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Simulation of Syngas Production from Lignin Using Guaiacol as a Model Compound

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  • Nancy Eloísa Rodríguez-Olalde

    (Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo. Edificio "V1", Ciudad Universitaria, 58060, Morelia, Michoacán, Mexico)

  • Erick Alejandro Mendoza-Chávez

    (Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo. Edificio "V1", Ciudad Universitaria, 58060, Morelia, Michoacán, Mexico)

  • Agustín Jaime Castro-Montoya

    (Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo. Edificio "V1", Ciudad Universitaria, 58060, Morelia, Michoacán, Mexico)

  • Jaime Saucedo-Luna

    (Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo. Edificio "V1", Ciudad Universitaria, 58060, Morelia, Michoacán, Mexico)

  • Rafael Maya-Yescas

    (Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo. Edificio "V1", Ciudad Universitaria, 58060, Morelia, Michoacán, Mexico)

  • José Guadalupe Rutiaga-Quiñones

    (Facultad de Ingeniería en Tecnología de la Madera, Universidad Michoacana de San Nicolás de Hidalgo. Edificio "D", Ciudad Universitaria, 58060, Morelia, Michoacán, Mexico)

  • José María Ponce Ortega

    (Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo. Edificio "V1", Ciudad Universitaria, 58060, Morelia, Michoacán, Mexico)

Abstract

Lignin is an abundant component in biomass that can be used a feedstock for producing several value-added products, including biofuels. However, lignin is a complex molecule (involving in its structure three types of phenylpropane units: coumaryl, coniferyl and sinapyl), which is difficult to implement in any process simulation task. The lignin from softwood is formed mainly by coniferyl units; therefore, in this work the use of the guaiacol molecule to model softwood lignin in the simulation of the syngas process (H 2 + CO) is proposed. A Gibbs reactor in ASPEN PLUS ® was feed with ratios of water and guaiacol from 0.5 to 20. The pressure was varied from 0.05 to 1.01 MPa and the temperature in the range of 200–3200 °C. H 2 , CO, CO 2 , CH 4 , O 2 and C as graphite were considered in the output stream. The pressure, temperature and ratio water/guaiacol conditions for syngas production for different H 2 /CO ratio are discussed. The obtained results allow to determine the operating conditions to improve the syngas production and show that C as graphite and water decomposition can be avoided.

Suggested Citation

  • Nancy Eloísa Rodríguez-Olalde & Erick Alejandro Mendoza-Chávez & Agustín Jaime Castro-Montoya & Jaime Saucedo-Luna & Rafael Maya-Yescas & José Guadalupe Rutiaga-Quiñones & José María Ponce Ortega, 2015. "Simulation of Syngas Production from Lignin Using Guaiacol as a Model Compound," Energies, MDPI, vol. 8(7), pages 1-10, June.
    • Handle: RePEc:gam:jeners:v:8:y:2015:i:7:p:6705-6714:d:51903
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    References listed on IDEAS

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    Cited by:

    1. Antonio Molino & Vincenzo Larocca & Simeone Chianese & Dino Musmarra, 2018. "Biofuels Production by Biomass Gasification: A Review," Energies, MDPI, vol. 11(4), pages 1-31, March.
    2. Henrik Von Storch & Sonja Becker-Hardt & Christian Sattler, 2018. "(Solar) Mixed Reforming of Methane: Potential and Limits in Utilizing CO 2 as Feedstock for Syngas Production—A Thermodynamic Analysis," Energies, MDPI, vol. 11(10), pages 1-14, September.
    3. Qitai Eri & Wenzhen Wu & Xinjun Zhao, 2017. "Numerical Investigation of the Air-Steam Biomass Gasification Process Based on Thermodynamic Equilibrium Model," Energies, MDPI, vol. 10(12), pages 1-19, December.

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