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Organic silicon compounds in biogases produced from grass silage, grass and maize in laboratory batch assays

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  • Rasi, S.
  • Seppälä, M.
  • Rintala, J.

Abstract

In the present study the occurrence of volatile organic silicon compounds in biogas produced from grass silage, grass and maize in laboratory batch assays was analyzed and methane potentials were determined. Inoculum from a mesophilic farm digester was used, and its effects were subtracted. Methane yields from grass silage, grass and maize were 0.38, 0.42 and 0.34 m3CH4/kg – volatile solids added (VSadd), respectively. Trimethyl silanol, hexamethylcyclotrisiloxane (D3), octamethylcyclotetrasiloxane (D4) and decamethylcyclopentasiloxane (D5) were detected from all the biogases. Higher yields of volatile organic silicon compounds in the grass (from 21.8 to 37.6 μg/kgVSadd) were detected than in grass silage or maize assays (from 14.7 to 20.4 and from 7.4 to 12.1 μg/kgVSadd, respectively). Overall, it is important to consider silicon-containing compounds also in biogases in energy crop digestion as the number of biogas plants using energy crops as feeding material increases and some biogas applications are sensitive to organic silicon compounds.

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  • Rasi, S. & Seppälä, M. & Rintala, J., 2013. "Organic silicon compounds in biogases produced from grass silage, grass and maize in laboratory batch assays," Energy, Elsevier, vol. 52(C), pages 137-142.
    • Handle: RePEc:eee:energy:v:52:y:2013:i:c:p:137-142
    DOI: 10.1016/j.energy.2013.01.015
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    1. Rey, M.D. & Font, R. & Aracil, I., 2013. "Biogas from MSW landfill: Composition and determination of chlorine content with the AOX (adsorbable organically bound halogens) technique," Energy, Elsevier, vol. 63(C), pages 161-167.
    2. Dong, Feiqing & Lu, Jianbo, 2013. "Using solar energy to enhance biogas production from livestock residue – A case study of the Tongren biogas engineering pig farm in South China," Energy, Elsevier, vol. 57(C), pages 759-765.
    3. Calbry-Muzyka, Adelaide & Madi, Hossein & Rüsch-Pfund, Florian & Gandiglio, Marta & Biollaz, Serge, 2022. "Biogas composition from agricultural sources and organic fraction of municipal solid waste," Renewable Energy, Elsevier, vol. 181(C), pages 1000-1007.
    4. Lombardi, Lidia & Carnevale, Ennio, 2013. "Economic evaluations of an innovative biogas upgrading method with CO2 storage," Energy, Elsevier, vol. 62(C), pages 88-94.

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