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Adsorptive Biogas Purification from Siloxanes—A Critical Review

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  • Kazimierz Gaj

    (Faculty of Environmental Engineering, Wroclaw University of Science and Technology, 50-370 Wrocław, Poland)

Abstract

Siloxanes are among the most technologically troublesome trace compounds present in biogas. As a result of their combustion, hard-to-remove sediments are formed, blocking biogas energy processing devices and reducing the efficiency of biogas plants. The purpose of this study was to help investors and designers to choose the optimal technology for the adsorptive removal of volatile methylsiloxanes (VMSs) from biogas and to identify adsorbents worth further development. This paper critically reviews and discusses the state-of-the-art technologies for the adsorption removal of siloxanes from biogas, indicating potentially beneficial directions in their development and deficiencies in the state of knowledge. The origin of VMSs in biogas, their selected physicochemical properties, technological problems that they can cause and their typical versus limit concentrations in biogases are presented. Both the already implemented methods of adsorptive VMSs removal from landfill and sewage gases and the ones being under development are verified and systematized. The parameters and effectiveness of adsorption processes are discussed, and individual adsorbents are compared. Possible ways of regenerating spent adsorbents are evaluated and prospects for their application are assessed. Finally, zeolite-based adsorbents—which can also be used for biogas desulfurization—and adsorbents based on polymer resins, as being particularly active against VMSs and most amenable to multiple regeneration, are identified.

Suggested Citation

  • Kazimierz Gaj, 2020. "Adsorptive Biogas Purification from Siloxanes—A Critical Review," Energies, MDPI, vol. 13(10), pages 1-10, May.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:10:p:2605-:d:360884
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    1. Gong, Huijuan & Chen, Zezhi & Fan, Yangmei & Zhang, Mengqun & Wu, Weili & Wang, Weibing, 2015. "Surface modification of activated carbon for siloxane adsorption," Renewable Energy, Elsevier, vol. 83(C), pages 144-150.
    2. Ana Almeida & Rui P. P. L. Ribeiro & José P. B. Mota & Carlos Grande, 2020. "Extrusion and Characterization of High Si/Al Ratio ZSM-5 Using Silica Binder," Energies, MDPI, vol. 13(5), pages 1-15, March.
    3. Rasi, Saija & Lehtinen, Jenni & Rintala, Jukka, 2010. "Determination of organic silicon compounds in biogas from wastewater treatments plants, landfills, and co-digestion plants," Renewable Energy, Elsevier, vol. 35(12), pages 2666-2673.
    4. Jung, Hyounduk & Lee, Dae-Young & Jurng, Jongsoo, 2017. "Low-temperature regeneration of novel polymeric adsorbent on decamethylcyclopentasiloxane (D5) removal for cost-effective purification of biogases from siloxane," Renewable Energy, Elsevier, vol. 111(C), pages 718-723.
    5. de Arespacochaga, N. & Valderrama, C. & Raich-Montiu, J. & Crest, M. & Mehta, S. & Cortina, J.L., 2015. "Understanding the effects of the origin, occurrence, monitoring, control, fate and removal of siloxanes on the energetic valorization of sewage biogas—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 366-381.
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    Cited by:

    1. Kazimierz Gaj & Urszula Miller & Izabela Sówka, 2020. "Progressing Climate Changes and Deteriorating Air Quality as One of the Biggest Challenges of Sustainable Development of the Present Decade in Poland," Sustainability, MDPI, vol. 12(16), pages 1-4, August.
    2. Hou, Xifeng & Zheng, Yanhui & Lv, Siqi & Ma, Zichuan & Ma, Xiaolong, 2022. "Effective removal of hexamethyldisiloxane using a citric acid modified three-dimensional graphene aerogel," Renewable Energy, Elsevier, vol. 199(C), pages 62-70.
    3. Lv, Siqi & Zhang, Rui & He, Yuanping & Ma, Zichuan & Ma, Xiaolong, 2024. "Efficient reactive adsorption of hexamethyldisiloxane on MCM-41 supported sulfuric acid," Renewable Energy, Elsevier, vol. 224(C).
    4. Kazimierz Gaj & Klaudia Cichuta, 2022. "Combined Biological Method for Simultaneous Removal of Hydrogen Sulphide and Volatile Methylsiloxanes from Biogas," Energies, MDPI, vol. 16(1), pages 1-18, December.
    5. Zheng, Yanhui & Hou, Xifeng & Liu, Yuheng & Ma, Zichuan, 2021. "Hexamethyldisiloxane removal from biogas using reduced graphene-oxide aerogels as adsorbents," Renewable Energy, Elsevier, vol. 178(C), pages 153-161.
    6. Pardon Nyamukamba & Patrick Mukumba & Evernice Shelter Chikukwa & Golden Makaka, 2020. "Biogas Upgrading Approaches with Special Focus on Siloxane Removal—A Review," Energies, MDPI, vol. 13(22), pages 1-17, November.

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