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Compatibility of elastomers in palm biodiesel

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  • Haseeb, A.S.M.A.
  • Masjuki, H.H.
  • Siang, C.T.
  • Fazal, M.A.

Abstract

In recent time, environmental awareness and concern over the rapid exhaustion of fossil fuels have led to an increased popularity of biodiesel as an alternative fuel for automobiles. However, there are concerns over enhanced degradation of automotive materials in biodiesel. The present study aims to investigate the impact of palm biodiesel on the degradation behavior of elastomers such as nitrile rubber (NBR), polychloroprene, and fluoro-viton A. Static immersion tests in B0 (diesel), B10 (10% biodiesel in diesel), B100 (biodiesel) were carried out at room temperature (25 °C) and at 50 °C for 500 h. At the end of immersion test, degradation behavior was investigated by measuring mass, volume, hardness as well as tensile strength and elongation. The exposed elastomer surface was studied by scanning electron microscopy (SEM). Fourier Transform Infrared (FTIR) spectroscopy was carried out to identify the chemical and structural changes. Results showed that the extent of degradation was higher for both polychloroprene and NBR while fluoro-viton exhibited good resistance to degradation and was least attacked.

Suggested Citation

  • Haseeb, A.S.M.A. & Masjuki, H.H. & Siang, C.T. & Fazal, M.A., 2010. "Compatibility of elastomers in palm biodiesel," Renewable Energy, Elsevier, vol. 35(10), pages 2356-2361.
  • Handle: RePEc:eee:renene:v:35:y:2010:i:10:p:2356-2361
    DOI: 10.1016/j.renene.2010.03.011
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    References listed on IDEAS

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    1. Haseeb, A.S.M.A. & Sia, S.Y. & Fazal, M.A. & Masjuki, H.H., 2010. "Effect of temperature on tribological properties of palm biodiesel," Energy, Elsevier, vol. 35(3), pages 1460-1464.
    2. Trakarnpruk, Wimonrat & Porntangjitlikit, Suriya, 2008. "Palm oil biodiesel synthesized with potassium loaded calcined hydrotalcite and effect of biodiesel blend on elastomer properties," Renewable Energy, Elsevier, vol. 33(7), pages 1558-1563.
    3. Eevera, T. & Rajendran, K. & Saradha, S., 2009. "Biodiesel production process optimization and characterization to assess the suitability of the product for varied environmental conditions," Renewable Energy, Elsevier, vol. 34(3), pages 762-765.
    4. Körbitz, W., 1999. "Biodiesel production in Europe and North America, an encouraging prospect," Renewable Energy, Elsevier, vol. 16(1), pages 1078-1083.
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    3. Coronado, Marcos & Montero, Gisela & Valdez, Benjamín & Stoytcheva, Margarita & Eliezer, Amir & García, Conrado & Campbell, Héctor & Pérez, Armando, 2014. "Degradation of nitrile rubber fuel hose by biodiesel use," Energy, Elsevier, vol. 68(C), pages 364-369.
    4. Singh, B. & Korstad, John & Sharma, Y.C., 2012. "A critical review on corrosion of compression ignition (CI) engine parts by biodiesel and biodiesel blends and its inhibition," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3401-3408.
    5. Linhares, Felipe Nunes & Corrêa, Harrison Lourenço & Khalil, Carlos Nagib & Amorim Moreira Leite, Márcia Christina & Guimarães Furtado, Cristina Russi, 2013. "Study of the compatibility of nitrile rubber with Brazilian biodiesel," Energy, Elsevier, vol. 49(C), pages 102-106.
    6. Shekarchian, M. & Moghavvemi, M. & Mahlia, T.M.I. & Mazandarani, A., 2011. "A review on the pattern of electricity generation and emission in Malaysia from 1976 to 2008," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(6), pages 2629-2642, August.
    7. Fazal, M.A. & Haseeb, A.S.M.A. & Masjuki, H.H., 2011. "Biodiesel feasibility study: An evaluation of material compatibility; performance; emission and engine durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(2), pages 1314-1324, February.
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    9. Shekarchian, M. & Moghavvemi, M. & Motasemi, F. & Zarifi, F. & Mahlia, T.M.I., 2012. "Energy and fuel consumption forecast by retrofitting absorption cooling in Malaysia from 2012 to 2025," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 6128-6141.
    10. Farfan-Cabrera, Leonardo Israel & Pérez-González, José & Gallardo-Hernández, Ezequiel Alberto, 2018. "Deterioration of seals of automotive fuel systems upon exposure to straight Jatropha oil and diesel," Renewable Energy, Elsevier, vol. 127(C), pages 125-133.
    11. Haseeb, A.S.M.A. & Jun, T.S. & Fazal, M.A. & Masjuki, H.H., 2011. "Degradation of physical properties of different elastomers upon exposure to palm biodiesel," Energy, Elsevier, vol. 36(3), pages 1814-1819.
    12. Sorate, Kamalesh A. & Bhale, Purnanand V., 2015. "Biodiesel properties and automotive system compatibility issues," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 777-798.

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    Keywords

    Elastomer; Biodiesel; Diesel;
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