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Methanol Reforming Processes for Fuel Cell Applications

Author

Listed:
  • Konstantinos Kappis

    (Department of Materials Science, University of Patras, GR-26504 Patras, Greece)

  • Joan Papavasiliou

    (Department of Materials Science, University of Patras, GR-26504 Patras, Greece
    Foundation for Research and Technology-Hellas (FORTH), Institute of Chemical Engineering Sciences (ICE-HT), P.O. Box 1414, GR-26504 Patras, Greece)

  • George Avgouropoulos

    (Department of Materials Science, University of Patras, GR-26504 Patras, Greece)

Abstract

Hydrogen production through methanol reforming processes has been stimulated over the years due to increasing interest in fuel cell technology and clean energy production. Among different types of methanol reforming, the steam reforming of methanol has attracted great interest as reformate gas stream where high concentration of hydrogen is produced with a negligible amount of carbon monoxide. In this review, recent progress of the main reforming processes of methanol towards hydrogen production is summarized. Different catalytic systems are reviewed for the steam reforming of methanol: mainly copper- and group 8–10-based catalysts, highlighting the catalytic key properties, while the promoting effect of the latter group in copper activity and selectivity is also discussed. The effect of different preparation methods, different promoters/stabilizers, and the formation mechanism is analyzed. Moreover, the integration of methanol steam reforming process and the high temperature–polymer electrolyte membrane fuel cells (HT-PEMFCs) for the development of clean energy production is discussed.

Suggested Citation

  • Konstantinos Kappis & Joan Papavasiliou & George Avgouropoulos, 2021. "Methanol Reforming Processes for Fuel Cell Applications," Energies, MDPI, vol. 14(24), pages 1-30, December.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:24:p:8442-:d:702293
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    References listed on IDEAS

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    2. Deng, Yimin & Li, Shuo & Appels, Lise & Zhang, Huili & Sweygers, Nick & Baeyens, Jan & Dewil, Raf, 2023. "Steam reforming of ethanol by non-noble metal catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    3. Li, Chengjie & Wang, Zixuan & Liu, He & Guo, Fafu & Li, Chenghao & Xiu, Xinyan & Wang, Cong & Qin, Jiang & Wei, Liqiu, 2024. "Integrated analysis and performance optimization of fuel cell engine cogeneration system with methanol for marine application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 199(C).
    4. Mohammed Abbas, Akhtar Hasnain & Cheralathan, Kanakkampalayam Krishnan & Porpatham, Ekambaram & Arumugam, Senthil Kumar, 2024. "Hydrogen generation using methanol steam reforming – catalysts, reactors, and thermo-chemical recuperation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 191(C).
    5. Li, Chengjie & Wang, Zixuan & Liu, He & Guo, Fafu & Xiu, Xinyan & Qin, Jiang & Wei, Liqiu, 2023. "4E analysis of a novel proton exchange membrane fuel cell/engine based cogeneration system with methanol fuel for ship application," Energy, Elsevier, vol. 282(C).

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