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Exfoliation of layered double hydroxides for enhanced oxygen evolution catalysis

Author

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  • Fang Song

    (Laboratory of Inorganic Synthesis and Catalysis, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), EPFL-ISIC-LSCI, BCH 3305)

  • Xile Hu

    (Laboratory of Inorganic Synthesis and Catalysis, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), EPFL-ISIC-LSCI, BCH 3305)

Abstract

The oxygen evolution reaction is a key reaction in water splitting. The common approach in the development of oxygen evolution catalysts is to search for catalytic materials with new and optimized chemical compositions and structures. Here we report an orthogonal approach to improve the activity of catalysts without alternating their compositions or structures. Specifically, liquid phase exfoliation is applied to enhance the oxygen evolution activity of layered double hydroxides. The exfoliated single-layer nanosheets exhibit significantly higher oxygen evolution activity than the corresponding bulk layered double hydroxides in alkaline conditions. The nanosheets from nickel iron and nickel cobalt layered double hydroxides outperform a commercial iridium dioxide catalyst in both activity and stability. The exfoliation creates more active sites and improves the electronic conductivity. This work demonstrates the promising catalytic activity of single-layered double hydroxides for the oxygen evolution reaction.

Suggested Citation

  • Fang Song & Xile Hu, 2014. "Exfoliation of layered double hydroxides for enhanced oxygen evolution catalysis," Nature Communications, Nature, vol. 5(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms5477
    DOI: 10.1038/ncomms5477
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    Cited by:

    1. Sihong Wang & Qu Jiang & Shenghong Ju & Chia-Shuo Hsu & Hao Ming Chen & Di Zhang & Fang Song, 2022. "Identifying the geometric catalytic active sites of crystalline cobalt oxyhydroxides for oxygen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    2. Yunchang Liang & Karla Banjac & Kévin Martin & Nicolas Zigon & Seunghwa Lee & Nicolas Vanthuyne & Felipe Andrés Garcés-Pineda & José R. Galán-Mascarós & Xile Hu & Narcis Avarvari & Magalí Lingenfelder, 2022. "Enhancement of electrocatalytic oxygen evolution by chiral molecular functionalization of hybrid 2D electrodes," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    3. Fangqing Wang & Peichao Zou & Yangyang Zhang & Wenli Pan & Ying Li & Limin Liang & Cong Chen & Hui Liu & Shijian Zheng, 2023. "Activating lattice oxygen in high-entropy LDH for robust and durable water oxidation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    4. Zuraya Angeles-Olvera & Alfonso Crespo-Yapur & Oliver Rodríguez & Jorge L. Cholula-Díaz & Luz María Martínez & Marcelo Videa, 2022. "Nickel-Based Electrocatalysts for Water Electrolysis," Energies, MDPI, vol. 15(5), pages 1-35, February.
    5. Zhang, Yuanyuan & Sun, Haohao & Qiu, Yunfeng & Zhang, Enhao & Ma, Tiange & Gao, Guang-gang & Cao, Changyan & Ma, Zhuo & Hu, PingAn, 2018. "Bifunctional hydrogen evolution and oxygen evolution catalysis using CoP-embedded N-doped nanoporous carbon synthesized via TEOS-assisted method," Energy, Elsevier, vol. 165(PB), pages 537-548.
    6. Zeyu Wang & William A. Goddard & Hai Xiao, 2023. "Potential-dependent transition of reaction mechanisms for oxygen evolution on layered double hydroxides," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    7. Michael High & Clemens F. Patzschke & Liya Zheng & Dewang Zeng & Oriol Gavalda-Diaz & Nan Ding & Ka Ho Horace Chien & Zili Zhang & George E. Wilson & Andrey V. Berenov & Stephen J. Skinner & Kyra L. S, 2022. "Precursor engineering of hydrotalcite-derived redox sorbents for reversible and stable thermochemical oxygen storage," Nature Communications, Nature, vol. 13(1), pages 1-14, December.
    8. Jiayi Chen & Mohammed Aliasgar & Fernando Buendia Zamudio & Tianyu Zhang & Yilin Zhao & Xu Lian & Lan Wen & Haozhou Yang & Wenping Sun & Sergey M. Kozlov & Wei Chen & Lei Wang, 2023. "Diversity of platinum-sites at platinum/fullerene interface accelerates alkaline hydrogen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    9. Jie Wei & Yangfan Shao & Jingbo Xu & Fang Yin & Zejian Li & Haitao Qian & Yinping Wei & Liang Chang & Yu Han & Jia Li & Lin Gan, 2024. "Sequential oxygen evolution and decoupled water splitting via electrochemical redox reaction of nickel hydroxides," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    10. Sanjiang Pan & Hao Li & Dan Liu & Rui Huang & Xuelei Pan & Dan Ren & Jun Li & Mohsen Shakouri & Qixing Zhang & Manjing Wang & Changchun Wei & Liqiang Mai & Bo Zhang & Ying Zhao & Zhenbin Wang & Michae, 2022. "Efficient and stable noble-metal-free catalyst for acidic water oxidation," Nature Communications, Nature, vol. 13(1), pages 1-10, December.

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