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Methanol synthesis from biogas: A thermodynamic analysis

Author

Listed:
  • Vita, A.
  • Italiano, C.
  • Previtali, D.
  • Fabiano, C.
  • Palella, A.
  • Freni, F.
  • Bozzano, G.
  • Pino, L.
  • Manenti, F.

Abstract

A new approach for the direct conversion of syngas into methanol has been proposed as alternative to the conventional process requiring WGS and/or PSA clean-up steps for syngas upgrading. A comparative thermodynamic equilibrium analysis of biogas reforming processes (dry reforming, steam reforming and oxy-steam reforming) has been performed using the Gibbs free energy minimization method. The calculations have been carried out under different biogas composition (CH4/CO2 = 1–2.3), reaction temperature (400–900 °C), S/CH4 (0.0–3.0) and O2/CH4 (0.0–0.2) molar ratios. The effects of process variables on the reforming performances as well as on the syngas quality, in term of CH4 and CO2 conversion, H2/CO and H2/CO2 ratios, coke deposition and energetic consumption, has been examined. Subsequently, methanol synthesis has been studied using the same mathematical approach, with the aim to identify the most adequate operating conditions for the direct conversion of the syngas obtained from reforming process into methanol. The simulations suggested that steam reforming of biogas, with high methane content, is the most appropriate route to produce a syngas quality suitable for the new proposed approach.

Suggested Citation

  • Vita, A. & Italiano, C. & Previtali, D. & Fabiano, C. & Palella, A. & Freni, F. & Bozzano, G. & Pino, L. & Manenti, F., 2018. "Methanol synthesis from biogas: A thermodynamic analysis," Renewable Energy, Elsevier, vol. 118(C), pages 673-684.
    • Handle: RePEc:eee:renene:v:118:y:2018:i:c:p:673-684
    DOI: 10.1016/j.renene.2017.11.029
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    1. Budzianowski, Wojciech M., 2016. "A review of potential innovations for production, conditioning and utilization of biogas with multiple-criteria assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 1148-1171.
    2. Zhou, Chunguang & Zhang, Lan & Swiderski, Artur & Yang, Weihong & Blasiak, Wlodzimierz, 2011. "Study and development of a high temperature process of multi-reformation of CH4 with CO2 for remediation of greenhouse gas," Energy, Elsevier, vol. 36(9), pages 5450-5459.
    3. Rasi, S. & Veijanen, A. & Rintala, J., 2007. "Trace compounds of biogas from different biogas production plants," Energy, Elsevier, vol. 32(8), pages 1375-1380.
    4. Braga, Lúcia Bollini & Silveira, Jose Luz & da Silva, Marcio Evaristo & Tuna, Celso Eduardo & Machin, Einara Blanco & Pedroso, Daniel Travieso, 2013. "Hydrogen production by biogas steam reforming: A technical, economic and ecological analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 166-173.
    5. Osorio, F. & Torres, J.C., 2009. "Biogas purification from anaerobic digestion in a wastewater treatment plant for biofuel production," Renewable Energy, Elsevier, vol. 34(10), pages 2164-2171.
    6. Rasi, Saija & Lehtinen, Jenni & Rintala, Jukka, 2010. "Determination of organic silicon compounds in biogas from wastewater treatments plants, landfills, and co-digestion plants," Renewable Energy, Elsevier, vol. 35(12), pages 2666-2673.
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    2. Ray, Debjyoti & Nepak, Devadutta & Vinodkumar, T. & Subrahmanyam, Ch., 2019. "g-C3N4 promoted DBD plasma assisted dry reforming of methane," Energy, Elsevier, vol. 183(C), pages 630-638.
    3. Lee, Boreum & Lee, Hyunjun & Lim, Dongjun & Brigljević, Boris & Cho, Wonchul & Cho, Hyun-Seok & Kim, Chang-Hee & Lim, Hankwon, 2020. "Renewable methanol synthesis from renewable H2 and captured CO2: How can power-to-liquid technology be economically feasible?," Applied Energy, Elsevier, vol. 279(C).
    4. Siang, T.J. & Jalil, A.A. & Abdulrasheed, A.A. & Hambali, H.U. & Nabgan, Walid, 2020. "Thermodynamic equilibrium study of altering methane partial oxidation for Fischer–Tropsch synfuel production," Energy, Elsevier, vol. 198(C).

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