IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-50544-1.html
   My bibliography  Save this article

Facet sensitivity of iron carbides in Fischer-Tropsch synthesis

Author

Listed:
  • Wenlong Wu

    (Anhui University of Technology
    University of Science and Technology of China
    University of Science and Technology of China)

  • Jiahua Luo

    (University of Science and Technology of China)

  • Jiankang Zhao

    (University of Science and Technology of China)

  • Menglin Wang

    (University of Science and Technology of China)

  • Lei Luo

    (University of Science and Technology of China)

  • Sunpei Hu

    (University of Science and Technology of China)

  • Bingxuan He

    (University of Science and Technology of China)

  • Chao Ma

    (Hunan University)

  • Hongliang Li

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Jie Zeng

    (Anhui University of Technology
    University of Science and Technology of China)

Abstract

Fischer-Tropsch synthesis (FTS) is a structure-sensitive reaction of which performance is strongly related to the active phase, particle size, and exposed facets. Compared with the full-pledged investigation on the active phase and particle size, the facet effect has been limited to theoretical studies or single-crystal surfaces, lacking experimental reports of practical catalysts, especially for Fe-based catalysts. Herein, we demonstrate the facet sensitivity of iron carbides in FTS. As the prerequisite, {202} and {112} facets of χ-Fe5C2 are fabricated as the outer shell through the conformal reconstruction of Fe3O4 nanocubes and octahedra, as the inner cores, respectively. During FTS, the activity and stability are highly sensitive to the exposed facet of iron carbides, whereas the facet sensitivity is not prominent for the chain growth. According to mechanistic studies, {202} χ-Fe5C2 surfaces follow hydrogen-assisted CO dissociation which lowers the activation energy compared with the direct CO dissociation over {112} surfaces, affording the high FTS activity.

Suggested Citation

  • Wenlong Wu & Jiahua Luo & Jiankang Zhao & Menglin Wang & Lei Luo & Sunpei Hu & Bingxuan He & Chao Ma & Hongliang Li & Jie Zeng, 2024. "Facet sensitivity of iron carbides in Fischer-Tropsch synthesis," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50544-1
    DOI: 10.1038/s41467-024-50544-1
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-50544-1
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-024-50544-1?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Ding, Mingyue & Yang, Yong & Wu, Baoshan & Li, Yongwang & Wang, Tiejun & Ma, Longlong, 2015. "Study on reduction and carburization behaviors of iron phases for iron-based Fischer–Tropsch synthesis catalyst," Applied Energy, Elsevier, vol. 160(C), pages 982-989.
    2. Yaru Zhang & Xiaoli Yang & Xiaofeng Yang & Hongmin Duan & Haifeng Qi & Yang Su & Binglian Liang & Huabing Tao & Bin Liu & De Chen & Xiong Su & Yanqiang Huang & Tao Zhang, 2020. "Tuning reactivity of Fischer–Tropsch synthesis by regulating TiOx overlayer over Ru/TiO2 nanocatalysts," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    3. Vera P. Santos & Tim A. Wezendonk & Juan José Delgado Jaén & A. Iulian Dugulan & Maxim A. Nasalevich & Husn-Ubayda Islam & Adam Chojecki & Sina Sartipi & Xiaohui Sun & Abrar A. Hakeem & Ard C.J. Koeke, 2015. "Metal organic framework-mediated synthesis of highly active and stable Fischer-Tropsch catalysts," Nature Communications, Nature, vol. 6(1), pages 1-8, May.
    4. Liangshu Zhong & Fei Yu & Yunlei An & Yonghui Zhao & Yuhan Sun & Zhengjia Li & Tiejun Lin & Yanjun Lin & Xingzhen Qi & Yuanyuan Dai & Lin Gu & Jinsong Hu & Shifeng Jin & Qun Shen & Hui Wang, 2016. "Cobalt carbide nanoprisms for direct production of lower olefins from syngas," Nature, Nature, vol. 538(7623), pages 84-87, October.
    5. Qingpeng Cheng & Ye Tian & Shuaishuai Lyu & Na Zhao & Kui Ma & Tong Ding & Zheng Jiang & Lihua Wang & Jing Zhang & Lirong Zheng & Fei Gao & Lin Dong & Noritatsu Tsubaki & Xingang Li, 2018. "Confined small-sized cobalt catalysts stimulate carbon-chain growth reversely by modifying ASF law of Fischer–Tropsch synthesis," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Fei Qian & Jiawei Bai & Yi Cai & Hui Yang & Xue-Min Cao & Xingchen Liu & Xing-Wu Liu & Yong Yang & Yong-Wang Li & Ding Ma & Xiao-Dong Wen, 2024. "Stabilized ε-Fe2C catalyst with Mn tuning to suppress C1 byproduct selectivity for high-temperature olefin synthesis," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Hailing Yu & Caiqi Wang & Xin Xin & Yao Wei & Shenggang Li & Yunlei An & Fanfei Sun & Tiejun Lin & Liangshu Zhong, 2024. "Engineering ZrO2–Ru interface to boost Fischer-Tropsch synthesis to olefins," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Yanfei Xu & Zhenxuan Zhang & Ke Wu & Jungang Wang & Bo Hou & Ruoting Shan & Ling Li & Mingyue Ding, 2024. "Effects of surface hydrophobization on the phase evolution behavior of iron-based catalyst during Fischer–Tropsch synthesis," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    4. Chuanhao Wang & Junjie Du & Lin Zeng & Zhongling Li & Yizhou Dai & Xu Li & Zijun Peng & Wenlong Wu & Hongliang Li & Jie Zeng, 2023. "Direct synthesis of extra-heavy olefins from carbon monoxide and water," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    5. Na Li & Yifeng Zhu & Feng Jiao & Xiulian Pan & Qike Jiang & Jun Cai & Yifan Li & Wei Tong & Changqi Xu & Shengcheng Qu & Bing Bai & Dengyun Miao & Zhi Liu & Xinhe Bao, 2022. "Steering the reaction pathway of syngas-to-light olefins with coordination unsaturated sites of ZnGaOx spinel," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    6. Galadima, Ahmad & Muraza, Oki, 2019. "Catalytic thermal conversion of CO2 into fuels: Perspective and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    7. Jiaqi Zhao & Jinjia Liu & Zhenhua Li & Kaiwen Wang & Run Shi & Pu Wang & Qing Wang & Geoffrey I. N. Waterhouse & Xiaodong Wen & Tierui Zhang, 2023. "Ruthenium-cobalt single atom alloy for CO photo-hydrogenation to liquid fuels at ambient pressures," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    8. Hailing Yu & Caiqi Wang & Tiejun Lin & Yunlei An & Yuchen Wang & Qingyu Chang & Fei Yu & Yao Wei & Fanfei Sun & Zheng Jiang & Shenggang Li & Yuhan Sun & Liangshu Zhong, 2022. "Direct production of olefins from syngas with ultrahigh carbon efficiency," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    9. Sheinbaum-Pardo, Claudia, 2016. "Decomposition analysis from demand services to material production: The case of CO2 emissions from steel produced for automobiles in Mexico," Applied Energy, Elsevier, vol. 174(C), pages 245-255.
    10. Pavel A. Kots & Tianjun Xie & Brandon C. Vance & Caitlin M. Quinn & Matheus Dorneles Mello & J. Anibal Boscoboinik & Cong Wang & Pawan Kumar & Eric A. Stach & Nebojsa S. Marinkovic & Lu Ma & Steven N., 2022. "Electronic modulation of metal-support interactions improves polypropylene hydrogenolysis over ruthenium catalysts," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    11. Xiaofeng Gao & Ling Zhu & Feng Yang & Lei Zhang & Wenhao Xu & Xian Zhou & Yongkang Huang & Houhong Song & Lili Lin & Xiaodong Wen & Ding Ma & Siyu Yao, 2023. "Subsurface nickel boosts the low-temperature performance of a boron oxide overlayer in propane oxidative dehydrogenation," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    12. Zhou, Jianli & Wu, Yunna & Tao, Yao & Gao, Jianwei & Zhong, Zhiming & Xu, Chuanbo, 2021. "Geographic information big data-driven two-stage optimization model for location decision of hydrogen refueling stations: An empirical study in China," Energy, Elsevier, vol. 225(C).
    13. Hao Meng & Yusen Yang & Tianyao Shen & Wei Liu & Lei Wang & Pan Yin & Zhen Ren & Yiming Niu & Bingsen Zhang & Lirong Zheng & Hong Yan & Jian Zhang & Feng-Shou Xiao & Min Wei & Xue Duan, 2023. "A strong bimetal-support interaction in ethanol steam reforming," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    14. Song, Wenjing & Song, Mengxue & Cai, Wenqing & Li, Weichu & Jiang, Xingmao & Fang, Weiping & Lai, Weikun, 2022. "Efficient and stable SiO2-encapsulated NiPt/HY catalyst for catalytic cracking of β-O-4 linkage compound," Renewable Energy, Elsevier, vol. 198(C), pages 334-342.
    15. Zhao, Zhitong & Chong, Katie & Jiang, Jingyang & Wilson, Karen & Zhang, Xiaochen & Wang, Feng, 2018. "Low-carbon roadmap of chemical production: A case study of ethylene in China," Renewable and Sustainable Energy Reviews, Elsevier, vol. 97(C), pages 580-591.
    16. Wang, Danfeng & Gu, Yu & Chen, Qianqian & Tang, Zhiyong, 2023. "Direct conversion of syngas to alpha olefins via Fischer–Tropsch synthesis: Process development and comparative techno-economic-environmental analysis," Energy, Elsevier, vol. 263(PE).
    17. Ming Xu & Xuetao Qin & Yao Xu & Xiaochen Zhang & Lirong Zheng & Jin-Xun Liu & Meng Wang & Xi Liu & Ding Ma, 2022. "Boosting CO hydrogenation towards C2+ hydrocarbons over interfacial TiO2−x/Ni catalysts," Nature Communications, Nature, vol. 13(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50544-1. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.