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Deciphering in-situ surface reconstruction in two-dimensional CdPS3 nanosheets for efficient biomass hydrogenation

Author

Listed:
  • Marshet Getaye Sendeku

    (Beijing University of Chemical Technology
    Research Institute of Tsinghua University in Shenzhen
    National Center for Nanoscience and Technology)

  • Karim Harrath

    (Southern University of Science and Technology)

  • Fekadu Tsegaye Dajan

    (National Center for Nanoscience and Technology)

  • Binglan Wu

    (National Center for Nanoscience and Technology
    Northwest University)

  • Sabir Hussain

    (University College Cork)

  • Ning Gao

    (National Center for Nanoscience and Technology)

  • Xueying Zhan

    (National Center for Nanoscience and Technology)

  • Ying Yang

    (Northwest University)

  • Zhenxing Wang

    (National Center for Nanoscience and Technology)

  • Chen Chen

    (Tsinghua University)

  • Weiqiang Liu

    (Research Institute of Tsinghua University in Shenzhen)

  • Fengmei Wang

    (Beijing University of Chemical Technology
    National Center for Nanoscience and Technology)

  • Haohong Duan

    (Tsinghua University)

  • Xiaoming Sun

    (Beijing University of Chemical Technology
    Research Institute of Tsinghua University in Shenzhen)

Abstract

Steering on the intrinsic active site of an electrode material is essential for efficient electrochemical biomass upgrading to valuable chemicals with high selectivity. Herein, we show that an in-situ surface reconstruction of a two-dimensional layered CdPS3 nanosheet electrocatalyst, triggered by electrolyte, facilitates efficient 5-hydroxymethylfurfural (HMF) hydrogenation to 2,5-bis(hydroxymethyl)furan (BHMF) under ambient condition. The in-situ Raman spectroscopy and comprehensive post-mortem catalyst characterizations evidence the construction of a surface-bounded CdS layer on CdPS3 to form CdPS3/CdS heterostructure. This electrocatalyst demonstrates promising catalytic activity, achieving a Faradaic efficiency for BHMF reaching 91.3 ± 2.3 % and a yield of 4.96 ± 0.16 mg/h at − 0.7 V versus reversible hydrogen electrode. Density functional theory calculations reveal that the in-situ generated CdPS3/CdS interface plays a pivotal role in optimizing the adsorption of HMF* and H* intermediate, thus facilitating the HMF hydrogenation process. Furthermore, the reconstructed CdPS3/CdS heterostructure cathode, when coupled with MnCo2O4.5 anode, enables simultaneous BHMF and formate synthesis from HMF and glycerol substrates with high efficiency.

Suggested Citation

  • Marshet Getaye Sendeku & Karim Harrath & Fekadu Tsegaye Dajan & Binglan Wu & Sabir Hussain & Ning Gao & Xueying Zhan & Ying Yang & Zhenxing Wang & Chen Chen & Weiqiang Liu & Fengmei Wang & Haohong Dua, 2024. "Deciphering in-situ surface reconstruction in two-dimensional CdPS3 nanosheets for efficient biomass hydrogenation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-49510-8
    DOI: 10.1038/s41467-024-49510-8
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    References listed on IDEAS

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