IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-37599-2.html
   My bibliography  Save this article

Direct synthesis of extra-heavy olefins from carbon monoxide and water

Author

Listed:
  • Chuanhao Wang

    (University of Science and Technology of China)

  • Junjie Du

    (University of Science and Technology of China)

  • Lin Zeng

    (University of Science and Technology of China)

  • Zhongling Li

    (University of Science and Technology of China)

  • Yizhou Dai

    (University of Science and Technology of China)

  • Xu Li

    (University of Science and Technology of China)

  • Zijun Peng

    (University of Science and Technology of China)

  • Wenlong Wu

    (University of Science and Technology of China)

  • Hongliang Li

    (University of Science and Technology of China)

  • Jie Zeng

    (University of Science and Technology of China
    Anhui University of Technology)

Abstract

Extra-heavy olefins (C12+=), feedstocks to synthesize a wide range of value-added products, are conventionally generated from fossil resources via energy-intensive wax cracking or multi-step processes. Fischer-Tropsch synthesis with sustainably obtained syngas as feed-in provides a potential way to produce C12+=, though there is a trade-off between enhancing C-C coupling and suppressing further hydrogenation of olefins. Herein, we achieve selective production of C12+= via the overall conversion of CO and water, denoted as Kölbel-Engelhardt synthesis (KES), in polyethylene glycol (PEG) over a mixture of Pt/Mo2N and Ru particles. KES provides a continuously high CO/H2 ratio, thermodynamically favoring chain propagation and olefin formation. PEG serves as a selective extraction agent to hinder hydrogenation of olefins. Under an optimal condition, the yield ratio of CO2 to hydrocarbons reaches the theoretical minimum, and the C12+= yield reaches its maximum of 1.79 mmol with a selectivity (among hydrocarbons) of as high as 40.4%.

Suggested Citation

  • Chuanhao Wang & Junjie Du & Lin Zeng & Zhongling Li & Yizhou Dai & Xu Li & Zijun Peng & Wenlong Wu & Hongliang Li & Jie Zeng, 2023. "Direct synthesis of extra-heavy olefins from carbon monoxide and water," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37599-2
    DOI: 10.1038/s41467-023-37599-2
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-37599-2
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-37599-2?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Lili Lin & Wu Zhou & Rui Gao & Siyu Yao & Xiao Zhang & Wenqian Xu & Shijian Zheng & Zheng Jiang & Qiaolin Yu & Yong-Wang Li & Chuan Shi & Xiao-Dong Wen & Ding Ma, 2017. "Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts," Nature, Nature, vol. 544(7648), pages 80-83, April.
    2. Zhenhua Zhang & Xuanye Chen & Jincan Kang & Zongyou Yu & Jie Tian & Zhongmiao Gong & Aiping Jia & Rui You & Kun Qian & Shun He & Botao Teng & Yi Cui & Ye Wang & Wenhua Zhang & Weixin Huang, 2021. "The active sites of Cu–ZnO catalysts for water gas shift and CO hydrogenation reactions," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    3. Yaru Zhang & Xiaoli Yang & Xiaofeng Yang & Hongmin Duan & Haifeng Qi & Yang Su & Binglian Liang & Huabing Tao & Bin Liu & De Chen & Xiong Su & Yanqiang Huang & Tao Zhang, 2020. "Tuning reactivity of Fischer–Tropsch synthesis by regulating TiOx overlayer over Ru/TiO2 nanocatalysts," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    4. Yao Xu & Jing Li & Wenjing Li & Weizhen Li & Xiaochen Zhang & Yue Zhao & Jinglin Xie & Xiaoping Wang & Xi Liu & Yongwang Li & Dequan Xiao & Zhen Yin & Yong Cao & Ding Ma, 2019. "Direct conversion of CO and H2O into liquid fuels under mild conditions," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
    5. Jovana Zecevic & Gina Vanbutsele & Krijn P. de Jong & Johan A. Martens, 2015. "Nanoscale intimacy in bifunctional catalysts for selective conversion of hydrocarbons," Nature, Nature, vol. 528(7581), pages 245-248, December.
    6. Xiao Zhang & Mengtao Zhang & Yuchen Deng & Mingquan Xu & Luca Artiglia & Wen Wen & Rui Gao & Bingbing Chen & Siyu Yao & Xiaochen Zhang & Mi Peng & Jie Yan & Aowen Li & Zheng Jiang & Xingyu Gao & Sufen, 2021. "A stable low-temperature H2-production catalyst by crowding Pt on α-MoC," Nature, Nature, vol. 589(7842), pages 396-401, January.
    7. Liangshu Zhong & Fei Yu & Yunlei An & Yonghui Zhao & Yuhan Sun & Zhengjia Li & Tiejun Lin & Yanjun Lin & Xingzhen Qi & Yuanyuan Dai & Lin Gu & Jinsong Hu & Shifeng Jin & Qun Shen & Hui Wang, 2016. "Cobalt carbide nanoprisms for direct production of lower olefins from syngas," Nature, Nature, vol. 538(7623), pages 84-87, October.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Hao Meng & Yusen Yang & Tianyao Shen & Zhiming Yin & Lei Wang & Wei Liu & Pan Yin & Zhen Ren & Lirong Zheng & Jian Zhang & Feng-Shou Xiao & Min Wei, 2023. "Designing Cu0−Cu+ dual sites for improved C−H bond fracture towards methanol steam reforming," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Hao Meng & Yusen Yang & Tianyao Shen & Wei Liu & Lei Wang & Pan Yin & Zhen Ren & Yiming Niu & Bingsen Zhang & Lirong Zheng & Hong Yan & Jian Zhang & Feng-Shou Xiao & Min Wei & Xue Duan, 2023. "A strong bimetal-support interaction in ethanol steam reforming," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    3. Hailing Yu & Caiqi Wang & Xin Xin & Yao Wei & Shenggang Li & Yunlei An & Fanfei Sun & Tiejun Lin & Liangshu Zhong, 2024. "Engineering ZrO2–Ru interface to boost Fischer-Tropsch synthesis to olefins," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    4. Wenlong Wu & Jiahua Luo & Jiankang Zhao & Menglin Wang & Lei Luo & Sunpei Hu & Bingxuan He & Chao Ma & Hongliang Li & Jie Zeng, 2024. "Facet sensitivity of iron carbides in Fischer-Tropsch synthesis," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Tang, Xincheng & Wu, Yanxiao & Fang, Zhenchang & Dong, Xinyu & Du, Zhongxuan & Deng, Bicai & Sun, Chunhua & Zhou, Feng & Qiao, Xinqi & Li, Xinling, 2024. "Syntheses, catalytic performances and DFT investigations: A recent review of copper-based catalysts of methanol steam reforming for hydrogen production," Energy, Elsevier, vol. 295(C).
    6. Zhu, Mengshu & Ai, Xiaomeng & Fang, Jiakun & Cui, Shichang & Wu, Kejing & Zheng, Lufan & Wen, Jinyu, 2024. "Optimal scheduling of hydrogen energy hub for stable demand with uncertain photovoltaic and biomass," Applied Energy, Elsevier, vol. 360(C).
    7. Na Li & Yifeng Zhu & Feng Jiao & Xiulian Pan & Qike Jiang & Jun Cai & Yifan Li & Wei Tong & Changqi Xu & Shengcheng Qu & Bing Bai & Dengyun Miao & Zhi Liu & Xinhe Bao, 2022. "Steering the reaction pathway of syngas-to-light olefins with coordination unsaturated sites of ZnGaOx spinel," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    8. Fei Qian & Jiawei Bai & Yi Cai & Hui Yang & Xue-Min Cao & Xingchen Liu & Xing-Wu Liu & Yong Yang & Yong-Wang Li & Ding Ma & Xiao-Dong Wen, 2024. "Stabilized ε-Fe2C catalyst with Mn tuning to suppress C1 byproduct selectivity for high-temperature olefin synthesis," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    9. Lin Chen & Chang Yu & Xuedan Song & Junting Dong & Jiawei Mu & Jieshan Qiu, 2024. "Integrated electrochemical and chemical system for ampere-level production of terephthalic acid alternatives and hydrogen," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    10. Bing Deng & Zhe Wang & Weiyin Chen & John Tianci Li & Duy Xuan Luong & Robert A. Carter & Guanhui Gao & Boris I. Yakobson & Yufeng Zhao & James M. Tour, 2022. "Phase controlled synthesis of transition metal carbide nanocrystals by ultrafast flash Joule heating," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    11. Konstantinos Kappis & Joan Papavasiliou & George Avgouropoulos, 2021. "Methanol Reforming Processes for Fuel Cell Applications," Energies, MDPI, vol. 14(24), pages 1-30, December.
    12. Wang, Yancheng & Liu, Haiyu & Mei, Deqing & Yu, Shizheng, 2022. "Direct ink writing of 3D SiC scaffold as catalyst support for thermally autonomous methanol steam reforming microreactor," Renewable Energy, Elsevier, vol. 187(C), pages 923-932.
    13. Rongkui Su & Hongguo Zhang & Feng Chen & Zhenxing Wang & Lei Huang, 2022. "Applications of Single Atom Catalysts for Environmental Management," IJERPH, MDPI, vol. 19(18), pages 1-6, September.
    14. Jiaqi Zhao & Jinjia Liu & Zhenhua Li & Kaiwen Wang & Run Shi & Pu Wang & Qing Wang & Geoffrey I. N. Waterhouse & Xiaodong Wen & Tierui Zhang, 2023. "Ruthenium-cobalt single atom alloy for CO photo-hydrogenation to liquid fuels at ambient pressures," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    15. Xin, Yanbin & Sun, Bing & Zhu, Xiaomei & Yan, Zhiyu & Zhao, Xiaotong & Sun, Xiaohang, 2017. "Hydrogen production from ethanol decomposition by pulsed discharge with needle-net configurations," Applied Energy, Elsevier, vol. 206(C), pages 126-133.
    16. Hailing Yu & Caiqi Wang & Tiejun Lin & Yunlei An & Yuchen Wang & Qingyu Chang & Fei Yu & Yao Wei & Fanfei Sun & Zheng Jiang & Shenggang Li & Yuhan Sun & Liangshu Zhong, 2022. "Direct production of olefins from syngas with ultrahigh carbon efficiency," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    17. Xin, Yanbin & Sun, Bing & Liu, Jingyu & Wang, Quanli & Zhu, Xiaomei & Yan, Zhiyu, 2021. "Effects of electrode configurations, solution pH, TiO2 addition on hydrogen production by in-liquid discharge plasma," Renewable Energy, Elsevier, vol. 171(C), pages 728-734.
    18. Zhiqiang Zheng & Lu Qi & Xiaoyu Luan & Shuya Zhao & Yurui Xue & Yuliang Li, 2024. "Growing highly ordered Pt and Mn bimetallic single atomic layers over graphdiyne," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    19. Yan, Xianyao & Duan, Chenyu & Yu, Shuihua & Dai, Bing & Sun, Chaoying & Chu, Huaqiang, 2024. "Recent advances on CO2 reduction reactions using single-atom catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 190(PB).
    20. Pavel A. Kots & Tianjun Xie & Brandon C. Vance & Caitlin M. Quinn & Matheus Dorneles Mello & J. Anibal Boscoboinik & Cong Wang & Pawan Kumar & Eric A. Stach & Nebojsa S. Marinkovic & Lu Ma & Steven N., 2022. "Electronic modulation of metal-support interactions improves polypropylene hydrogenolysis over ruthenium catalysts," Nature Communications, Nature, vol. 13(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37599-2. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.