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Zero-dimensional halide hybrid bulk glass exhibiting reversible photochromic ultralong phosphorescence

Author

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  • Fei Nie

    (Beijing Normal University)

  • Dongpeng Yan

    (Beijing Normal University)

Abstract

Dynamically responsive materials, capable of reversible changes in color appearance and/or photoemission upon external stimuli, have attracted substantial attention across various fields. This study presents an effective approach wherein switchable modulation of photochromism and ultralong phosphorescence can be achieved simultaneously in a zero-dimensional organic-inorganic halide hybrid glass doped with 4,4´-bipyridine. The facile fabrication of large-scale glasses is accomplished through a combined grinding-melting-quenching process. The persistent luminescence can be regulated through the photochromic switch induced by photo-generated radicals. Furthermore, the incorporation of the aggregation-induced chirality effect generates intriguing circularly polarized luminescence, with an optical dissymmetry factor (glum) reaching the order of 10–2. Exploiting the dynamic ultralong phosphorescence, this work further achieves promising applications, such as three-dimensional optical storage, rewritable photo-patterning, and multi-mode anti-counterfeiting with ease. Therefore, this study introduces a smart hybrid glass platform as a new photo-responsive switchable system, offering versatility for a wide array of photonic applications.

Suggested Citation

  • Fei Nie & Dongpeng Yan, 2024. "Zero-dimensional halide hybrid bulk glass exhibiting reversible photochromic ultralong phosphorescence," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-49886-7
    DOI: 10.1038/s41467-024-49886-7
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    References listed on IDEAS

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    1. Zizhao Huang & Zhenyi He & Bingbing Ding & He Tian & Xiang Ma, 2022. "Photoprogrammable circularly polarized phosphorescence switching of chiral helical polyacetylene thin films," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    2. Fei Nie & Ke-Zhi Wang & Dongpeng Yan, 2023. "Supramolecular glasses with color-tunable circularly polarized afterglow through evaporation-induced self-assembly of chiral metal–organic complexes," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    3. Zheng Zhao & Xiaoyan Zheng & Lili Du & Yu Xiong & Wei He & Xiuxiu Gao & Chunli Li & Yingjie Liu & Bin Xu & Jing Zhang & Fengyan Song & Ying Yu & Xueqian Zhao & Yuanjing Cai & Xuewen He & Ryan T. K. Kw, 2019. "Non-aromatic annulene-based aggregation-induced emission system via aromaticity reversal process," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
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