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Enabling robust blue circularly polarized organic afterglow through self-confining isolated chiral chromophore

Author

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  • Mingjian Zeng

    (Nanjing University of Posts & Tele communications)

  • Weiguang Wang

    (Nanjing University of Posts & Tele communications)

  • Shuman Zhang

    (Nanjing University of Posts & Tele communications)

  • Zhisheng Gao

    (Nanjing University of Posts & Tele communications)

  • Yingmeng Yan

    (Nanjing University of Posts & Tele communications)

  • Yitong Liu

    (Nanjing University of Posts & Tele communications)

  • Yulong Qi

    (Nanjing University of Posts & Tele communications)

  • Xin Yan

    (Nanjing University of Posts & Tele communications)

  • Wei Zhao

    (Nanjing University of Posts & Tele communications)

  • Xin Zhang

    (Nanjing University of Posts & Tele communications)

  • Ningning Guo

    (Nanjing University of Posts & Tele communications)

  • Huanhuan Li

    (Nanjing University of Posts & Tele communications)

  • Hui Li

    (Nanjing University of Posts & Tele communications)

  • Gaozhan Xie

    (Nanjing University of Posts & Tele communications)

  • Ye Tao

    (Nanjing University of Posts & Tele communications
    Songshan Lake Materials Laboratory)

  • Runfeng Chen

    (Nanjing University of Posts & Tele communications)

  • Wei Huang

    (Nanjing University of Posts & Tele communications
    Northwestern Polytechnical University)

Abstract

Creating circularly polarized organic afterglow system with elevated triplet energy levels, suppressed non-radiative transitions, and effective chirality, which are three critical prerequisites for achieving blue circularly polarized afterglow, has posed a formidable challenge. Herein, a straightforward approach is unveiled to attain blue circularly polarized afterglow materials by covalently self-confining isolated chiral chromophore within polymer matrix. The formation of robust hydrogen bonds within the polymer matrix confers a distinctly isolated and stabilized molecular state of chiral chromophores, endowing a blue emission band at 414 nm, lifetime of 3.0 s, and luminescent dissymmetry factor of ~ 10−2. Utilizing the synergistic afterglow and chirality energy transfer, full-color circularly polarized afterglow systems are endowed by doping colorful fluorescent molecules into designed blue polymers, empowering versatile applications. This work paves the way for the streamlined design of blue circularly polarized afterglow materials, expanding the horizons of circularly polarized afterglow materials into various domains.

Suggested Citation

  • Mingjian Zeng & Weiguang Wang & Shuman Zhang & Zhisheng Gao & Yingmeng Yan & Yitong Liu & Yulong Qi & Xin Yan & Wei Zhao & Xin Zhang & Ningning Guo & Huanhuan Li & Hui Li & Gaozhan Xie & Ye Tao & Runf, 2024. "Enabling robust blue circularly polarized organic afterglow through self-confining isolated chiral chromophore," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-47240-5
    DOI: 10.1038/s41467-024-47240-5
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    References listed on IDEAS

    as
    1. Siyang Lin & Yuqi Tang & Wenxin Kang & Hari Krishna Bisoyi & Jinbao Guo & Quan Li, 2023. "Photo-triggered full-color circularly polarized luminescence based on photonic capsules for multilevel information encryption," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Fei Nie & Ke-Zhi Wang & Dongpeng Yan, 2023. "Supramolecular glasses with color-tunable circularly polarized afterglow through evaporation-induced self-assembly of chiral metal–organic complexes," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    3. Qi Qian & Huaying Ren & Jingyuan Zhou & Zhong Wan & Jingxuan Zhou & Xingxu Yan & Jin Cai & Peiqi Wang & Bailing Li & Zdenek Sofer & Bo Li & Xidong Duan & Xiaoqing Pan & Yu Huang & Xiangfeng Duan, 2022. "Chiral molecular intercalation superlattices," Nature, Nature, vol. 606(7916), pages 902-908, June.
    4. Biao Chen & Wenhuan Huang & Guoqing Zhang, 2023. "Observation of Chiral-selective room-temperature phosphorescence enhancement via chirality-dependent energy transfer," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    5. Inho Song & Jaeyong Ahn & Hyungju Ahn & Sang Hyuk Lee & Jianguo Mei & Nicholas A. Kotov & Joon Hak Oh, 2023. "Helical polymers for dissymmetric circularly polarized light imaging," Nature, Nature, vol. 617(7959), pages 92-99, May.
    6. Hui Li & Jie Gu & Zijie Wang & Juan Wang & Fei He & Ping Li & Ye Tao & Huanhuan Li & Gaozhan Xie & Wei Huang & Chao Zheng & Runfeng Chen, 2022. "Single-component color-tunable circularly polarized organic afterglow through chiral clusterization," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    7. Xiao Zhang & Mingjian Zeng & Yewen Zhang & Chenyu Zhang & Zhisheng Gao & Fei He & Xudong Xue & Huanhuan Li & Ping Li & Gaozhan Xie & Hui Li & Xin Zhang & Ningning Guo & He Cheng & Ansheng Luo & Wei Zh, 2023. "Multicolor hyperafterglow from isolated fluorescence chromophores," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    8. Zizhao Huang & Zhenyi He & Bingbing Ding & He Tian & Xiang Ma, 2022. "Photoprogrammable circularly polarized phosphorescence switching of chiral helical polyacetylene thin films," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    9. Jichao Jia & Xue Cao & Xuekai Ma & Jianbo De & Jiannian Yao & Stefan Schumacher & Qing Liao & Hongbing Fu, 2023. "Circularly polarized electroluminescence from a single-crystal organic microcavity light-emitting diode based on photonic spin-orbit interactions," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    10. Long Gu & Hongwei Wu & Huili Ma & Wenpeng Ye & Wenyong Jia & He Wang & Hongzhong Chen & Nan Zhang & Dongdong Wang & Cheng Qian & Zhongfu An & Wei Huang & Yanli Zhao, 2020. "Color-tunable ultralong organic room temperature phosphorescence from a multicomponent copolymer," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    11. Xiaokang Yao & Huili Ma & Xiao Wang & He Wang & Qian Wang & Xin Zou & Zhicheng Song & Wenyong Jia & Yuxin Li & Yufeng Mao & Manjeet Singh & Wenpeng Ye & Jian Liang & Yanyun Zhang & Zhuang Liu & Yixiao, 2022. "Ultralong organic phosphorescence from isolated molecules with repulsive interactions for multifunctional applications," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
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