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Supramolecular glasses with color-tunable circularly polarized afterglow through evaporation-induced self-assembly of chiral metal–organic complexes

Author

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  • Fei Nie

    (Beijing Normal University)

  • Ke-Zhi Wang

    (Beijing Normal University)

  • Dongpeng Yan

    (Beijing Normal University)

Abstract

The fabrication of chiral molecules into macroscopic systems has many valuable applications, especially in the fields of optical displays, data encryption, information storage, and so on. Here, we design and prepare a serious of supramolecular glasses (SGs) based on Zn-L-Histidine complexes, via an evaporation-induced self-assembly (EISA) strategy. Metal-ligand interactions between the zinc(II) ion and chiral L-Histidine endow the SGs with interesting circularly polarized afterglow (CPA). Multicolored CPA emissions from blue to red with dissymmetry factor as high as 9.5 × 10−3 and excited-state lifetime up to 356.7 ms are achieved under ambient conditions. Therefore, this work not only communicates the bulk SGs with wide-tunable afterglow and large circular polarization, but also provides an EISA method for the macroscopic self-assembly of chiral metal–organic hybrids toward photonic applications.

Suggested Citation

  • Fei Nie & Ke-Zhi Wang & Dongpeng Yan, 2023. "Supramolecular glasses with color-tunable circularly polarized afterglow through evaporation-induced self-assembly of chiral metal–organic complexes," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37331-0
    DOI: 10.1038/s41467-023-37331-0
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    1. Hui Li & Jie Gu & Zijie Wang & Juan Wang & Fei He & Ping Li & Ye Tao & Huanhuan Li & Gaozhan Xie & Wei Huang & Chao Zheng & Runfeng Chen, 2022. "Single-component color-tunable circularly polarized organic afterglow through chiral clusterization," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    2. Tao Wang & Zhubin Hu & Xiancheng Nie & Linkun Huang & Miao Hui & Xiang Sun & Guoqing Zhang, 2021. "Thermochromic aggregation-induced dual phosphorescence via temperature-dependent sp3-linked donor-acceptor electronic coupling," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    3. Diederik W. R. Balkenende & Christophe A. Monnier & Gina L. Fiore & Christoph Weder, 2016. "Optically responsive supramolecular polymer glasses," Nature Communications, Nature, vol. 7(1), pages 1-9, April.
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    Cited by:

    1. Wenqing Xu & Guanheng Huang & Zhan Yang & Ziqi Deng & Chen Zhou & Jian-An Li & Ming-De Li & Tao Hu & Ben Zhong Tang & David Lee Phillips, 2024. "Nucleic-acid-base photofunctional cocrystal for information security and antimicrobial applications," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Xiaolu Zhou & Xue Bai & Fangjian Shang & Heng-Yi Zhang & Li-Hua Wang & Xiufang Xu & Yu Liu, 2024. "Supramolecular assembly activated single-molecule phosphorescence resonance energy transfer for near-infrared targeted cell imaging," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    3. Fei Nie & Dongpeng Yan, 2024. "Bio-sourced flexible supramolecular glasses for dynamic and full-color phosphorescence," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Changyong Cai & Shuanggen Wu & Yunfei Zhang & Fenfang Li & Zhijian Tan & Shengyi Dong, 2024. "Bulk transparent supramolecular glass enabled by host–guest molecular recognition," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    5. Fei Nie & Dongpeng Yan, 2024. "Zero-dimensional halide hybrid bulk glass exhibiting reversible photochromic ultralong phosphorescence," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    6. Mingjian Zeng & Weiguang Wang & Shuman Zhang & Zhisheng Gao & Yingmeng Yan & Yitong Liu & Yulong Qi & Xin Yan & Wei Zhao & Xin Zhang & Ningning Guo & Huanhuan Li & Hui Li & Gaozhan Xie & Ye Tao & Runf, 2024. "Enabling robust blue circularly polarized organic afterglow through self-confining isolated chiral chromophore," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    7. Borneo S. Vijar III & Galilei Jade DR. Morale & Mhia B. Silverio & Joseline M. Santos & Reniel Renz C. Gallardo, 2024. "Aesthetic Characteristics Skills of the Students through Visual Understanding and Visual Matching Skills," International Journal of Research and Innovation in Social Science, International Journal of Research and Innovation in Social Science (IJRISS), vol. 8(3s), pages 1785-1798, March.
    8. Borneo S. Vijar III & Galilei Jade DR. Morale & Mhia B. Silverio & Joseline M. Santos & Reniel Renz C. Gallardo, 2024. "Aesthetic Characteristics Skills of the Students through Visual Understanding and Visual Matching Skills," International Journal of Research and Innovation in Social Science, International Journal of Research and Innovation in Social Science (IJRISS), vol. 8(6), pages 1785-1798, June.

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