen Zhang & Wenbo Mi & Ji-Jun Zou, 2023. "Spin selection in atomic-level chiral metal oxide for photocatalysis," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    4. Priscila Vensaus & Yunchang Liang & Jean-Philippe Ansermet & Galo J. A. A. Soler-Illia & Magalí Lingenfelder, 2024. "Enhancement of electrocatalysis through magnetic field effects on mass transport," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Chengwen Li & Ying-Bo Shao & Xi Gao & Zhiyuan Ren & Chenhao Guo & Meng Li & Xin Li, 2023. "Enantioselective synthesis of chiral quinohelicenes through sequential organocatalyzed Povarov reaction and oxidative aromatization," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    6. Aravind Vadakkayil & Caleb Clever & Karli N. Kunzler & Susheng Tan & Brian P. Bloom & David H. Waldeck, 2023. "Chiral electrocatalysts eclipse water splitting metrics through spin control," Nature Communications, Nature, vol. 14(1), pages 1-7, December.

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