IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v8y2015i7p6705-6714d51903.html
   My bibliography  Save this article

Simulation of Syngas Production from Lignin Using Guaiacol as a Model Compound

Author

Listed:
  • Nancy Eloísa Rodríguez-Olalde

    (Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo. Edificio "V1", Ciudad Universitaria, 58060, Morelia, Michoacán, Mexico)

  • Erick Alejandro Mendoza-Chávez

    (Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo. Edificio "V1", Ciudad Universitaria, 58060, Morelia, Michoacán, Mexico)

  • Agustín Jaime Castro-Montoya

    (Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo. Edificio "V1", Ciudad Universitaria, 58060, Morelia, Michoacán, Mexico)

  • Jaime Saucedo-Luna

    (Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo. Edificio "V1", Ciudad Universitaria, 58060, Morelia, Michoacán, Mexico)

  • Rafael Maya-Yescas

    (Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo. Edificio "V1", Ciudad Universitaria, 58060, Morelia, Michoacán, Mexico)

  • José Guadalupe Rutiaga-Quiñones

    (Facultad de Ingeniería en Tecnología de la Madera, Universidad Michoacana de San Nicolás de Hidalgo. Edificio "D", Ciudad Universitaria, 58060, Morelia, Michoacán, Mexico)

  • José María Ponce Ortega

    (Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo. Edificio "V1", Ciudad Universitaria, 58060, Morelia, Michoacán, Mexico)

Abstract

Lignin is an abundant component in biomass that can be used a feedstock for producing several value-added products, including biofuels. However, lignin is a complex molecule (involving in its structure three types of phenylpropane units: coumaryl, coniferyl and sinapyl), which is difficult to implement in any process simulation task. The lignin from softwood is formed mainly by coniferyl units; therefore, in this work the use of the guaiacol molecule to model softwood lignin in the simulation of the syngas process (H 2 + CO) is proposed. A Gibbs reactor in ASPEN PLUS ® was feed with ratios of water and guaiacol from 0.5 to 20. The pressure was varied from 0.05 to 1.01 MPa and the temperature in the range of 200–3200 °C. H 2 , CO, CO 2 , CH 4 , O 2 and C as graphite were considered in the output stream. The pressure, temperature and ratio water/guaiacol conditions for syngas production for different H 2 /CO ratio are discussed. The obtained results allow to determine the operating conditions to improve the syngas production and show that C as graphite and water decomposition can be avoided.

Suggested Citation

  • Nancy Eloísa Rodríguez-Olalde & Erick Alejandro Mendoza-Chávez & Agustín Jaime Castro-Montoya & Jaime Saucedo-Luna & Rafael Maya-Yescas & José Guadalupe Rutiaga-Quiñones & José María Ponce Ortega, 2015. "Simulation of Syngas Production from Lignin Using Guaiacol as a Model Compound," Energies, MDPI, vol. 8(7), pages 1-10, June.
    • Handle: RePEc:gam:jeners:v:8:y:2015:i:7:p:6705-6714:d:51903
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/8/7/6705/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/8/7/6705/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Azadi, Pooya & Inderwildi, Oliver R. & Farnood, Ramin & King, David A., 2013. "Liquid fuels, hydrogen and chemicals from lignin: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 506-523.
    2. Sang Shin Park & Hyo Jae Jeong & Jungho Hwang, 2015. "3-D CFD Modeling for Parametric Study in a 300-MWe One-Stage Oxygen-Blown Entrained-Bed Coal Gasifier," Energies, MDPI, vol. 8(5), pages 1-21, May.
    3. Yueshi Wu & Weihong Yang & Wlodzimierz Blasiak, 2014. "Energy and Exergy Analysis of High Temperature Agent Gasification of Biomass," Energies, MDPI, vol. 7(4), pages 1-16, April.
    4. Theresa Weith & Florian Heberle & Markus Preißinger & Dieter Brüggemann, 2014. "Performance of Siloxane Mixtures in a High-Temperature Organic Rankine Cycle Considering the Heat Transfer Characteristics during Evaporation," Energies, MDPI, vol. 7(9), pages 1-18, August.
    5. Saxena, R.C. & Seal, Diptendu & Kumar, Satinder & Goyal, H.B., 2008. "Thermo-chemical routes for hydrogen rich gas from biomass: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(7), pages 1909-1927, September.
    6. Sharmina Begum & Mohammad G. Rasul & Delwar Akbar & Naveed Ramzan, 2013. "Performance Analysis of an Integrated Fixed Bed Gasifier Model for Different Biomass Feedstocks," Energies, MDPI, vol. 6(12), pages 1-17, December.
    7. Ajay Kumar & David D. Jones & Milford A. Hanna, 2009. "Thermochemical Biomass Gasification: A Review of the Current Status of the Technology," Energies, MDPI, vol. 2(3), pages 1-26, July.
    8. Jorge E. Preciado & John J. Ortiz-Martinez & Juan C. Gonzalez-Rivera & Rocio Sierra-Ramirez & Gerardo Gordillo, 2012. "Simulation of Synthesis Gas Production from Steam Oxygen Gasification of Colombian Coal Using Aspen Plus ®," Energies, MDPI, vol. 5(12), pages 1-17, November.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Antonio Molino & Vincenzo Larocca & Simeone Chianese & Dino Musmarra, 2018. "Biofuels Production by Biomass Gasification: A Review," Energies, MDPI, vol. 11(4), pages 1-31, March.
    2. Henrik Von Storch & Sonja Becker-Hardt & Christian Sattler, 2018. "(Solar) Mixed Reforming of Methane: Potential and Limits in Utilizing CO 2 as Feedstock for Syngas Production—A Thermodynamic Analysis," Energies, MDPI, vol. 11(10), pages 1-14, September.
    3. Qitai Eri & Wenzhen Wu & Xinjun Zhao, 2017. "Numerical Investigation of the Air-Steam Biomass Gasification Process Based on Thermodynamic Equilibrium Model," Energies, MDPI, vol. 10(12), pages 1-19, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ramos, Ana & Monteiro, Eliseu & Rouboa, Abel, 2019. "Numerical approaches and comprehensive models for gasification process: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 110(C), pages 188-206.
    2. Burra, K.G. & Hussein, M.S. & Amano, R.S. & Gupta, A.K., 2016. "Syngas evolutionary behavior during chicken manure pyrolysis and air gasification," Applied Energy, Elsevier, vol. 181(C), pages 408-415.
    3. Jiu Huang & Klaus Gerhard Schmidt & Zhengfu Bian, 2011. "Removal and Conversion of Tar in Syngas from Woody Biomass Gasification for Power Utilization Using Catalytic Hydrocracking," Energies, MDPI, vol. 4(8), pages 1-15, August.
    4. Hossam A. Gabbar & Mohamed Aboughaly & Stefano Russo, 2017. "Conceptual Design and Energy Analysis of Integrated Combined Cycle Gasification System," Sustainability, MDPI, vol. 9(8), pages 1-18, August.
    5. Marcelo Hamaguchi & Marcelo Cardoso & Esa Vakkilainen, 2012. "Alternative Technologies for Biofuels Production in Kraft Pulp Mills—Potential and Prospects," Energies, MDPI, vol. 5(7), pages 1-22, July.
    6. Ahmed, Tigabwa Y. & Ahmad, Murni M. & Yusup, Suzana & Inayat, Abrar & Khan, Zakir, 2012. "Mathematical and computational approaches for design of biomass gasification for hydrogen production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 2304-2315.
    7. Domenico Borello & Antonio M. Pantaleo & Michele Caucci & Benedetta De Caprariis & Paolo De Filippis & Nilay Shah, 2017. "Modeling and Experimental Study of a Small Scale Olive Pomace Gasifier for Cogeneration: Energy and Profitability Analysis," Energies, MDPI, vol. 10(12), pages 1-17, November.
    8. Hameed, Zeeshan & Aslam, Muhammad & Khan, Zakir & Maqsood, Khuram & Atabani, A.E. & Ghauri, Moinuddin & Khurram, Muhammad Shahzad & Rehan, Mohammad & Nizami, Abdul-Sattar, 2021. "Gasification of municipal solid waste blends with biomass for energy production and resources recovery: Current status, hybrid technologies and innovative prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 136(C).
    9. Vera Marcantonio & Michael Müller & Enrico Bocci, 2021. "A Review of Hot Gas Cleaning Techniques for Hydrogen Chloride Removal from Biomass-Derived Syngas," Energies, MDPI, vol. 14(20), pages 1-15, October.
    10. Antonio Molino & Vincenzo Larocca & Simeone Chianese & Dino Musmarra, 2018. "Biofuels Production by Biomass Gasification: A Review," Energies, MDPI, vol. 11(4), pages 1-31, March.
    11. Xia Liu & Juntao Wei & Wei Huo & Guangsuo Yu, 2017. "Gasification under CO 2 –Steam Mixture: Kinetic Model Study Based on Shared Active Sites," Energies, MDPI, vol. 10(11), pages 1-10, November.
    12. Matteo Borella & Alessandro A. Casazza & Gabriella Garbarino & Paola Riani & Guido Busca, 2022. "A Study of the Pyrolysis Products of Kraft Lignin," Energies, MDPI, vol. 15(3), pages 1-15, January.
    13. Chen, Zhu & Wan, Caixia, 2017. "Biological valorization strategies for converting lignin into fuels and chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 610-621.
    14. Smoliński, A. & Howaniec, N. & Stańczyk, K., 2011. "A comparative experimental study of biomass, lignite and hard coal steam gasification," Renewable Energy, Elsevier, vol. 36(6), pages 1836-1842.
    15. M. Faizal & L. S. Chuah & C. Lee & A. Hameed & J. Lee & M. Shankar, 2019. "Review Of Hydrogen Fuel For Internal Combustion Engines," Journal of Mechanical Engineering Research & Developments (JMERD), Zibeline International Publishing, vol. 42(3), pages 35-46, April.
    16. Ummartyotin, Sarute & Manuspiya, Hathaikarn, 2015. "A critical review on cellulose: From fundamental to an approach on sensor technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 402-412.
    17. Zhou, Hui & Park, Ah-Hyung Alissa, 2020. "Bio-energy with carbon capture and storage via alkaline thermal Treatment: Production of high purity H2 from wet wheat straw grass with CO2 capture," Applied Energy, Elsevier, vol. 264(C).
    18. Masnadi, Mohammad S. & Grace, John R. & Bi, Xiaotao T. & Lim, C. Jim & Ellis, Naoko & Li, Yong Hua & Watkinson, A. Paul, 2015. "From coal towards renewables: Catalytic/synergistic effects during steam co-gasification of switchgrass and coal in a pilot-scale bubbling fluidized bed," Renewable Energy, Elsevier, vol. 83(C), pages 918-930.
    19. Gallarini, Simone & Spinelli, Andrea & Lietti, Luca & Guardone, Alberto, 2023. "Thermal stability of linear siloxanes and their mixtures," Energy, Elsevier, vol. 278(C).
    20. David Bannon & Mirka Deza & Masoud Masoumi & Bahareh Estejab, 2023. "Assessment of Irregular Biomass Particles Fluidization in Bubbling Fluidized Beds," Energies, MDPI, vol. 16(4), pages 1-20, February.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:8:y:2015:i:7:p:6705-6714:d:51903. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.