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Degradation of automotive materials in palm biodiesel

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  • Fazal, M.A.
  • Haseeb, A.S.M.A.
  • Masjuki, H.H.

Abstract

As compared to petroleum diesel, biodiesel is more corrosive for automotive materials. Studies on the characterization of corrosion products of fuel exposed automotive materials are scarce. Automotive fuel system and engine components are made from different ferrous and non-ferrous materials. The present study aims to investigate the corrosion products of different types of automotive materials such as copper, brass, aluminum and cast iron upon exposure to diesel and palm biodiesel. Changes in fuel properties due to exposure of different materials were also examined. Degradation of metal surface was characterized by digital camera, SEM/EDS and X-ray diffraction (XRD). Fuel properties were examined by measuring TAN (total acid number), density and viscosity. Among the metal investigated, copper is found to be least resistant in biodiesel and formed comparatively more corrosion products than other metals. Upon exposure of metals in biodiesel, TAN number crosses the limit given by standard while density and viscosity remain within the acceptable range of limit.

Suggested Citation

  • Fazal, M.A. & Haseeb, A.S.M.A. & Masjuki, H.H., 2012. "Degradation of automotive materials in palm biodiesel," Energy, Elsevier, vol. 40(1), pages 76-83.
    • Handle: RePEc:eee:energy:v:40:y:2012:i:1:p:76-83
    DOI: 10.1016/j.energy.2012.02.026
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    References listed on IDEAS

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    Cited by:

    1. Sundus, F. & Fazal, M.A. & Masjuki, H.H., 2017. "Tribology with biodiesel: A study on enhancing biodiesel stability and its fuel properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 399-412.
    2. Chandran, Davannendran, 2020. "Compatibility of diesel engine materials with biodiesel fuel," Renewable Energy, Elsevier, vol. 147(P1), pages 89-99.
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    5. Serqueira, Dalyelli S. & Pereira, Jian F.S. & Squissato, André L. & Rodrigues, Mônica A. & Lima, Renata C. & Faria, Anízio M. & Richter, Eduardo M. & Munoz, Rodrigo A.A., 2021. "Oxidative stability and corrosivity of biodiesel produced from residual cooking oil exposed to copper and carbon steel under simulated storage conditions: Dual effect of antioxidants," Renewable Energy, Elsevier, vol. 164(C), pages 1485-1495.
    6. Kugelmeier, Cristie Luis & Monteiro, Marcos Roberto & da Silva, Rodrigo & Kuri, Sebastião Elias & Sordi, Vitor Luiz & Della Rovere, Carlos Alberto, 2021. "Corrosion behavior of carbon steel, stainless steel, aluminum and copper upon exposure to biodiesel blended with petrodiesel," Energy, Elsevier, vol. 226(C).
    7. Rocabruno-Valdés, C.I. & González-Rodriguez, J.G. & Díaz-Blanco, Y. & Juantorena, A.U. & Muñoz-Ledo, J.A. & El-Hamzaoui, Y. & Hernández, J.A., 2019. "Corrosion rate prediction for metals in biodiesel using artificial neural networks," Renewable Energy, Elsevier, vol. 140(C), pages 592-601.
    8. Fernandes, David M. & Squissato, André L. & Lima, Alexandre F. & Richter, Eduardo M. & Munoz, Rodrigo A.A., 2019. "Corrosive character of Moringa oleifera Lam biodiesel exposed to carbon steel under simulated storage conditions," Renewable Energy, Elsevier, vol. 139(C), pages 1263-1271.
    9. Fazal, M.A. & Jakeria, M.R. & Haseeb, A.S.M.A. & Rubaiee, Saeed, 2017. "Effect of antioxidants on the stability and corrosiveness of palm biodiesel upon exposure of different metals," Energy, Elsevier, vol. 135(C), pages 220-226.
    10. Chew, K.V. & Haseeb, A.S.M.A. & Masjuki, H.H. & Fazal, M.A. & Gupta, M., 2013. "Corrosion of magnesium and aluminum in palm biodiesel: A comparative evaluation," Energy, Elsevier, vol. 57(C), pages 478-483.
    11. Aamir Shehzad & Arslan Ahmed & Moinuddin Mohammed Quazi & Muhammad Jamshaid & S. M. Ashrafur Rahman & Masjuki Haji Hassan & Hafiz Muhammad Asif Javed, 2021. "Current Research and Development Status of Corrosion Behavior of Automotive Materials in Biofuels," Energies, MDPI, vol. 14(5), pages 1-36, March.
    12. Jakeria, M.R. & Fazal, M.A. & Haseeb, A.S.M.A., 2014. "Influence of different factors on the stability of biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 154-163.
    13. Chen, Tao & Hu, Run-Ze & Yao, Xiao-Hui & Yang, Qiang & Shuai, Shi-Min & Wang, Jun & Xu, Ming & Zhang, Dong-Yang & Fu, Yu-Jie & Li, Long & Zhao, Wei-Guo, 2020. "Effect of Pyrola extract on the stability of palm biodiesel upon exposure to copper," Renewable Energy, Elsevier, vol. 149(C), pages 1282-1289.
    14. Thangavelu, Saravana Kannan & Ahmed, Abu Saleh & Ani, Farid Nasir, 2016. "Impact of metals on corrosive behavior of biodiesel–diesel–ethanol (BDE) alternative fuel," Renewable Energy, Elsevier, vol. 94(C), pages 1-9.
    15. Sui, Meng & Li, Fashe, 2019. "Effect of TEPA on oxidation stability and metal ion content of biodiesel," Renewable Energy, Elsevier, vol. 143(C), pages 352-358.
    16. E, Jiaqiang & Pham, Minhhieu & Zhao, D. & Deng, Yuanwang & Le, DucHieu & Zuo, Wei & Zhu, Hao & Liu, Teng & Peng, Qingguo & Zhang, Zhiqing, 2017. "Effect of different technologies on combustion and emissions of the diesel engine fueled with biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 620-647.

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