IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-51937-y.html
   My bibliography  Save this article

Integrated electrochemical and chemical system for ampere-level production of terephthalic acid alternatives and hydrogen

Author

Listed:
  • Lin Chen

    (Dalian University of Technology)

  • Chang Yu

    (Dalian University of Technology)

  • Xuedan Song

    (Dalian University of Technology)

  • Junting Dong

    (Dalian University of Technology)

  • Jiawei Mu

    (Dalian University of Technology)

  • Jieshan Qiu

    (Beijing University of Chemical Technology)

Abstract

2,5-Furandicarboxylic acid (FDCA), a critical polymer platform molecule that can potentially replace terephthalic acid, coupled hydrogen coproduction holds great prospects via electrolysis. However, the electrosynthesis of FDCA faces challenges in product separation from complex electrolytes and unclear electrochemical and nonelectrochemical reactions during the 5-hydroxymethylfurfural (HMF) oxidation. Herein, an electrochemical/chemical integrated system of alkaline HMF-H2O co-electrolysis is proposed, achieving distillation-free synthesis of high-purity FDCA by acidic separation/purification and hydrogen coproduction. This system achieves ampere-level current densities of 812 and 1290 mA cm−2 at potentials of 1.50 and 1.60 V, with nearly 100% FDCA yield and HMF conversion in only 6 min at 1.50 V. The electrooxidation of HMF involves a coupling of electrochemical and nonelectrochemical reactions, wherein the aldehyde group is dehydrogenated and oxidized, followed by dehydrated and oxidized of the hydroxyl group, ultimately forming FDCA. Concurrently, nonelectrochemical reactions of intermolecular electron transfer occur in HMF and aldehyde group-containing intermediates.

Suggested Citation

  • Lin Chen & Chang Yu & Xuedan Song & Junting Dong & Jiawei Mu & Jieshan Qiu, 2024. "Integrated electrochemical and chemical system for ampere-level production of terephthalic acid alternatives and hydrogen," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51937-y
    DOI: 10.1038/s41467-024-51937-y
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-51937-y
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-51937-y?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Ganceng Yang & Yanqing Jiao & Haijing Yan & Ying Xie & Chungui Tian & Aiping Wu & Yu Wang & Honggang Fu, 2022. "Unraveling the mechanism for paired electrocatalysis of organics with water as a feedstock," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    2. Lili Lin & Wu Zhou & Rui Gao & Siyu Yao & Xiao Zhang & Wenqian Xu & Shijian Zheng & Zheng Jiang & Qiaolin Yu & Yong-Wang Li & Chuan Shi & Xiao-Dong Wen & Ding Ma, 2017. "Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts," Nature, Nature, vol. 544(7648), pages 80-83, April.
    3. Ling Zhou & Daying Guo & Lianhui Wu & Zhixi Guan & Chao Zou & Huile Jin & Guoyong Fang & Xi’an Chen & Shun Wang, 2024. "A restricted dynamic surface self-reconstruction toward high-performance of direct seawater oxidation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    4. Shanlin Li & Ruguang Ma & Jingcong Hu & Zichuang Li & Lijia Liu & Xunlu Wang & Yue Lu & George E. Sterbinsky & Shuhu Liu & Lei Zheng & Jie Liu & Danmin Liu & Jiacheng Wang, 2022. "Coordination environment tuning of nickel sites by oxyanions to optimize methanol electro-oxidation activity," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    5. Zuyun He & Jinwoo Hwang & Zhiheng Gong & Mengzhen Zhou & Nian Zhang & Xiongwu Kang & Jeong Woo Han & Yan Chen, 2022. "Promoting biomass electrooxidation via modulating proton and oxygen anion deintercalation in hydroxide," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    6. L. Jiang & A. Gonzalez-Diaz & J. Ling-Chin & A. Malik & A. P. Roskilly & A. J. Smallbone, 2020. "PEF plastic synthesized from industrial carbon dioxide and biowaste," Nature Sustainability, Nature, vol. 3(9), pages 761-767, September.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Suiqin Li & Shibin Wang & Yuhang Wang & Jiahui He & Kai Li & James B. Gerken & Shannon S. Stahl & Xing Zhong & Jianguo Wang, 2025. "Synergistic enhancement of electrochemical alcohol oxidation by combining NiV-layered double hydroxide with an aminoxyl radical," Nature Communications, Nature, vol. 16(1), pages 1-14, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Qiqi Mao & Xu Mu & Wenxin Wang & Kai Deng & Hongjie Yu & Ziqiang Wang & You Xu & Liang Wang & Hongjing Wang, 2023. "Atomically dispersed Cu coordinated Rh metallene arrays for simultaneously electrochemical aniline synthesis and biomass upgrading," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Jun Qi & Yadong Du & Qi Yang & Na Jiang & Jiachun Li & Yi Ma & Yangjun Ma & Xin Zhao & Jieshan Qiu, 2023. "Energy-saving and product-oriented hydrogen peroxide electrosynthesis enabled by electrochemistry pairing and product engineering," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    3. Ming Yang & Yimin Jiang & Chung-Li Dong & Leitao Xu & Yutong Huang & Shifan Leng & Yandong Wu & Yongxiang Luo & Wei Chen & Ta Thi Thuy Nga & Shuangyin Wang & Yuqin Zou, 2024. "A self-reactivated PdCu catalyst for aldehyde electro-oxidation with anodic hydrogen production," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    4. Bailin Tian & Fangyuan Wang & Pan Ran & Luhan Dai & Yang Lv & Yuxia Sun & Zhangyan Mu & Yamei Sun & Lingyu Tang & William A. Goddard & Mengning Ding, 2024. "Parameterization and quantification of two key operando physio-chemical descriptors for water-assisted electro-catalytic organic oxidation," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    5. Sethu Sundar Pethaiah & Kishor Kumar Sadasivuni & Arunkumar Jayakumar & Deepalekshmi Ponnamma & Chandra Sekhar Tiwary & Gangadharan Sasikumar, 2020. "Methanol Electrolysis for Hydrogen Production Using Polymer Electrolyte Membrane: A Mini-Review," Energies, MDPI, vol. 13(22), pages 1-17, November.
    6. Yuantao Peng & Jie Yang & Chenqiang Deng & Jin Deng & Li Shen & Yao Fu, 2023. "Acetolysis of waste polyethylene terephthalate for upcycling and life-cycle assessment study," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    7. Li, Wenjia & Hao, Yong, 2017. "Efficient solar power generation combining photovoltaics and mid-/low-temperature methanol thermochemistry," Applied Energy, Elsevier, vol. 202(C), pages 377-385.
    8. Si, H. & Chen, S. & Xie, R.Y. & Zeng, W.Q. & Zhang, X.J. & Jiang, L., 2024. "Techno-economic analysis on a hybrid system with carbon capture and energy storage for liquefied natural gas cold energy utilization," Energy, Elsevier, vol. 308(C).
    9. Suiqin Li & Shibin Wang & Yuhang Wang & Jiahui He & Kai Li & James B. Gerken & Shannon S. Stahl & Xing Zhong & Jianguo Wang, 2025. "Synergistic enhancement of electrochemical alcohol oxidation by combining NiV-layered double hydroxide with an aminoxyl radical," Nature Communications, Nature, vol. 16(1), pages 1-14, December.
    10. Evgeniy Yurevich Titov & Ivan Vasilevich Bodrikov & Anton Igorevich Serov & Yuriy Alekseevich Kurskii & Dmitry Yurievich Titov & Evgenia Ruslanovna Bodrikova, 2022. "Liquid-Phase Non-Thermal Plasma Discharge for Fuel Oil Processing," Energies, MDPI, vol. 15(9), pages 1-9, May.
    11. Konstantinos Kappis & Joan Papavasiliou & George Avgouropoulos, 2021. "Methanol Reforming Processes for Fuel Cell Applications," Energies, MDPI, vol. 14(24), pages 1-30, December.
    12. Chen, S. & Shi, W.K. & Yong, J.Y. & Zhuang, Y. & Lin, Q.Y. & Gao, N. & Zhang, X.J. & Jiang, L., 2023. "Numerical study on a structured packed adsorption bed for indoor direct air capture," Energy, Elsevier, vol. 282(C).
    13. Wang, Yancheng & Liu, Haiyu & Mei, Deqing & Yu, Shizheng, 2022. "Direct ink writing of 3D SiC scaffold as catalyst support for thermally autonomous methanol steam reforming microreactor," Renewable Energy, Elsevier, vol. 187(C), pages 923-932.
    14. Tang, Xincheng & Wu, Yanxiao & Fang, Zhenchang & Dong, Xinyu & Du, Zhongxuan & Deng, Bicai & Sun, Chunhua & Zhou, Feng & Qiao, Xinqi & Li, Xinling, 2024. "Syntheses, catalytic performances and DFT investigations: A recent review of copper-based catalysts of methanol steam reforming for hydrogen production," Energy, Elsevier, vol. 295(C).
    15. Rongkui Su & Hongguo Zhang & Feng Chen & Zhenxing Wang & Lei Huang, 2022. "Applications of Single Atom Catalysts for Environmental Management," IJERPH, MDPI, vol. 19(18), pages 1-6, September.
    16. Zhang, Chen & Zhang, Xinqi & Su, Tingyu & Zhang, Yiheng & Wang, Liwei & Zhu, Xuancan, 2023. "Modification schemes of efficient sorbents for trace CO2 capture," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
    17. Xin, Yanbin & Sun, Bing & Zhu, Xiaomei & Yan, Zhiyu & Zhao, Xiaotong & Sun, Xiaohang, 2017. "Hydrogen production from ethanol decomposition by pulsed discharge with needle-net configurations," Applied Energy, Elsevier, vol. 206(C), pages 126-133.
    18. Hao Meng & Yusen Yang & Tianyao Shen & Wei Liu & Lei Wang & Pan Yin & Zhen Ren & Yiming Niu & Bingsen Zhang & Lirong Zheng & Hong Yan & Jian Zhang & Feng-Shou Xiao & Min Wei & Xue Duan, 2023. "A strong bimetal-support interaction in ethanol steam reforming," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    19. Hao Meng & Yusen Yang & Tianyao Shen & Zhiming Yin & Lei Wang & Wei Liu & Pan Yin & Zhen Ren & Lirong Zheng & Jian Zhang & Feng-Shou Xiao & Min Wei, 2023. "Designing Cu0−Cu+ dual sites for improved C−H bond fracture towards methanol steam reforming," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    20. Lin, Min & Yan, Yuhao & Jiang, Daxin & Zhou, Shaomin & Zhan, Lulu & Li, Rui & Song, Xianliang & Wu, Yulong, 2024. "Catalytic transfer hydrogenation with methanol over Pt/C catalyst for synergistic hydrothermal hydrogenation of palmitic acid," Energy, Elsevier, vol. 304(C).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51937-y. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.