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Ultralong phosphorescence cellulose with excellent anti-bacterial, water-resistant and ease-to-process performance

Author

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  • Xin Zhang

    (CAS Key Laboratory of Engineering Plastics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS)
    University of Chinese Academy of Sciences)

  • Yaohui Cheng

    (CAS Key Laboratory of Engineering Plastics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS)
    University of Chinese Academy of Sciences)

  • Jingxuan You

    (CAS Key Laboratory of Engineering Plastics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS)
    University of Chinese Academy of Sciences)

  • Jinming Zhang

    (CAS Key Laboratory of Engineering Plastics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS))

  • Chunchun Yin

    (CAS Key Laboratory of Engineering Plastics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS)
    University of Chinese Academy of Sciences)

  • Jun Zhang

    (CAS Key Laboratory of Engineering Plastics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS)
    University of Chinese Academy of Sciences)

Abstract

Herein, we present a phosphorescent cationized cellulose derivative by simply introducing ionic structures, including cyanomethylimidazolium cations and chloride anions, into cellulose chains. The imidazolium cations with the cyano group and nitrogen element promote intersystem crossing. The cyano-containing cations, chloride anions and hydroxyl groups of cellulose form multiple hydrogen bonding interactions and electrostatic attraction interactions, effectively inhibiting the non-radiative transitions. The resultant cellulose-based RTP material is easily processed into phosphorescent films, fibers, coatings and patterns by using eco-friendly aqueous solution processing strategies. Furthermore, after we construct a cross-linking structure by adding a small amount of glutaraldehyde as the cross-linking agent, the as-fabricated phosphorescent patterns exhibit excellent antibacterial properties and water resistance. Therefore, considering the outstanding biodegradability and sustainability of cellulose materials, cellulose-based easy-to-process RTP materials can act as antibacterial, water-resistant, and eco-friendly phosphorescent patterns, coatings and bulk materials, which have enormous potential in advanced anti-counterfeiting, information encryption, disposable smart labels, etc.

Suggested Citation

  • Xin Zhang & Yaohui Cheng & Jingxuan You & Jinming Zhang & Chunchun Yin & Jun Zhang, 2022. "Ultralong phosphorescence cellulose with excellent anti-bacterial, water-resistant and ease-to-process performance," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28759-x
    DOI: 10.1038/s41467-022-28759-x
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    References listed on IDEAS

    as
    1. Yunqing Zhu & Charles Romain & Charlotte K. Williams, 2016. "Sustainable polymers from renewable resources," Nature, Nature, vol. 540(7633), pages 354-362, December.
    2. Yongfeng Zhang & Liang Gao & Xian Zheng & Zhonghao Wang & Chaolong Yang & Hailong Tang & Lunjun Qu & Youbing Li & Yanli Zhao, 2021. "Ultraviolet irradiation-responsive dynamic ultralong organic phosphorescence in polymeric systems," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    3. Tao Wang & Zhubin Hu & Xiancheng Nie & Linkun Huang & Miao Hui & Xiang Sun & Guoqing Zhang, 2021. "Thermochromic aggregation-induced dual phosphorescence via temperature-dependent sp3-linked donor-acceptor electronic coupling," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
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    1. Xiaoyu Chen & Renlong Zhu & Baicheng Zhang & Xiaolong Zhang & Aoyuan Cheng & Hongping Liu & Ruiying Gao & Xuepeng Zhang & Biao Chen & Shuji Ye & Jun Jiang & Guoqing Zhang, 2024. "Rapid room-temperature phosphorescence chiral recognition of natural amino acids," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Guijie Li & Kewei Xu & Jianbing Zheng & Xiaoli Fang & Yun-Fang Yang & Weiwei Lou & Qingshan Chu & Jianxin Dai & Qidong Chen & Yuning Yang & Yuan-Bin She, 2023. "Double boron–oxygen-fused polycyclic aromatic hydrocarbons: skeletal editing and applications as organic optoelectronic materials," Nature Communications, Nature, vol. 14(1), pages 1-16, December.
    3. Zongliang Xie & Yufeng Xue & Xianhe Zhang & Junru Chen & Zesen Lin & Bin Liu, 2024. "Isostructural doping for organic persistent mechanoluminescence," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    4. Longqiang Li & Jiayin Zhou & Junyi Han & Depeng Liu & Min Qi & Juanfang Xu & Guangqiang Yin & Tao Chen, 2024. "Finely manipulating room temperature phosphorescence by dynamic lanthanide coordination toward multi-level information security," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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