IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v219y2023ip1s0960148123013757.html
   My bibliography  Save this article

Fuel phase extraction from pyrolytic liquid of Azadirachta indica biomass followed by subsequent characterization of pyrolysis products

Author

Listed:
  • Ahmed, Gaffer
  • Kishore, Nanda

Abstract

Growing concerns over fossil fuel utilization and their impending scarcity have spurred a transition towards renewable energy sources. Among these, biomass has gained remarkable traction due to its widespread availability and adaptability. Pyrolysis, amid various biomass conversion routes, boasts advantages like moderate operating conditions, facile handling and efficient product distribution. Nonetheless, the commercialization of pyrolysis faces hurdles. A key challenge involves extracting the fuel phase from raw bio-oil. While numerous studies focus on biomass pyrolysis, comprehensive examinations of fuel phase extraction and subsequent characterization remain limited. Thus, this research concentrates on extracting the fuel phase from pyrolysis oil generated via the lesser-explored Azadirachta indica biomass followed by subsequent characterization. Dichloromethane and n-hexane were the solvents employed at four different volume percentages (10%, 20%, 30% and 40%) as solvents relative to raw bio-oil. The n-hexane emerged as a superior choice based on density, dynamic viscosity, calorific value and selectivity. The pinnacle achievement lies in the fuel phase extracted using 30 and 40 vol. % n-hexane, exhibiting physiochemical comparability to conventional gasoline. For instance, calorific values ranged between 29.1 and 37.1 MJ/kg for n-hexane-extracted fuel phases, compared to 15.1–19.6 MJ/kg for dichloromethane-extracted ones. Fourier-Transform-Infrared spectroscopy unveiled aliphatic compounds, ketones, aromatics, t-butyl compounds, alcohols, hydrocarbons and carboxylic acids. Gas-Chromatography-Mass-Spectroscopy highlighted furan, 2-methoxy- and ethanol, pentamethyl as principal compounds. Energy density of biochar and non-condensable gases stood at 28.5 MJ/kg and 14.9 MJ/Nm3, respectively. Non-condensable gases comprised of 15.9% H2, 26.7% CO, 23.8% CH4 and 33.6% CO2.

Suggested Citation

  • Ahmed, Gaffer & Kishore, Nanda, 2023. "Fuel phase extraction from pyrolytic liquid of Azadirachta indica biomass followed by subsequent characterization of pyrolysis products," Renewable Energy, Elsevier, vol. 219(P1).
    • Handle: RePEc:eee:renene:v:219:y:2023:i:p1:s0960148123013757
    DOI: 10.1016/j.renene.2023.119460
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148123013757
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2023.119460?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Liu, Zhijia & Mi, Bingbing & Jiang, Zehui & Fei, Benhua & Cai, Zhiyong & Liu, Xing'e, 2016. "Improved bulk density of bamboo pellets as biomass for energy production," Renewable Energy, Elsevier, vol. 86(C), pages 1-7.
    2. Das, Sutapa & Goud, Vaibhav V., 2021. "RSM-optimised slow pyrolysis of rice husk for bio-oil production and its upgradation," Energy, Elsevier, vol. 225(C).
    3. Aghbashlo, Mortaza & Almasi, Fatemeh & Jafari, Ali & Nadian, Mohammad Hossein & Soltanian, Salman & Lam, Su Shiung & Tabatabaei, Meisam, 2021. "Describing biomass pyrolysis kinetics using a generic hybrid intelligent model: A critical stage in sustainable waste-oriented biorefineries," Renewable Energy, Elsevier, vol. 170(C), pages 81-91.
    4. Nawaz, Ahmad & Kumar, Pradeep, 2022. "Pyrolysis behavior of low value biomass (Sesbania bispinosa) to elucidate its bioenergy potential: Kinetic, thermodynamic and prediction modelling using artificial neural network," Renewable Energy, Elsevier, vol. 200(C), pages 257-270.
    5. Sun, Yifan & Li, Chao & Zhang, Shu & Li, Qiaoling & Gholizadeh, Mortaza & Wang, Yi & Hu, Song & Xiang, Jun & Hu, Xun, 2021. "Pyrolysis of soybean residue: Understanding characteristics of the products," Renewable Energy, Elsevier, vol. 174(C), pages 487-500.
    6. Rammohan, Draksharapu & Kishore, Nanda & Uppaluri, Ramagopal V.S., 2022. "Pyro–catalytic co–pyrolysis of Delonix regia and butyl rubber tube: Kinetic modelling and thermodynamic insights," Renewable Energy, Elsevier, vol. 201(P1), pages 194-203.
    7. Hasan, M.M. & Rasul, M.G. & Ashwath, N. & Khan, M.M.K. & Jahirul, M.I., 2022. "Fast pyrolysis of Beauty Leaf Fruit Husk (BLFH) in an auger reactor: Effect of temperature on the yield and physicochemical properties of BLFH oil," Renewable Energy, Elsevier, vol. 194(C), pages 1098-1109.
    8. Yang, Yadong & Shahbeik, Hossein & Shafizadeh, Alireza & Masoudnia, Nima & Rafiee, Shahin & Zhang, Yijia & Pan, Junting & Tabatabaei, Meisam & Aghbashlo, Mortaza, 2022. "Biomass microwave pyrolysis characterization by machine learning for sustainable rural biorefineries," Renewable Energy, Elsevier, vol. 201(P2), pages 70-86.
    9. Krishna, Bhavya B. & Biswas, Bijoy & Ohri, Priyanka & Kumar, Jitendra & Singh, Rawel & Bhaskar, Thallada, 2016. "Pyrolysis of Cedrus deodara saw mill shavings in hydrogen and nitrogen atmosphere for the production of bio-oil," Renewable Energy, Elsevier, vol. 98(C), pages 238-244.
    10. Raheem, Abdul & Wan Azlina, W.A.K.G. & Taufiq Yap, Y.H. & Danquah, Michael K. & Harun, Razif, 2015. "Thermochemical conversion of microalgal biomass for biofuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 49(C), pages 990-999.
    11. Zhang, Zhiyi & Li, Yingkai & Luo, Laipeng & Yellezuome, Dominic & Rahman, Md Maksudur & Zou, Jianfeng & Hu, Hangli & Cai, Junmeng, 2023. "Insight into kinetic and Thermodynamic Analysis methods for lignocellulosic biomass pyrolysis," Renewable Energy, Elsevier, vol. 202(C), pages 154-171.
    12. Marcin Jewiarz & Krzysztof Mudryk & Marek Wróbel & Jarosław Frączek & Krzysztof Dziedzic, 2020. "Parameters Affecting RDF-Based Pellet Quality," Energies, MDPI, vol. 13(4), pages 1-17, February.
    13. Garg, Rahul & Anand, Neeru & Kumar, Dinesh, 2016. "Pyrolysis of babool seeds (Acacia nilotica) in a fixed bed reactor and bio-oil characterization," Renewable Energy, Elsevier, vol. 96(PA), pages 167-171.
    14. Kartal, Furkan & Dalbudak, Yağmur & Özveren, Uğur, 2023. "Prediction of thermal degradation of biopolymers in biomass under pyrolysis atmosphere by means of machine learning," Renewable Energy, Elsevier, vol. 204(C), pages 774-787.
    15. Kawale, Harshal D. & Kishore, Nanda, 2021. "Comprehensive study on thermochemical putrefaction of Delonix Regia in non-catalytic, catalytic and hydro-catalytic pyrolysis atmospheres," Renewable Energy, Elsevier, vol. 173(C), pages 223-236.
    16. Baghel, Paramjeet & Sakhiya, Anil Kumar & Kaushal, Priyanka, 2022. "Influence of temperature on slow pyrolysis of Prosopis Juliflora: An experimental and thermodynamic approach," Renewable Energy, Elsevier, vol. 185(C), pages 538-551.
    17. Wu, Yujian & Wang, Haoyu & Li, Haoyang & Han, Xue & Zhang, Mingyuan & Sun, Yan & Fan, Xudong & Tu, Ren & Zeng, Yimin & Xu, Chunbao Charles & Xu, Xiwei, 2022. "Applications of catalysts in thermochemical conversion of biomass (pyrolysis, hydrothermal liquefaction and gasification): A critical review," Renewable Energy, Elsevier, vol. 196(C), pages 462-481.
    18. Zhang, Haifeng & Ju, Shuai & Jin, Xin & Yuan, Yan & Wu, Yingji & Nadda, Ashok Kumar & Pugazhendhi, Arivalagan & Cai, Liping & Xia, Changlei, 2022. "A review of sensor applications towards precise control of pyrolysis of solid waste and biomasses," Renewable and Sustainable Energy Reviews, Elsevier, vol. 169(C).
    19. Kim, Jeong Wook & Lee, Hyung Won & Lee, In-Gu & Jeon, Jong-Ki & Ryu, Changkook & Park, Sung Hoon & Jung, Sang-Chul & Park, Young-Kwon, 2014. "Influence of reaction conditions on bio-oil production from pyrolysis of construction waste wood," Renewable Energy, Elsevier, vol. 65(C), pages 41-48.
    20. Çeli̇k, Mehmet & Bayindirli, Cihan, 2020. "Enhancement performance and exhaust emissions of rapeseed methyl ester by using n-hexadecane and n-hexane fuel additives," Energy, Elsevier, vol. 202(C).
    21. Ellison, Candice Raffaela & Hoff, Ryan & Mărculescu, Cosmin & Boldor, Dorin, 2020. "Investigation of microwave-assisted pyrolysis of biomass with char in a rectangular waveguide applicator with built-in phase-shifting," Applied Energy, Elsevier, vol. 259(C).
    22. Singh, Satyansh & Chakraborty, Jyoti Prasad & Mondal, Monoj Kumar, 2020. "Torrefaction of woody biomass (Acacia nilotica): Investigation of fuel and flow properties to study its suitability as a good quality solid fuel," Renewable Energy, Elsevier, vol. 153(C), pages 711-724.
    23. Akhtar, Javaid & Saidina Amin, NorAishah, 2012. "A review on operating parameters for optimum liquid oil yield in biomass pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5101-5109.
    24. Collard, François-Xavier & Blin, Joël, 2014. "A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 594-608.
    25. Kawale, Harshal D. & Kishore, Nanda, 2020. "Comparative study on pyrolysis of Delonix Regia, Pinewood sawdust and their co-feed for plausible bio-fuels production," Energy, Elsevier, vol. 203(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ahmed, Gaffer & Kishore, Nanda, 2024. "Synergistic effects on properties of biofuel and biochar produced through co-feed pyrolysis of Erythrina indica and Azadirachta indica biomass," Renewable Energy, Elsevier, vol. 227(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ahmed, Gaffer & Kishore, Nanda, 2024. "Synergistic effects on properties of biofuel and biochar produced through co-feed pyrolysis of Erythrina indica and Azadirachta indica biomass," Renewable Energy, Elsevier, vol. 227(C).
    2. Bhoi, P.R. & Ouedraogo, A.S. & Soloiu, V. & Quirino, R., 2020. "Recent advances on catalysts for improving hydrocarbon compounds in bio-oil of biomass catalytic pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    3. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.
    4. Gurevich Messina, L.I. & Bonelli, P.R. & Cukierman, A.L., 2017. "Effect of acid pretreatment and process temperature on characteristics and yields of pyrolysis products of peanut shells," Renewable Energy, Elsevier, vol. 114(PB), pages 697-707.
    5. Xie, Yingpu & Zeng, Kuo & Flamant, Gilles & Yang, Haiping & Liu, Nian & He, Xiao & Yang, Xinyi & Nzihou, Ange & Chen, Hanping, 2019. "Solar pyrolysis of cotton stalk in molten salt for bio-fuel production," Energy, Elsevier, vol. 179(C), pages 1124-1132.
    6. Luo, Juan & Ma, Rui & Lin, Junhao & Sun, Shichang & Gong, Guojin & Sun, Jiaman & Chen, Yi & Ma, Ning, 2023. "Review of microwave pyrolysis of sludge to produce high quality biogas: Multi-perspectives process optimization and critical issues proposal," Renewable and Sustainable Energy Reviews, Elsevier, vol. 173(C).
    7. Li, Longzhi & Cai, Dongqiang & Zhang, Lianjie & Zhang, Yue & Zhao, Zhiyang & Zhang, Zhonglei & Sun, Jifu & Tan, Yongdong & Zou, Guifu, 2023. "Synergistic effects during pyrolysis of binary mixtures of biomass components using microwave-assisted heating coupled with iron base tip-metal," Renewable Energy, Elsevier, vol. 203(C), pages 312-322.
    8. Mishra, Ranjeet Kumar & Mohanty, Kaustubha, 2019. "Pyrolysis of three waste biomass: Effect of biomass bed thickness and distance between successive beds on pyrolytic products yield and properties," Renewable Energy, Elsevier, vol. 141(C), pages 549-558.
    9. Hemant Ghai & Deepak Sakhuja & Shikha Yadav & Preeti Solanki & Chayanika Putatunda & Ravi Kant Bhatia & Arvind Kumar Bhatt & Sunita Varjani & Yung-Hun Yang & Shashi Kant Bhatia & Abhishek Walia, 2022. "An Overview on Co-Pyrolysis of Biodegradable and Non-Biodegradable Wastes," Energies, MDPI, vol. 15(11), pages 1-27, June.
    10. Biswas, Bijoy & Singh, Rawel & Kumar, Jitendra & Singh, Raghuvir & Gupta, Piyush & Krishna, Bhavya B. & Bhaskar, Thallada, 2018. "Pyrolysis behavior of rice straw under carbon dioxide for production of bio-oil," Renewable Energy, Elsevier, vol. 129(PB), pages 686-694.
    11. Cai, Junmeng & Xu, Di & Dong, Zhujun & Yu, Xi & Yang, Yang & Banks, Scott W. & Bridgwater, Anthony V., 2018. "Processing thermogravimetric analysis data for isoconversional kinetic analysis of lignocellulosic biomass pyrolysis: Case study of corn stalk," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2705-2715.
    12. Kabir, G. & Hameed, B.H., 2017. "Recent progress on catalytic pyrolysis of lignocellulosic biomass to high-grade bio-oil and bio-chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 945-967.
    13. Rammohan, Draksharapu & Kishore, Nanda & Uppaluri, Ramagopal V.S., 2022. "Pyro–catalytic co–pyrolysis of Delonix regia and butyl rubber tube: Kinetic modelling and thermodynamic insights," Renewable Energy, Elsevier, vol. 201(P1), pages 194-203.
    14. Kan, Tao & Strezov, Vladimir & Evans, Tim J., 2016. "Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1126-1140.
    15. Chen, Wei-Hsin & Lin, Bo-Jhih, 2016. "Characteristics of products from the pyrolysis of oil palm fiber and its pellets in nitrogen and carbon dioxide atmospheres," Energy, Elsevier, vol. 94(C), pages 569-578.
    16. Andrew N. Amenaghawon & Chinedu L. Anyalewechi & Charity O. Okieimen & Heri Septya Kusuma, 2021. "Biomass pyrolysis technologies for value-added products: a state-of-the-art review," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 23(10), pages 14324-14378, October.
    17. Angelos-Ikaros Altantzis & Nikolaos-Christos Kallistridis & George Stavropoulos & Anastasia Zabaniotou, 2022. "Peach Seeds Pyrolysis Integrated into a Zero Waste Biorefinery: an Experimental Study," Circular Economy and Sustainability, Springer, vol. 2(1), pages 351-382, March.
    18. Al-Rumaihi, Aisha & Shahbaz, Muhammad & Mckay, Gordon & Mackey, Hamish & Al-Ansari, Tareq, 2022. "A review of pyrolysis technologies and feedstock: A blending approach for plastic and biomass towards optimum biochar yield," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    19. Sahoo, Abhisek & Saini, Komal & Negi, Shweta & Kumar, Jitendra & Pant, Kamal K. & Bhaskar, Thallada, 2022. "Inspecting the bioenergy potential of noxious Vachellia nilotica weed via pyrolysis: Thermo-kinetic study, neural network modeling and response surface optimization," Renewable Energy, Elsevier, vol. 185(C), pages 386-402.
    20. Qin, Tao & Lu, Qiuxiang & Xiang, Hao & Luo, Xiulin & Shenfu, Yuan, 2023. "Ca promoted Ni–Co bimetallic catalyzed coal pyrolysis and char steam gasification," Energy, Elsevier, vol. 282(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:219:y:2023:i:p1:s0960148123013757. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.