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Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction

Author

Listed:
  • Dong Young Chung

    (Argonne National Laboratory)

  • Pietro P. Lopes

    (Argonne National Laboratory)

  • Pedro Farinazzo Bergamo Dias Martins

    (Argonne National Laboratory)

  • Haiying He

    (Valparaiso University)

  • Tomoya Kawaguchi

    (Argonne National Laboratory)

  • Peter Zapol

    (Argonne National Laboratory)

  • Hoydoo You

    (Argonne National Laboratory)

  • Dusan Tripkovic

    (University of Belgrade)

  • Dusan Strmcnik

    (Argonne National Laboratory)

  • Yisi Zhu

    (Argonne National Laboratory)

  • Soenke Seifert

    (Argonne National Laboratory)

  • Sungsik Lee

    (Argonne National Laboratory)

  • Vojislav R. Stamenkovic

    (Argonne National Laboratory)

  • Nenad M. Markovic

    (Argonne National Laboratory)

Abstract

The poor activity and stability of electrode materials for the oxygen evolution reaction are the main bottlenecks in the water-splitting reaction for H2 production. Here, by studying the activity–stability trends for the oxygen evolution reaction on conductive M1OxHy, Fe–M1OxHy and Fe–M1M2OxHy hydr(oxy)oxide clusters (M1 = Ni, Co, Fe; M2 = Mn, Co, Cu), we show that balancing the rates of Fe dissolution and redeposition over a MOxHy host establishes dynamically stable Fe active sites. Together with tuning the Fe content of the electrolyte, the strong interaction of Fe with the MOxHy host is the key to controlling the average number of Fe active sites present at the solid/liquid interface. We suggest that the Fe–M adsorption energy can therefore serve as a reaction descriptor that unifies oxygen evolution reaction catalysis on 3d transition-metal hydr(oxy)oxides in alkaline media. Thus, the introduction of dynamically stable active sites extends the design rules for creating active and stable interfaces.

Suggested Citation

  • Dong Young Chung & Pietro P. Lopes & Pedro Farinazzo Bergamo Dias Martins & Haiying He & Tomoya Kawaguchi & Peter Zapol & Hoydoo You & Dusan Tripkovic & Dusan Strmcnik & Yisi Zhu & Soenke Seifert & Su, 2020. "Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction," Nature Energy, Nature, vol. 5(3), pages 222-230, March.
    • Handle: RePEc:nat:natene:v:5:y:2020:i:3:d:10.1038_s41560-020-0576-y
    DOI: 10.1038/s41560-020-0576-y
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    Cited by:

    1. Qu Jiang & Sihong Wang & Chaoran Zhang & Ziyang Sheng & Haoyue Zhang & Ruohan Feng & Yuanman Ni & Xiaoan Tang & Yichuan Gu & Xinhong Zhou & Seunghwa Lee & Di Zhang & Fang Song, 2023. "Active oxygen species mediate the iron-promoting electrocatalysis of oxygen evolution reaction on metal oxyhydroxides," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    2. Zhirong Zhang & Chen Feng & Dongdi Wang & Shiming Zhou & Ruyang Wang & Sunpei Hu & Hongliang Li & Ming Zuo & Yuan Kong & Jun Bao & Jie Zeng, 2022. "Selectively anchoring single atoms on specific sites of supports for improved oxygen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    3. Yunchang Liang & Karla Banjac & Kévin Martin & Nicolas Zigon & Seunghwa Lee & Nicolas Vanthuyne & Felipe Andrés Garcés-Pineda & José R. Galán-Mascarós & Xile Hu & Narcis Avarvari & Magalí Lingenfelder, 2022. "Enhancement of electrocatalytic oxygen evolution by chiral molecular functionalization of hybrid 2D electrodes," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    4. Yingqing Ou & Liam P. Twight & Bipasa Samanta & Lu Liu & Santu Biswas & Jessica L. Fehrs & Nicole A. Sagui & Javier Villalobos & Joaquín Morales-Santelices & Denis Antipin & Marcel Risch & Maytal Casp, 2023. "Cooperative Fe sites on transition metal (oxy)hydroxides drive high oxygen evolution activity in base," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    5. Fangqing Wang & Peichao Zou & Yangyang Zhang & Wenli Pan & Ying Li & Limin Liang & Cong Chen & Hui Liu & Shijian Zheng, 2023. "Activating lattice oxygen in high-entropy LDH for robust and durable water oxidation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    6. Agnes E. Thorarinsdottir & Samuel S. Veroneau & Daniel G. Nocera, 2022. "Self-healing oxygen evolution catalysts," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    7. Xin Zhang & Haoyin Zhong & Qi Zhang & Qihan Zhang & Chao Wu & Junchen Yu & Yifan Ma & Hang An & Hao Wang & Yiming Zou & Caozheng Diao & Jingsheng Chen & Zhi Gen Yu & Shibo Xi & Xiaopeng Wang & Junmin , 2024. "High-spin Co3+ in cobalt oxyhydroxide for efficient water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    8. Haoliang Huang & Yu-Chung Chang & Yu-Cheng Huang & Lili Li & Alexander C. Komarek & Liu Hao Tjeng & Yuki Orikasa & Chih-Wen Pao & Ting-Shan Chan & Jin-Ming Chen & Shu-Chih Haw & Jing Zhou & Yifeng Wan, 2023. "Unusual double ligand holes as catalytic active sites in LiNiO2," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    9. Jie Wei & Yangfan Shao & Jingbo Xu & Fang Yin & Zejian Li & Haitao Qian & Yinping Wei & Liang Chang & Yu Han & Jia Li & Lin Gan, 2024. "Sequential oxygen evolution and decoupled water splitting via electrochemical redox reaction of nickel hydroxides," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    10. Sang Eon Jun & Youn-Hye Kim & Jaehyun Kim & Woo Seok Cheon & Sungkyun Choi & Jinwook Yang & Hoonkee Park & Hyungsoo Lee & Sun Hwa Park & Ki Chang Kwon & Jooho Moon & Soo-Hyun Kim & Ho Won Jang, 2023. "Atomically dispersed iridium catalysts on silicon photoanode for efficient photoelectrochemical water splitting," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    11. Xiaojing Lin & Zhaojie Wang & Shoufu Cao & Yuying Hu & Siyuan Liu & Xiaodong Chen & Hongyu Chen & Xingheng Zhang & Shuxian Wei & Hui Xu & Zhi Cheng & Qi Hou & Daofeng Sun & Xiaoqing Lu, 2023. "Bioinspired trimesic acid anchored electrocatalysts with unique static and dynamic compatibility for enhanced water oxidation," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    12. Ling Zhou & Daying Guo & Lianhui Wu & Zhixi Guan & Chao Zou & Huile Jin & Guoyong Fang & Xi’an Chen & Shun Wang, 2024. "A restricted dynamic surface self-reconstruction toward high-performance of direct seawater oxidation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    13. Yuzhen Chen & Qiuhong Li & Yuxing Lin & Jiao Liu & Jing Pan & Jingguo Hu & Xiaoyong Xu, 2024. "Boosting oxygen evolution reaction by FeNi hydroxide-organic framework electrocatalyst toward alkaline water electrolyzer," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    14. Chao Feng & Faze Wang & Zhi Liu & Mamiko Nakabayashi & Yequan Xiao & Qiugui Zeng & Jie Fu & Qianbao Wu & Chunhua Cui & Yifan Han & Naoya Shibata & Kazunari Domen & Ian D. Sharp & Yanbo Li, 2021. "A self-healing catalyst for electrocatalytic and photoelectrochemical oxygen evolution in highly alkaline conditions," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    15. Changhao Liu & Ningsi Zhang & Yang Li & Rongli Fan & Wenjing Wang & Jianyong Feng & Chen Liu & Jiaou Wang & Weichang Hao & Zhaosheng Li & Zhigang Zou, 2023. "Long-term durability of metastable β-Fe2O3 photoanodes in highly corrosive seawater," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    16. Earl Matthew Davis & Arno Bergmann & Chao Zhan & Helmut Kuhlenbeck & Beatriz Roldan Cuenya, 2023. "Comparative study of Co3O4(111), CoFe2O4(111), and Fe3O4(111) thin film electrocatalysts for the oxygen evolution reaction," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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