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Single-component color-tunable circularly polarized organic afterglow through chiral clusterization

Author

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  • Hui Li

    (State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications)

  • Jie Gu

    (State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications)

  • Zijie Wang

    (State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications)

  • Juan Wang

    (State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications)

  • Fei He

    (State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications)

  • Ping Li

    (State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications)

  • Ye Tao

    (State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications)

  • Huanhuan Li

    (State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications)

  • Gaozhan Xie

    (State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications)

  • Wei Huang

    (State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications
    Institute of Flexible Electronics (IFE), Northwestern Polytechnical University)

  • Chao Zheng

    (State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications)

  • Runfeng Chen

    (State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications)

Abstract

Circularly polarized organic afterglow (CPOA) with both long-lived room-temperature phosphorescence (RTP) and circularly polarized luminescence (CPL) is currently attracting great interest, but the development of multicolor-tunable CPOA in a single-component material remains a formidable challenge. Here, we report an efficient strategy to achieve multicolor CPOA molecules through chiral clusterization by implanting chirality center into non-conjugated organic cluster. Owing to excitation-dependent emission of clusters, highly efficient and significantly tuned CPOA emissions from blue to yellowish-green with dissymmetry factor over 2.3 × 10−3 and lifetime up to 587 ms are observed under different excitation wavelengths. With the distinguished color-tunable CPOA, the multicolor CPL displays and visual RTP detection of ultraviolent light wavelength are successfully constructed. These results not only provide a new paradigm for realization of multicolor-tunable CPOA materials in single-component molecular systems, but also offer new opportunities for expanding the applicability of CPL and RTP materials for diversified applications.

Suggested Citation

  • Hui Li & Jie Gu & Zijie Wang & Juan Wang & Fei He & Ping Li & Ye Tao & Huanhuan Li & Gaozhan Xie & Wei Huang & Chao Zheng & Runfeng Chen, 2022. "Single-component color-tunable circularly polarized organic afterglow through chiral clusterization," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28070-9
    DOI: 10.1038/s41467-022-28070-9
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    1. Xiugang Wu & Chun-Ying Huang & Deng-Gao Chen & Denghui Liu & Chichi Wu & Keh-Jiunh Chou & Bin Zhang & Yafei Wang & Yu Liu & Elise Y. Li & Weiguo Zhu & Pi-Tai Chou, 2020. "Exploiting racemism enhanced organic room-temperature phosphorescence to demonstrate Wallach’s rule in the lighting chiral chromophores," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
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    Cited by:

    1. Xiaoyu Chen & Renlong Zhu & Baicheng Zhang & Xiaolong Zhang & Aoyuan Cheng & Hongping Liu & Ruiying Gao & Xuepeng Zhang & Biao Chen & Shuji Ye & Jun Jiang & Guoqing Zhang, 2024. "Rapid room-temperature phosphorescence chiral recognition of natural amino acids," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Weiwei Xie & Wenbin Huang & Jietai Li & Zikai He & Guangxi Huang & Bing Shi Li & Ben Zhong Tang, 2023. "Anti-Kasha triplet energy transfer and excitation wavelength dependent persistent luminescence from host-guest doping systems," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    3. Yuchen Guo & Yifei Zhang & Jianfei Ma & Rui Liao & Feng Wang, 2024. "Wide-range tunable circularly polarized luminescence in triphenylamine supramolecular polymers via charge-transfer complexation," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Xiao Zhang & Mingjian Zeng & Yewen Zhang & Chenyu Zhang & Zhisheng Gao & Fei He & Xudong Xue & Huanhuan Li & Ping Li & Gaozhan Xie & Hui Li & Xin Zhang & Ningning Guo & He Cheng & Ansheng Luo & Wei Zh, 2023. "Multicolor hyperafterglow from isolated fluorescence chromophores," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    5. Fei Nie & Ke-Zhi Wang & Dongpeng Yan, 2023. "Supramolecular glasses with color-tunable circularly polarized afterglow through evaporation-induced self-assembly of chiral metal–organic complexes," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    6. Mingjian Zeng & Weiguang Wang & Shuman Zhang & Zhisheng Gao & Yingmeng Yan & Yitong Liu & Yulong Qi & Xin Yan & Wei Zhao & Xin Zhang & Ningning Guo & Huanhuan Li & Hui Li & Gaozhan Xie & Ye Tao & Runf, 2024. "Enabling robust blue circularly polarized organic afterglow through self-confining isolated chiral chromophore," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    7. Wenlang Li & Qiuyi Huang & Zhu Mao & Xiaoyi He & Dongyu Ma & Juan Zhao & Jacky W. Y. Lam & Yi Zhang & Ben Zhong Tang & Zhenguo Chi, 2022. "A dish-like molecular architecture for dynamic ultralong room-temperature phosphorescence through reversible guest accommodation," Nature Communications, Nature, vol. 13(1), pages 1-11, December.

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