IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v177y2021icp61-71.html
   My bibliography  Save this article

Sampling, on-line and off-line measurement of organic silicon compounds at an industrial biogas-fed 175-kWe SOFC plant

Author

Listed:
  • Calbry-Muzyka, Adelaide
  • Tarik, Mohamed
  • Gandiglio, Marta
  • Li, Jianrong
  • Foppiano, Debora
  • de Krom, Iris
  • Heikens, Dita
  • Ludwig, Christian
  • Biollaz, Serge

Abstract

The use of biogas in the energy sector requires efficient removal of harmful trace levels of impurities. Reliable and robust online analytical equipment to measure these impurities is necessary and must be validated using offline techniques. In this work, total silicon and siloxanes were measured at an industrial solid oxide fuel cell fed by biogas. SOFC anodes are sensitive to silicon-based contaminants even at parts-per-billion levels. Online measurements of total silicon were carried out using a nondispersive infrared sensor (NDIR). Different sampling methods, including chemical adsorption, liquid quenching, and solid-phase adsorption were used at six biogas sampling points. Organic silicon compounds in the samples were determined by offline methods including GC-FID and GC-ICP-MS. The online analyzer's performance was satisfactory in both untreated biogas, where it agreed within the error margin of the most reliable offline technique used, and in clean biogas, where <0.1 mgSi/m3 siloxanes were detected. Several operational issues with different offline sampling and analytical methods are discussed, as is the performance of the sorbent-based biogas cleaning system used.

Suggested Citation

  • Calbry-Muzyka, Adelaide & Tarik, Mohamed & Gandiglio, Marta & Li, Jianrong & Foppiano, Debora & de Krom, Iris & Heikens, Dita & Ludwig, Christian & Biollaz, Serge, 2021. "Sampling, on-line and off-line measurement of organic silicon compounds at an industrial biogas-fed 175-kWe SOFC plant," Renewable Energy, Elsevier, vol. 177(C), pages 61-71.
    • Handle: RePEc:eee:renene:v:177:y:2021:i:c:p:61-71
    DOI: 10.1016/j.renene.2021.05.047
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148121007230
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2021.05.047?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Scarlat, Nicolae & Dallemand, Jean-François & Fahl, Fernando, 2018. "Biogas: Developments and perspectives in Europe," Renewable Energy, Elsevier, vol. 129(PA), pages 457-472.
    2. Saadabadi, S. Ali & Thallam Thattai, Aditya & Fan, Liyuan & Lindeboom, Ralph E.F. & Spanjers, Henri & Aravind, P.V., 2019. "Solid Oxide Fuel Cells fuelled with biogas: Potential and constraints," Renewable Energy, Elsevier, vol. 134(C), pages 194-214.
    3. Papadias, Dionissios D. & Ahmed, Shabbir & Kumar, Romesh, 2012. "Fuel quality issues with biogas energy – An economic analysis for a stationary fuel cell system," Energy, Elsevier, vol. 44(1), pages 257-277.
    4. Rasi, Saija & Lehtinen, Jenni & Rintala, Jukka, 2010. "Determination of organic silicon compounds in biogas from wastewater treatments plants, landfills, and co-digestion plants," Renewable Energy, Elsevier, vol. 35(12), pages 2666-2673.
    5. de Arespacochaga, N. & Valderrama, C. & Raich-Montiu, J. & Crest, M. & Mehta, S. & Cortina, J.L., 2015. "Understanding the effects of the origin, occurrence, monitoring, control, fate and removal of siloxanes on the energetic valorization of sewage biogas—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 366-381.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Gandiglio, Marta, 2022. "Design and operation of an industrial size adsorption-based cleaning system for biogas use in fuel cells," Energy, Elsevier, vol. 259(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Roberto Paglini & Marta Gandiglio & Andrea Lanzini, 2022. "Technologies for Deep Biogas Purification and Use in Zero-Emission Fuel Cells Systems," Energies, MDPI, vol. 15(10), pages 1-30, May.
    2. Rasi, S. & Seppälä, M. & Rintala, J., 2013. "Organic silicon compounds in biogases produced from grass silage, grass and maize in laboratory batch assays," Energy, Elsevier, vol. 52(C), pages 137-142.
    3. Xue, Shengrong & Zhang, Siqi & Wang, Ying & Wang, Yanbo & Song, Jinghui & Lyu, Xingang & Wang, Xiaojiao & Yang, Gaihe, 2022. "What can we learn from the experience of European countries in biomethane industry: Taking China as an example?," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    4. Henry Wasajja & Saqr A. A. Al-Muraisy & Antonella L. Piaggio & Pamela Ceron-Chafla & Purushothaman Vellayani Aravind & Henri Spanjers & Jules B. van Lier & Ralph E. F. Lindeboom, 2021. "Improvement of Biogas Quality and Quantity for Small-Scale Biogas-Electricity Generation Application in off-Grid Settings: A Field-Based Study," Energies, MDPI, vol. 14(11), pages 1-20, May.
    5. Kazimierz Gaj, 2020. "Adsorptive Biogas Purification from Siloxanes—A Critical Review," Energies, MDPI, vol. 13(10), pages 1-10, May.
    6. Costas Athanasiou & Christos Drosakis & Gaylord Kabongo Booto & Costas Elmasides, 2022. "Economic Feasibility of Power/Heat Cogeneration by Biogas–Solid Oxide Fuel Cell (SOFC) Integrated Systems," Energies, MDPI, vol. 16(1), pages 1-30, December.
    7. Josipa Pavičić & Karolina Novak Mavar & Vladislav Brkić & Katarina Simon, 2022. "Biogas and Biomethane Production and Usage: Technology Development, Advantages and Challenges in Europe," Energies, MDPI, vol. 15(8), pages 1-28, April.
    8. Rey, M.D. & Font, R. & Aracil, I., 2013. "Biogas from MSW landfill: Composition and determination of chlorine content with the AOX (adsorbable organically bound halogens) technique," Energy, Elsevier, vol. 63(C), pages 161-167.
    9. Tiwari, Prince & Wang, Tiantian & Indlekofer, Julian & El Haddad, Imad & Biollaz, Serge & Prevot, Andre Stephan Henry & Lamkaddam, Houssni, 2022. "Online detection of trace volatile organic sulfur compounds in a complex biogas mixture with proton-transfer-reaction mass spectrometry," Renewable Energy, Elsevier, vol. 196(C), pages 1197-1203.
    10. González, Ruben & García-Cascallana, José & Gómez, Xiomar, 2023. "Energetic valorization of biogas. A comparison between centralized and decentralized approach," Renewable Energy, Elsevier, vol. 215(C).
    11. Mac Clay, Pablo & Börner, Jan & Sellare, Jorge, 2023. "Institutional and macroeconomic stability mediate the effect of auctions on renewable energy capacity," Energy Policy, Elsevier, vol. 180(C).
    12. Papurello, Davide & Lanzini, Andrea & Drago, Davide & Leone, Pierluigi & Santarelli, Massimo, 2016. "Limiting factors for planar solid oxide fuel cells under different trace compound concentrations," Energy, Elsevier, vol. 95(C), pages 67-78.
    13. Fernandez, Helen Coarita & Buffiere, Pierre & Bayard, Rémy, 2022. "Understanding the role of mechanical pretreatment before anaerobic digestion: Lab-scale investigations," Renewable Energy, Elsevier, vol. 187(C), pages 193-203.
    14. Dumitru Peni & Marcin Dębowski & Mariusz Jerzy Stolarski, 2022. "Influence of the Fertilization Method on the Silphium perfoliatum Biomass Composition and Methane Fermentation Efficiency," Energies, MDPI, vol. 15(3), pages 1-13, January.
    15. Maktabifard, Mojtaba & Al-Hazmi, Hussein E. & Szulc, Paulina & Mousavizadegan, Mohammad & Xu, Xianbao & Zaborowska, Ewa & Li, Xiang & Mąkinia, Jacek, 2023. "Net-zero carbon condition in wastewater treatment plants: A systematic review of mitigation strategies and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 185(C).
    16. Surita, Sharon C. & Tansel, Berrin, 2015. "Preliminary investigation to characterize deposits forming during combustion of biogas from anaerobic digesters and landfills," Renewable Energy, Elsevier, vol. 80(C), pages 674-681.
    17. Md Muzammel Hossain & Yuan Yuan & Hengliang Huang & Ziwei Wang & Mohammad Abdul Baki & Zhihua Dai & Muhammad Rizwan & Shuanglian Xiong & Menghua Cao & Shuxin Tu, 2021. "Exposure to Dodecamethylcyclohexasiloxane (D6) Affects the Antioxidant Response and Gene Expression of Procambarus clarkii," Sustainability, MDPI, vol. 13(6), pages 1-12, March.
    18. Sofia Dahlgren & Jonas Ammenberg, 2021. "Sustainability Assessment of Public Transport, Part II—Applying a Multi-Criteria Assessment Method to Compare Different Bus Technologies," Sustainability, MDPI, vol. 13(3), pages 1-30, January.
    19. Park, Min-Ju & Kim, Hak-Min & Gu, Yun-Jeong & Jeong, Dae-Woon, 2023. "Optimization of biogas-reforming conditions considering carbon formation, hydrogen production, and energy efficiencies," Energy, Elsevier, vol. 265(C).
    20. Elena Tamburini & Mattias Gaglio & Giuseppe Castaldelli & Elisa Anna Fano, 2020. "Is Bioenergy Truly Sustainable When Land-Use-Change (LUC) Emissions Are Accounted for? The Case-Study of Biogas from Agricultural Biomass in Emilia-Romagna Region, Italy," Sustainability, MDPI, vol. 12(8), pages 1-20, April.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:177:y:2021:i:c:p:61-71. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.